化妆品生产废水处理技术研究进展

5[1]。2025%20102000[2]。200821t10.56t49550g309.4g121.6g[3]。、LAS。。1、、、、。、、、、、、、。—、、、、、、、、、[4]。1。、、[5]。2。、、。、、[6]。1。1。。COD、LASCOD10000mg/L*200092、、、。X703Adoi10.3969/j.issn.1003-6504.2010.05.0231003-6504(2010)05-0103-06ProgressonTreatmentMethodforWastewaterfromCosmeticIndustryCHENXinYANGHai-zhenHUANGXiang-feng*StateKeyLaboratoryofPollutionControlandResourceReuseSchoolofEnvironmentalScienceandEngineeringTongjiUniversityShanghai200092ChinaAbstractSourcesandcharacteristicsofwastewaterfromcosmeticindustrywereintroduced.Avarietyofphysicalchemicalphysi-chemicalbiologicalandecologicaltreatmenttechnologiesforcosmeticindustrywastewaterincludingnewtechnologieswerestudiedwhichwouldprovidereferenceforthetreatmentofcosmeticindustrywastewater.Keywordscosmeticindustrywastewatertreatmenttechnologydevelopment2009-12-2220[e-mail]*[e-mail]。EnvironmentalScience&Technology33520105Vol.33No.5May20101Table1ThewaterqualityofwastewaterfromcosmeticindustryCODBODSSLASpH1700~10000500~500080~500020~30017~2005~12pHmg/L。33。1000mg/L[7]。2。AES、、PCMX、、、[8]。。3。BOD/COD、[9]。4。。、、[10][11]。2CODLAS。、、、。2.11。5~36h。[9]。2。[12]。3。SS、。[13]。[14]LAS80mg/L10mg/L。2.21。FentonFe2+-H2O2Fe2+H2O2。BautistaP[15]TOCCOD、。COD47302660mg/LpH3.0Fe2+200mg/LH2O2COD2.12TOC25℃45%50℃60%。FentonCOD1750mg/L。2。、Fe、C。[16]。pH6、、、[17]。Fe2+FeOH2FeOH3。[18]、。1/33.8h。COD5440mg/L4080mg/L25%。3TiO2。[19]。[20]。BoroskiM[21]COD=1753mg/LBOD=200mg/LSS=150~250mg/LpH=7.325.50。/763A/m2pH6.090min86%COD91%COD1753mg/L1045160mg/L。pH3.0UV/TiO2/H2O20.25g/LTiO210mmol/LH2O24hCOD50mg/L。2.3SSLAS。[22]pH5.5~8.5150mg/LCOD91.80%SS80%。COD79.62%COD128mg/L-。[23]。COD、SS、LASCOD9783mg/L3033mg/L69%SS4175mg/L334mg/LLAS192mg/L15.2mg/LpH8.5。[9]。Al2SO43Al2O315mg/L25mg/L35mg/LCOD35.6%42.1%49.2%。。AlouiF[24]Jasminal-Fenton。COD11423mg/LLAS3148mg/L———FeAlFentonCODLAS。Fenton98%LAS80%COD。2.4、。2.4.11。[25]。。LAS[5]。[26]COD、BOD5、SS、LAS64%、45%、9%、73%B/C0.410.64。[9]A/O。15h13h4d、CODBOD51782.8mg/L537mg/LCODBOD51165.6mg/L417mg/LB/C0.30.36。。2ASBR。ASBRCOD。[23]ASBR-SBRASBRCOD、LAS、、。ASBRCOD=3033mg/LSS=334mg/LLAS=38mg/LCOD=657mg/LSS=178mg/LLAS=6.4mg/L。[12]ASBR12h。ASBRB/C0.4630.5400.3920.518ASBR。3UASB。UASB[27]。[14]、、400m3/dCOD10000mg/LBOD53000mg/LLAS80mg/L。UASB48hCOD90%。UASB、、、。[28]UASB———、、。1053318.8h。UASB、。COD90%LAS95%。2.4.21SBR。SBR。[13]--SBR、、SBRCOD、BOD、SS、LAS93%、95%、28%、33%。COD=4830~9245mg/LSBRCOD=712~1310mg/LCODCOD≤80mg/L。2。、、、、、[29]。。[30]COD=4000mg/LBOD5=1100mg/LSS=120mg/L。38h19hCOD0.44kg/m3·d0.25kg/m3·dCOD70%60%。[31]、、COD=5000mg/LBOD5=1500mg/LSS=1000mg/L。