合成阻垢剂研究现状及展望张波

张　波1　唐星华1　苏玉春1　王仙芳1　张　涛2(1.　330063;2.　330029)　:,。,,。。:　　,,[1]。,,,,,,、,[2]。,,、、[3]。,,。,,,,,。,、、,,,[4]。1　,(AA)、(MA),(PAA)、(PMAA)、(PMA)(HPMA)。-COOH,Ca2+、Mg2+、Ba2+、Fe3+、Cu2+,,,。Doherty[5],2000～4000。[6]、、,(HPMA),HPMA,HP-MA。,AkioYuchi[7],Cu2+,Ca2+CaCO3。,,,。2　2080,。T-225;NalcoN-7319;Chemed/;Belz/(HPA)。[8],,(IA),(MAA)/(IA/MAA),、、。IA/MAA,,83%。[9],、(AA)/(HPA),、、、,,,,。,,[10]、,,,-。[11],30%,12　　　20094　DOI:10.14127/j.cnki.jiangxihuagong.2009.04.017-。、、、。,CaCO3,。3　,,,,。[12],。、、,,。,,、、。[13],,(MA)、(AA)(MAS)。、、、。[14](MA)、(AA)(AM),PMAA。,PMAA,,。[15],(BPO),、,--。[16](IA)、(IBS)(AA)IA/IBS/AA,,,CaCO394.65%。[17](AA)、2-(AMPS)。,,,。300mg·L-1,。[18]、、,、、、,。,2400。,15mg/L。4　,,,21,,,。(PASP)(PE-SA)。4.1　,,。Donla、,,,,,。,。OdaYoshihisa[19];[20],,,,,,,,,。[21],,,CaCO3,,,;[22],,,。[23],,,、、。PASP,PASP。Collins[24],,。[25]L-,,,,,5.0mg·L-1,CaCO3100,。4.2　(PESA)13　200912　　　(PESA)、,PESA、。,,。PESA,,。Nakato[26]PASP,。Ross[27]PASP,,1000～4000,2000～4000,,1000～2000,。,PASP,。[28],,、,,、、,,。[29]、、,,。,,、,。5　50,,。,,。,,,。:(1),,,;(2),,。[1],,.[J].,2002,(1):40-41[2],,.[J].,2004.17(1):26-28[3],,.[J].,2006,26(4):12-14.[4],,,.[J].,2007,24(2):1-4.[5]WOSDoherty,CMFellows,SGorjian,etal.Inhi-bitionofCalciumOxalateMonohydratebyPoly(acrylicacid)swithDifferentEndGroups[J].Journalofap-pliedPolymerScience,2004,91:2035-2041.[6],,.[J].(),2005,21(3):218-220[7]AkioYuchi,YasumasaGotoh,ShinsukeItoh.Poten-tiometryofeffectiveconcentrationofpolyacrylateasscaleinhibitor[J].AnalyticalChimicalActa.2007,547:199-203.[8],,./[J].,2007,24(1):65-68.[9],,./[J].,2004,22(2):19-23.[10],.-[J].,2008,36(6):12-15.[11],,,.-[J].:2006,26(6):612-615.[12],,,.[J].,2006,26(12):50-52.[13],,.MA-AA-MAS[J].(),2005,20(6):56-59.[14],,.MA-AA-AM[J].,2006,19(1):25-27.[15],,.[J].,2005,36(6):68-71.[16],,.[J].,2005,25(10):44-46.[17],,.TS25110[J].,2006,26(1):49-51.14　　　20094　[18],.--[J].,2006,26(6):50-53.[19]OdaYoshihisa.etal.MethodforProductionThereofandUseThereof[P].US6355771B,2002[20],,,.[J].,2005,24(2):105-108.[21],.[J].,2003(2):33-35[22],,,.[J].,2005,34(1):20-21.[23],.[J].,2006,18(3):34-36.[24]IRCollins,B.Hedges,LMHarris.TheDevelop-mentofaNovelEnvironmentallyFriendlyDualFunc-tionCorrosionandScaleInhibitor/[C]2001SPEIn-ternationalSympositumonOilfieldChemistry.Hous-ton:TX,2002:1316.[25],,.[J].,2002,24(1):87-89.[26]NakatoT,Kesser.Relationshipbetweenstructureandpropertiesofpolyasparticacids[J].Macromole-cules,1998,31(7):2107-2113.[27]RossRJ,LowKC,ShannonJE.Polyaspartatescaleinhibitors———biodegradablealternativestopolyacry-lates[J].MaterialPerformance,2003,36(4):53-57.[28],.[J].,2004(3):34-36[29],.[J].,2005,23(1):85-87.CircumstanceandprospectofsyntheticscaleinhibitorZhangBo　TangXing-hua　SuYun-chun　WangXian-fang　ZhangTao(1.CollegeofAeronauticsEnvironmentChemicalEngineering,NanchanghangkongUniversity,nanchang330063,china;2.EastChinaJiaoTongUniversityForeighLanguageDeparment,330029)Abstract:Syntheticscaleinhibitorsaresomekindwatertreatmentagent,whichareappliedwidelyinindustrialcirclewatersystem.Thesortsanddomesticcircumstanceofsyntheticscaleinhibitorswassummarized,anditsresearchdirectionwaspointedout.Poly-asparticacidandpoly-asparticacidarethefocusofgreenscaleinhibitorbothhomeandabroad.KeyWords:scaleinhibitor　synthesis　application15　200912