高盐氨氮废污水处理技术进展吴叶

46520175AppliedChemicalIndustryVol．46No．5May20172016-10-102016-12-13515680231993－。[e-mail]。[e-mail]/341000/、/。。/TQ085+．4X703A1671－3206201705－0972－05Theresearchprogressintreatmentofhigh-saltandammonium-nitrogenwastewaterWUYeCHENYun-nenGUOLinLIUChenSchoolofＲesourceandEnvironmentalEngineeringJiangxiUniversityofScienceandTechnologyGanzhou341000ChinaAbstractTheresearchstatusathomeandabroadwasintroducedincludingphysicalandchemicaltech-nologybiotechnologyandcombinedprocess．Themethodsofdifferentwaterqualitywascomparedandthetechnicaldevelopmentofhighsaltandammoniumnitrogenwastewaterinthefuturewaspointedoutsothatprovideduseffectivedealingmethodforactualammonium-nitrogenwastewater．Keywordshigh-saltammoniumnitrogenwastewatertreatmentreviewNH4+NH3。。pH。、、、。、、、。1%。、、。。、//。1、、、。1．1AOPs1·OH。。·OH。Cl－Cl22。DOI:10.16581/j.cnki.issn1671-3206.2017.05.0345/2Cl－→Cl2+2e－1Cl2+H2O→HClO+H++Cl－2NH4+3·OH→0．5N2+3H2O+H+32NH4+3HClO→N2+3H2O+5H++3Cl－4、、、3。。4DSATi/ＲuO2-IrＲ2Na+、Cl－。。3750．4mg/L、28g/L200mA/cm2120min100%。、pH、。5Ti/ＲuO2-TiO2-IrO2-SnO2、。472．73mg/L7%156mA/cm20．8dm2/L1．5cmpH60min99．94%。0．096kW·h/g。6TiO2500mg/L3mg/L。7。1．2。、、。、Na+、Ca2+NH4+8-9。。-。10Na+30g/L、600mg/L。NH4+OH－NH3NH3。NaOH0．75mol/LNH3/TN0．57．68g/L99．8%。1．3。nMg∶nN∶nP=1．2∶1∶1．240min95．5%11。12NaClON2NaClO。、NaClO500∶1。pHNH4+NH3NH3NH42SO4H2SO4。13、pH、。7．5%99．8%。2。。、。A/O、SBＲ、、MBＲ。2．1--。37946。2．1．1A/OA/O-。1450%A/OpHHＲT。Yufei15200%、80%、C/N4．5～5．5A/O《》GB13458—2013。A/O。。。16A/O、、COD、《》GB8978—1996B。。2．1．2SBＲSBＲ。、。17。18K+、Ca2+、Mg2+。K+K+100mg/L39．8%。19SBＲ、90%。20SBＲ。2．2、、、、。Anammoxan-ammoxNO2－NH2OHNH2OHNH4+-NN2NO3－。NaCl50g/Lanammox21。Tomonori22anammox60danammox85．5%。。Yang2392d。30g/LKU2。。24512mg/L、30g/L51%11%。。25。10h、30℃、pH8．5DO4mg/LC/N1090%。2．3-、、、2．7%～4．7%、26A/O、、COD。。272．5g/L。MBＲ。28MBＲ4795/。MBＲ9g/L99%29。3017．5g/L300mg/L。COD90%。。31MBBＲAFAF-MBBＲ78%。32MABＲNaCl5g/L45g/L0COD。330～2%COD。SBBＲCOD。3。。COD、、NaCl。34Fenton“+”PAC。COD99．8%95%《》GB8978—1996。、、Ca2+、Cl－SO42－、。--A/O35、90．3%90．5%。。、、、、。36《》GB26451—2011。2000mg/L10mg/L。37MVP“+MVP”。。Wang38A/O--MBＲ。。80%。Hirata39-90%～98%80%～92%。--。。4/。、、、A/OSBＲ57946。、、。①②。③④⑤。1．J．201533936-940．2．CODJ．201121613-17．3．Ce-PbO2/CBJ．201483941-947．4．J．201535760-64．5．J．201373815-819．6．J．201542590-91．7．D．2013．8Leyva-ＲamosＲMonsivais-ＲochaJEAragon-PiaAetal．ＲemovalofammoniumfromaqueoussolutionbyionexchangeonnaturalandmodifiedchabaziteJ．JournalofEnvironmentalManagement201091122662-2668．9HuangHMXiaoXMYanBetal．AmmoniumremovalfromaqueoussolutionsbyusingnaturalChineseCheng-dezeoliteasadsorbentJ．