COD、BOD5、SS97.6%97.9%87.4%。。3BAF。MeutiaA.A[32]1998。SSpH。2r/min48L/dCODBOD90%。。[33]-COD3~8mg/LCODCOD100mg/L80mg/L。2.5。KoukiosM[34]COD10000~15000mg/L。COD520mg/LBOD5237mg/L。COD86mg/LBOD540mg/L。3。-、--1。、。1065、。。。5。、、。。[][1].[J].200411299-101.WuJian-jun.AnalysisanddiscussiononChina'scurrentregulationsofcosmetic[J].ChineseJournalofHealthInspec－tion200411299-101.inChinese[2][J].200619323.ThedevelopmentprospectsofChina'scosmeticindustry[J].Light&TextileIndustriesofFujian200619323.inChinese[3].[M].2008.LeadingGroupOfficeoftheFirstNationalPollutionCensusoftheStateCouncil.TheFirstNationalCensusofIndustrialPollutionSourcesProducingSewageCoefficientHandbook[M].BeijingLeadingGroupOfficeoftheFirstNationalPollutionCensusoftheStateCouncil2008.inChinese[4].[M].2007.DongYin-mao.CosmeticFormulationDesignandProduc－tionProcess[M].BeijingChinaTextile&ApparelPress2007.inChinese[5].[M].2002.ZhangTian-shengLiMing-rong.HouseholdChemicalWastewaterTreatmentTechnologyandItsApplications[M].BeijingChemicalIndustryPress2002.inChinese[6].[M].2001.WangShen-min.DailyChemicalsChemistryDailyChemi－calFormulaDesignandProductionProcess[M].HarbinHarbinInstituteofTechnologyPress2001.inChinese[7]ADEME.TensioactifetOléagineuxEtudesurlesmatièrespremièresoléagineusesdisponiblessurlemarchéeuropéenpourlaproductiondetensioactifs[C].ParisAgencedel’En－vironnementetdelaMaìtrisedel’EnergieDirectiondel’AgricultureetdesBioénergies2001.[8].[M].2000.FengXiao-xiWuXi-kang.FineChemicalsWastewaterTreatmentTechnology[M].BeijingChemicalIndustryPress2002.inChinese[9].A/O[J].20011431-2.YuRanLvXi-wu.Experimentstudyofcosmeticssewagetreatmentbybiologicalcontactoxidationsystem[J].JiangsuEnvironmentalScienceandTechnology20011431-2.inChinese[10].[D].20053-4.ZhaoXu.ResearchontheApplicationofFlotationandBi－ologicalTreatmentofCosmeticsWastewater[D].HebeiNorthChinaElectricPowerUniversity20053-4.inChinese[11],.[J].200730443-4447.ChenZhu-ling,HuangYu-kui,WangGui-mei,etal.De－tectionmethodofphthalatesofenvironmenthormoneincosmetics[J].EnvironmentalScience&Technology200730443-4447.inChinese[12].ASBR-SBR[J].200321131-3243.YangMin-shan.Treatmentofcosmetic-producingwastew－aterbyprocessASBR-SBR[J].EnvironmentEngineering200321131-3243.inChinese[13].--SBR[J].200536278-80.YangMin-shanHuYong-youChenQiu-yan.Treatmentofwastewaterfromcosmeticsplantbyprocessfloatation-hydrolysis-SBR[J].IndustrialWater&Wastewater200536278-80.inChinese[14].-UASB-[J].200511625-26.LinFang-min.Exampleforwastewaterofc