费托合成催化剂载体的研究进展

31320087COALCONVERSIONVol.31No.3Jul.20081);2);3),,100013:2008204209;:20082052151)2)1)3).,,.,,,,TQ426.6,TQ529.20,,,..[1],,.Fe,Co,Ni,RuRh,.[2],FeCo,:,,,,,,,.F2T,.1,,Al2O3,SiO2,TiO2ZrO2.,,CO.SiO2,.,SiO2,.,,,C5+,,Khodakov[3].,,CO,C5+A,,,,,.[4][5],degussaA300degussaR106,,,,,,C5C18,.,,;,SiO2.[6]Al2O3,,,,Al2O3,.Al2O3SiO2,Co3O4SiO2;,Co3O4Al2O3,CoAl2O4[7,8],,.,.CeO2,CoöAl2O3,,,[9];Pt,RuPd,Co3O4Al2O3,C5+[10];,CO,[11];Al2O3,C5+[12];Al2O3SiO2,,,.[13]TiO2,,TiO2,Co,Co,C5+,TiO2,.ZrO2,,,,.ZrO2,.,Ar,H2COCo2ZrO2,ArCO,400500ZrO2,600;500;H2,400,600,ZrO2.[14]ZrO2,,,,CO,m2CZt2CZ,t2CZ;CO,CHx,m2CZ,H2Co,CO.[15]CoöZrO2,,,,.,ZrO2,,.ZrO2.ZrO2.2(1000m2ög),,,(2nm50nm);,,.,.,,,,COH2;,,.,,,,C5+.Y,ZSM25,,.Anderson[16218]ZSM25,.[19]HMS,,CoöHMS,,,Co3O4,393.,,.[20]SPAO211,,,,,.[21]MSU21,SBA212HMS,MSU21SBA212(C19+),,HMS.[22]HMS,.,COC5+HMS.3.(AC),Co,,,.[23],,,.[24]La2O3ZrCo,,.,,,,,,.[25][26](CNTs),COC24.,C5+,,.4SiC.SiC,,,.[27]SiC,,,.,.,,CO,,,.5.,,.,.,,;,.,.,.[1],,.[J].,2004,27(2):80284.[2],,.[M].:,2003.[3]KhodakovAY,ConstantAG,BecharaRetal.PoreSizeEffectsinFischer2TropschSynthesisoverCobalt2suppoetedMesoporousSilicas[J].JCatal,2002,206:230.[4],,.2CoöSiO2[J].,2000,21(2):1692171.[5],,.F2T[J].,2004,27(3):39243.[6],,.CoöRuöSiO2[J].,2006,34(3):3432347.[7]IglesiaE,SoledSL,BaumgartnerJEetal.SynthesisandCatalyticPropertiesofEggshellCobaltCatalystsfortheF2TSyn2thesis[J].JCatal,1995,153:108.492008[8],,.F2T[J].,2001,22(3):2752278.[9],,.CeO2CoöAl2O3F2T[J].,2001,22(2):1042107.[10],,.Pt,RuPdF2TCoöC2Al2O3[J].,2005,26(9):7802784.[11],,.F2TCOöAl2O3[J].,2002,18(3):2602263.[12],,.[J].,2003,24(2):3012304.[13]ZhangYi,MasahikoK,NoritatsuT.PreparationofAlumina2silicaBimodalPoreCatalystsforFischer2TropschSynthesis[J].CatalysisLetters,2005,91(324):1932198.[14],,.Co2ZrO2[J].,2006,22(11):140421408.[15],,.ZrO2CoCO+H2[J].,2005,26(3):9022906.[16]AndersonRB.TheFischer2TropschSynthesis[J].NewYork:AcademicPress,1984:1.[17]LeendertBG,BitterJH,Kuipers2HermanPCEetal.CobaltParticleSizeEffectsintheFischer2TropschReactionStudiedwithCarbonNanofiberSupportedCatalysts[J].JournaloftheAmericanChemicalSociety,2006,128(1ö2):395623964.[18]YatesIC,SatterfieldCN.IntrinsicoftheFischer2TropschSynthesisonaCobaltCatalyst[J].Energy&Fuels,1991,5:1682173.[19],,.CoöHMSCoöSiO22[J].,2005,26(4):3292334.[20],.SAPO211[J].,2006,10(3):1422145.[21],,.F2T[J].,2002,23(9):174821752.[22],,.HMS2HMS[J].,2002,23(2):1182120.[23]LeendertBG,BitterJH,Kuipers2HermanPCEetal.CobaltParticleSizeEffectsintheFischer2TropschReactionStudiedwithCarbonNanofiberSupportedCatalysts[J].JournaloftheAmericanChemicalSociety,2006,128(1ö2):395623964.[24],,.F2T[J].,2002,25(2):38242.[25]GuoDengzhu,XueZengquan.SynthesisofMethaneinNanotubeChannelsbyaFlash[J].JACS,2006,128:15102215103.[26],,.Co2Cu[J].,2005,44(4):4452449.[27],.[J].,2005,13(7):60264.RESEARCHPROGRESSOFCARRIERSFORFISCHER-TROPSCHSYNTHESISCATALYSTSXuZhengangLuoWeiWangNaijiandXiaoCuiwei(BeijingResearchInsitituteofCoalChemistry,ChinaCoalResearchInstitute,100013Bejing)ABSTRACTThecurrentresearchstatusofFischer2Tropschsynthesiscatalystsandthefunctionofcarriersarereviewed.Particularattentionispaidtotheinfluenceofaperture,specificsurfacearea,surfaceacidity,mechanicalstrength,thermalstabilityonthecatalyticactivity,longevityandselectivitycontrolinthepreparationofF2Tcatalysts.ThefunctionandofcarriersforFischer2Tropschsynthesiscatalystsisalsoanalyzed,somesuggestionstostudythecatalystsinthefuturearealsogiven.KEYWORDScatalystcarriers,F2Tsynthesis,metaloxide,zeolite,porestructure593