煤燃烧过程中氮氧化物的转化及控制

20034(31)SHANXIENERGYANDCONSERVATION200312,,,(,250061):,NOV,NOV,:NOV;;:TQ534.9:B,,28%70%,,SO2NOV,NOV,2000NOV750mgöm3,NOV258.02t,2010NOV2000136t,NONO2NOVNOV,NO90%,NO25%10%,N2O1%NOV,NOV,NOV,,,NOV,,NOV,NOV:2003205207:(1973-),,,1995,(1958-),,,,(1965-),,,,(1978-),,,1NOV,NOV3:,NOV;CHHCNN,NOV,NOV;NOV,NOV1.1NOVNOV(N2)(O2),(Zeldovich)Zeldovich,:O2+M\2O+M,O+N2\NO+N,N+O2\NO+ONOVö:1800O,NOVA0.95T1800O,NOV1.2NOVNOVCHi(),1.2.1NOV,NOV:a),,CHCH2CH3C2,HCN,CN:CH+N2\HCN+N,CH2+N2\HCN+NH,CH3+N2\HCN+NH2,C2+N2\2CNb)HCNCN,O,OHNCO:HCN+O\NCO+H,HCN+OH\NCO+H2,CN+O2\HCO+Oc)NCONO:NCO+O\NO+CO,NCO+OH\NO+CO+Hd),,HCN,(NHi),NO:NH+O\N+OH,NH+O\NO+H,N+OH\NO+H,N+O2\NO+O1.2.2NOV,NOVNOVNOV,NOVN2CHiHCN,NOVNOV,NOVNOV5%,NOV,,NOVNOV11701359,T=501001800O,NOV1.3NOV0.5%2.5%,,(HCN)(NH3)CN,,NN,N75%90%NOVNOVNOVNOV1.3.1NHCN11HCNN,,,NHCNHCO,,NCO,NCONO,,NCONH:a),NO:HCN+ONCO+H,NCO+ONO+CO,NCO+OHNO+CO+Hb),NCONH:NCO+HNH+CONH,:NH+HN+H2,NH+NON2+OHNH,NO:NH+O2NO+OH,NH+ONO+H,NH+OHNO+H21.3.2NNH322NNH2,NH3NO,NO:a)NH3NO:NH3+OHNH2+H2O,NH3+ONH2+OH,NH3+HNH2+H2b)NH2NH:NH2+OHNH+H2O,NH2+ONH+OH,NH2+HNH+H2c)NHNO:NH+O2NO+OH,NH+ONO+H,NH+OHNO+H2,NOVNNOVNO60%80%,NNOV20%40%2NOVNOV,,,NOVNOV(),(N2)163NOV,NOVNOV,NOV:5120034,:3NOVa),NOV(NHi)(N)(N2),:NO+NHN2+OH,NO+NH2N2+H2O,NO+NN2+Ob)NO(CHi),:NO+CHHCN+O,NO+CH2HCN+OH,NO+CH3HCN+H2O,HCNOOHH(NCOHCNO):HCN+ONCO+H,HCO+OHHNCO+H:NCO+HNH+CO,HNCO+HNH2+CO,NH+HN+H2,NH2+NH2NH3+NHNHia)NON2NO,N2,:2NO+2CN2+2CO,2NO+2CON2+2CO2c)NONHiNON2O,:NCO+NON2O+CO,NH+NON2O+HN2ON23NOV3.1:,70%75%(80%),,A1,,,NOV,NOV,(OFA(OverFireAir)),,A1NOV,,40%50%3.2A1NOV,;15%20%,A1,NOV,,,NOV50%,NOV15%20%,3%CO,,,,,,3.3NOVCHiH2CCnHm,NO,80%85%,3.4,,,,15%20%,NOV25%4,,SO2NOV,,,NOV,NOV,,,:[1].[M].:,2000.[2].[M].:,1985.[3].NOV[J].,2000(11):34-38.[4].[M].,1992.[5].NOV[M].:,1993.61200312