JournalofHazardousMateri-als20101751/2/3247-252．10．D．2012．11．MAPJ．20143021110-113．12．NaClOJ．20131140-42．13．D．2013．14．A/OD．2008．15BaoYufeiLiMengZhangQian．Ｒesearchonthelarge-scaleapplicationofnitrogenremovalforthetreatmentofsyntheticammoniawastewaterJ．DesalinationandWaterTreatment2016572712763-12769．16．A/OJ．20161031035-1040．17．M．3．2008．18．K+、Ca2+、Mg2+J．20148104267-4272．19．SBＲJ．201434354-57．20．J．2015962699-2705．21．J．2016252346-352．22TomonoriKindaichiTakanoriAwataYujiSuzukietal．Enrichmentusinganup-flowcolumnreactorandcommu-nitystructureofmarineanammoxbacteriafromcoastalsedimentJ．MicrobesandEnvironments201126167-73．23YangJiachunZhangLiHiraDaisukeetal．Anammoxtr-eatmentofhigh-salinitywastewateratambienttemperatureJ．BioresourceTechnology201010232367-2372．24．、D．2015．25．J．2013751807-1812．26．A/OJ．2011271102-104108．27．D．2011．28JohirMAHVigneswaranSKandasamyJetal．EffectofsaltconcentrationonmembranebioreactorMBＲper-formancesDetailedorganiccharacterizationJ．Desalina-tion201332213-20．9816795PLA31OriettaMMichelaCLorenzaG．SilsesquioxanesnovelcompatibilizingagentsfortuningthemicrostructureandpropertiesofPLA/PCLimmiscibleblendsJ．EuropeanPolymerJournal20145869-78．32LiLZSongGTangGY．Novelbiodegradablepolylac-tide/polybutylenesuccinatecompositesviacross-link-ingwithmethylenediphenyldiisocyanateJ．Polymer-PlasticsTechnologyandEngineering201352121183-1187．33BriassoulisDMistriotisAGiannoulisAetal．OptimizedPLAbasedEMAPsystemsforhorticulturalproducede-signedtoregulatethetargetedin-packageatmosphereJ．IndustrialCropsandProducts201348768-80．34．J．2015439216-218．35ChenBKShenCHChenA．PreparationofductilePLAmaterialsbymodificationwithtrimethylhexamethylenedi-isocyanateJ．PolymerBull2012693313-322．36MihaiMHuneaultMAFavisBD．Ｒheologyandextru-sionfoamingofchain-branchedpolylacticacidJ．PolymerEngineeringandScience2010503629-642．37WangJZhuWZhangHetal．Continuousprocessingoflow-densitymicrocellularpolylacticacidfoamswithcontrolledcellmorphologyandcrystallinityJ．ChemicalEngineeringScience201275390-399．38DeanKMPetinakisEMeureSetal．Meltstrengthandrheologicalpropertiesofbiodegradablepolylacticacidmodifiedviaalkylradical-basedreactiveextrusionproces-sesJ．JournalofPolymersandtheEnvironment2012203741-747．39．/J．201433123304-3309．40MaSJLiYFZhaoYetal．Hemocompatibilityandcy-tocompatibilityofdiblockcopolymerpolypoly2-ethyl-2-oxazoline-polydlactide-basedmicellesJ．JournalofChinesePharmaceuticalSciences20142310674-680．41．D．201312-13．42KuMarsillaKIVerbeekCJＲ．Modificationofpolylac-ticacidusingitaconicanhydri