表面_界面的作用与粘接机理_一_潘慧铭

()2)3,24(:,,,()(,51)),,,,,,,T30.1A10015922(3)-,(),,11.,,,,(),(,)mNm,,rnJm2,,(),(L)()(V),/yL,7:2,40(),,7sL()ys,:7=,S+(:75),(ll),GGirico,:75:=7:+2(:s)/,(l2),:4(::)/,(75+7:Neu~,(l3)[z]:10.0075(14)shellNauman():(::l0.015(757:)(l5)/:2(X)20716:,,,3.2),,,,,,()()():+(l6)Owens,,,,:,2=7,+22(7,Zd),2(:72p)/,(l7)wkes,,,(),[]:7,2;+2(7ld+72),(ls),:7sL=7+2(75d)/2(l9)(),;1.2,,,,](11)W,s,,7sH,,,0,0ss(A)(B)9.12D6teined11eJoftliquconetane12,:7eososw=75()(l11),coswsH()(l12),,()1.3(),():J(,)(18),(),,7:%2,,,(l8)7,dY,r..=(9.11IaeStateofIiquiddroPonsueeofsolid117+yZrZ2%p=%d(l13)(l14)eoss(110),(),,,Halllilton,(,1ZA)()[,,1ZBH(),,Zismans],s.w7grand,[,()wkes,,,d7J41()NJIEZ,24(0(19)(110):,+90)(l16),d=[,:+(1+9)2IL(115)(113),J:,:(7:=30.7mNm)(7:=sl.omNm)(NRAAM)(NR)ys1l[Tab.,1ys11vajuesofgraffcopenlersyemJm2O,49”26”11”62930302829292930306.7,l,28292930302929NRNRAM5.NRAAM11NRAM18NRAAM26NRAM3NRAAM8NRAM14NRAAM2030.330.9O2046””„,2829302929505029305859605756595758205618128517161510:NRAA55%M,,EVA,,:,75,()(13A),d7512.12sdvaluesofsolidrrtenals(A)(B)(A)(B)(A),21mJmy(A)(A)sd/m2!.4187451.91.442.5,,,4}3117093.:(A),(B)d.7ycosos+cosess2[(7),(7)/,}(116):7,7=27.1mNm;y,718.4mNm1;7;,sl.3mNm;7,/50.lmNm;cosos;cosos42,(17)](17),p1.4,;1,,,,,F,2)3,(2)FsL=7:eoss(117),K_kcos(l18):h(),K2/981,p,R90,cosaM,,cosa,,,,,,(,),,(),,[]T.13Eeff.ofwettingeonadhesimstrength13://()/h,7/MPa70/()/30/V/10/301070//01.51.120.8620.7380.3507.80.57.90.78.20.460034.90578727361,t:_2:coso(l19):r,,L,tcoso,,/,//,/(,)(l3),,.5,,,[6J7+:7=7:(l+eoso)(l),(00o,cosa=l),=Zy:;(o=90,cooo=0),=y:;(8=1800,eoso=1),=0,,,,,73lmNm,54mNm,63,,/,(),,,,//(),(120),IVaw:ys,+(121)(18):ysysy,2(ysd7,d):+,2(y:y,J)(l21),(l22),(l23)(l9):=,2(d,)v,+(7,d),+(%dd)]7,[(d7,),+(d,d)U,+(dd),(43()N2.24{)O,;7(ys)(7d)/,+(ysJ:d),wo()/0,,,(110):s:7eosss(l25)L=:7,eos0L(126)(120):=(eosss+eoso:)(l27),0L900,,,,/,,(),(),,1.6,,Freundlich,,XC,16]:XocKC(l28):K,n,on1,()()()()3(14ABc)JlFig.13Sehematiediagramofad3orbingofPolymers131.:,As()m:A:=K(l29):K2.:,,()==KlnoK(l30)3.:,:A:Km(l31):oa1Mcren,FC(128),:F=A+BCm(132):ABmdeBruyne,2[91,,,,,,(,),(),a,(2)),(),,,(),,,()R.J.C,L.A.Gidfaleo.,J.Phys.ehem.,1960(64):5611.Skeists,HandbookOfAdhesives,ZndEd,NewJorsey,1977,3366D.K.Owens.,J.APPI.POlymer.Sci.,1970(14):1725F.M.Fowkos.,J..Chem.,]962(66):382..:,1997.38~40W.C.Harnilion;J.COlloid.Interfaee,Sci.,1972(40):219:1973(41):6727.,1987(3):448W.A.zisman,ContaetAngie,WettabilityandAdhesion,Am.ChemSoc.,1964.19S.Wu.,J.Colloid.Inteeesei.,1969(31):15310.,1983(l):311H.Pan,Adhesionscieneeandteehnology(EditedbyH.Mizumaehi),GoonandBreaeh,1997,6712H.Pan.,Adhesionseieneeandtechnolo(EditedbyH.Mizumachi),GoonandBreach,1197,5913.,1987(1):3415..1987(4):4216.(),:,1987.13017A.D.Melaren.,J.PolylnerSci.,1949(4):6318A.D.Melaon.,Mod.Plasties.,1954(31):11419N.A.deBne;J.Appl.Chem.,1956(6):303Eeffeetofsurface,interfaceandadhesionPrineiPle(I)PANHuimingHUANGSujuan(ResearchInstituteofMaterialsSeienee,SouthChinaUniversityofTeehnolo,Guanhou51(40)AbstractTheeffeetofsurfaeeandinterfaeehasavasteontributiononadhesionproeess.Theidueneeofwettingandadsorbingofmaterialsurfaeeandinterfaeeonadhesionareintrodueedinthisper.Itseontentin-eludesthesurfaeerensionandinterfaeetension,eontaetangle,determinationofsolidsueeene,wettingandwertingrate,adhesionworkandstabilityofadhesioninterfaee,andtheeontrastofadhesionandabsorption.KeywordsSurfaeeandinterfaeeSurfaeetensionWetting,Adhesion()