环糊精在环境污染治理中的应用分析朱顺生

*266071。。。ANALYSISONAPPLICATIONOFCYCLODEXTRINSINENVIRONMENTALENGINEERINGZhuShunshengYanDongyunLouYinghuaShiLeiCollegeofChemicalEngineeringandEnvironmentalSciencesQingdaoUniversityQingdao266071ChinaAbstractBecauseofitsuniquestructuralfeaturescyclodextrinwillbewidelyusedinenvironmentalengineering.Thispapersummarizedtheroleofcyclodextrinsintheremovaloforganicpollutantsinwatertheremedyofthepollutantsinthesoilandotherapplicationsindealingwithenvironmentalpollutants.Intheendtheprospectsofcyclodextrinsandtheirderivatives'applicationinenvironmentalprotectionwerediscussed.Keywordscyclodextrinorganiccontaminantstreatmentwaterpollutionsoilpollution*Y052010023。0CyclodextrinCD6～12D－。6、7、8alpha-、beta-gama-。RimCavityHostGuest。Cd2+1。。11.12。Soman。β－CDpH7.4。1203-4。1.25。。1β－CD6。1.31220112291DOI:10.13205/j.hjgc.2011.01.0081β－CDg/L24h40mg/LCD24h30101－1051430.0580020060。Wang7HPCD、、、DDT。HPCDHPCD。HPCD。HPCD。8。HPCDβ－。β－CD－β－9。。Jodi10β－4。1.411。、12。β－13。。、“”。1.5。。14β－19β－。15β－HPCD1.7～22.4。。。β－。60mg/Lβ－30%～50%16。22.1。。Chatain17β－CMCD、、。80mmol/LCMCD、、20、1000、4000。β－3CMCD18。CMCD90%。CMCD。、、2220112291CMCDCMCD10g/LCMCD200mg/L。CMCD1000mg/LCMCD。19。。2.2。。。β－20。。21。Garon22。。Bardi23β－。2.3。2425。。。β－26。Ko27HPCD。HPCD25%6.85mmol/LHPCD56%。2.42090。。、、、、、。Brusseau28HPCDHPCD、、、2－、、、244′－2。HPCD。HPCD。2HPCDHPCD8.05.292.015.72.11.12.21.12－5.01.128.61.1161.82.4244′－8281.633.129－30。。3.23220112291。HPCDβ－CD31。3.3。。432。3.4FF。40minβ－21%120minβ－F48%F18%。F33。AnandanTiO2TiO2－β－CD34。1.8TiO2β－。4。、。。。1.J.20072911844-847.2.J.1992122126-138.3DesireBSaint-AndreS.Interactionofsomanwithβ-CyclodextrinJ.ToxicologicalSciences198674646－657.4VoyksnerRDWiuiamsFPSmithCSetal.Analysisofcyclodextrinsusingfastatombombardment/massspectrometryandtandemmassspectrometryJ.BioMassSpectrometry198918121071-1078.5OláhJCserhátiTSzejtliJ.β-CyclodextrinenhancedbiologicaldetoxificationofindustrialwastewatersJ.WaterRes198822111345-1351.6SzejtliJMinutesIntSymcyclodextrinsM.6th.ParisStante1992521.7WangXJBrusseauML.Solubilizationofsomelow-polarityorganiccompoundsbyhydroxypropyl-beta-cyclodextrinJ.EnvironSciTechnol199327132821-2825.8SingerYShityHBarR.AroleforLTEPalowtemperatureessentialproteininvolvedinmitosisinproproteinprocessingintheyeastsecretorypathwayJ.ApplMicrobiolBiotechnol199135731-746.9MurphyRSBohneC.Useofstyreneradicalcationsasprobesforthecomplexationdynamicsofchargedguestswithα-andβ-cyclodextrinsJ.PhotochemistryandPhotobiology19931074655-4662.10JodiMSchuetteTNodouT.Influenceofalcoholsontheβ-cyclodextrinacridinecomplexJ.JAmChemSoc19931151292-298.11KawaguchiYMizobuchiYTanakaMetal.Bulltchemsorptionbehaviorofaromaticcompoundsinwateronβ-cyclodextrinpolyurethaneJ.ResinsSocJpn19825582611-2614.12KimuraMWakaiMShimizuY.SelectedadsorptionofcomponentsindyeingwastewaterbyacellulosicadsorbentandreuseofthetreatedwastewaterJ.MizuShoriGijutsu1986277485-490.13.J.200826176-179.14.J.19986480-86.15.J.2002225387-391.16JezsefOCserhatiTSzejtliJ.β-CyclodextrinenhancedbiologicaldetoxificationofindustrialwastewatersJ.WaterRes198822111345-1349.17ChatainVHannaKBrauerCDetal.Enhancedsolubilizationofarsenicand2346tetrachlorophenolfromsoilsbyacyclodextrinderivativeJ.Chemosphere2004573197-206.18WangXJ.BrusseauML.Cyclodextrin-enhancedsolubilizationofpolycyclicaromatichydrocarbonsbycyclodextrinsJ.EnvironSciTechnol19952992346-2351.19BrusseauMLWangXJWangWZ.SimultaneouselutionofheavymetalsandorganiccompoundsfromsoilbycyclodextrinJ.EnvironSciTechnol19973141087-1092.20BardiLRicciRMarzonaM.InsitubioremediationofahydrocarbonpollutedsitewithcyclodextrinasacoadjuvanttoincreasebioavailabilityJ.WaterAir＆SoilPollution20023315-23.422011229121SivaramanC.AnasuyagangulysrikanthmutnuribiodegradationofhydrocarbonsinthepresenceofcyclodextrinsJ.WordJMicrobiolbiotechnol2009226227-232.22GaronDSageLSeigle-MurandiF.EffectsoffungalbioaugmentationandeyclodextrinamendmentonfluorenedegradationinsoilslurryJ.Biodegradation20041511-8.23BardiLMartiniCOpsiFetal.Cyclodextrin-enhancedinsitubioremediationofpolyaromatichydrocarbons-contaminatedsoilsandplantuptakeJ.InclPhenomMacrocyclChem200757439-444.24.J.200425298-103.25LagemanR.ElectroreclamationapplicationsintheNetherlandsJ.EnvironSciTechnol199327132648-2650.26KrantiMaturi.KrishnaRReddy.Cosolvent-enhanceddesorptionandtransportofheavymetalsandorganiccontaminantsinsoilsduringelectrokineticremediationJ.WaterAirSoilPollut2008189199-211.27KoSOSehlautmanMACart′awayER.Cyclodextrin-enhancedelectrokineticremovalofphenanthrenefromamodelclaysoilJ.EnvironSciTechno120003481535-1541.28BrusseauMLWangXHuQ.Enhancedtransportoflow-polarityorganiccompoundsthroughsoilbycyclodextrinJ.EnvironSciTechnol1994285952-958.29.J.2009272105-109.30ShibanaiINagatomoSGoseiJ.USPatent5492947BarriermaterialcomprisingathermoplasticandacompatiblecyclodextrinderivativeJ.PatternStorm19883442-9.31PatonGI.ReidBJ.Applicationofaluminescence-basedbiosensorforassessingnaphthalenebiodegradationinsoilsfromamanufacturedgasplantJ.EnvironmentalPollution20091571643-1648.32HuaGuoxiongJohnBroderickKirkTSempleetal.Rapidquantificationofpolycyclicaromatichydrocarb