微波辅助湿式氧化处理对硝ahref=1基a酚溶液的研究

324E2005,35(3):324~336SCIENCEINCHINASer.EEngineering&MaterialsScience*(,116024)(PNP).,(218.61200mg/L)500W,6.4mL/min,4060mL/min90%,65%.0.2840.607.,.,[1~3],,[4,5].,129[6],1),.[1,7~10],(0~150mg/L),.[11~13][14,15].[16~19].(wetairoxidation,WAO)(catalyticwetairoxidation,CWAO)[20,21],,.(1m~1mm)(300MHz~300GHz)2003-12-22,2004-12-09*(:20337020)“863”(:2002AA649090)1)UKMOD.Defencestandardizationwebsite.:325“”,[22][23],[24][25]NOxSO2[26][27].:,;.Abramovitch[28]Tai[29,30][31],;[32],97.4%.Park[33][34][35],..,,,.,,;,,,,,,;,,,.11.1,,,,,Tedia,,.1.220,208~10%18h,2h,pH5~6,1058h,.1.31.(2450MHz,),,326E35SCIENCEINCHINASer.EEngineering&MaterialsScience11,2,3,4,5,6,7,8,9,10,11,12,13,141,152,16,17,18.,,.,.,,,,1,2,,.1.4,0.1mol/LNaOHpH6.42,pH,;200r/min24h[36],/(V-550,JASCO,),.1.50.100g20mL,4h(200r/min),,,GC-MS.1.6(HPLC)(PU-1580,UV-1575,JASCO,)3:327(250mm×4.6mm,5µmODS,Kromasil,),=0.60.4mL/min,280nm,25µL..(TOC)(TOC-VCPH,),.GC(HP6890)-MS(HP5973N),HP-5MS,30m×0.25mm×0.25µm.1mL/min.:4010min,15/min260,20min.260.NIST.(CODCr)(BOD5),.CODCrCOD(ZL92.243434.4),-,,,,CODCr;BOD5,,BOD5.22.12.1.1Ce(mg/L)q(mg/g),2.,Redlich-Peterson..2,Ce110mg/L,q290mg/g.45g,13.05g(110mg/L)(t=22),.2.1.2,,.45g12,84g,(PM)400W,(QS)10mL/min(QA)80mL/min,(C0)110mg/L.,(1,),,,3.328E35SCIENCEINCHINASer.EEngineering&MaterialsScience2pH=6.42,T=223C0=110mg/L,QS=10mL/min,QA=80mL/min,PM=400W3,45g12g,C0,,;4g,C0,,;8g150mg/L,C0,.,45g8gC0218.6mg/L(t=2214.9g);15g3:329(t=2220.4g).2.2218.6mg/L218.6mg/L62,,PM=500W,QS=6.4mL/minQA=40mL/min,4.(GC-MS),HPLC,4.4218.6mg/LPNP(a),(b)(a).C0=218.6mg/L,PM=500W,QS=6.4mL/min,QA=40mL/min330E35SCIENCEINCHINASer.EEngineering&MaterialsScience4(a),0~20minTOC,;20~40min,40min.,,(),20min,20min,,.4(b),80min,TOC,3h90%65%.5.,,500,,250~320[21],.52.31200mg/LPM=500W,QS=6.4mL/minQA=60mL/min,721200mg/L4,6.6(a),,,,,30min,,,.6(b),3.5h,TOC94%83%,.3:331(a),(b)(a).C0=1200mg/L,PM=500W,QS=6.4mL/min,QA=60mL/min2.4,.PE660W,2.3,7.,3h,TOC332E35SCIENCEINCHINASer.EEngineering&MaterialsScience7C0=1200mg/L,QS=6.4mL/min,QA=60mL/min,PM=500W,PE=660W,PNP;HPLC,.2.5GC-MS,GC-MS.,,.,3-[]-;3-[]-.(4(a)6(a)),.8.8(1),(2),(3),(4),(5)3-[]-3:333[]-,.pH(2.16)pH(6.41),.NO2−-N(N-(1-)-)NO3−-N().2.6CODCrBOD5,,1.BOD5COD,,.0.3,;0.7,.1,BOD5/CODCr0.284()0.607,,.91(C0=1200mg/L)CODCrBOD5a)CODCr/mg·L−11589.6745.2716.5BOD5/mg·L−1451.8452.2271.4BOD5/CODCr0.2840.6070.379a):QS=6.4mL/min,QA=60mL/min,PM=500W334E35SCIENCEINCHINASer.EEngineering&MaterialsScience.3()PM=500W,QS=6.4mL/min,QA=4060mL/minGAC,,3h90%65%.WAOCWAO,,,;(),.(),.,,98,;,,,.(),,3-[]-,.(),.1BhushanB,ChauhanA,SamantaSK,etal.Kineticsofbiodegradationofp-nitrophenolbydifferentbacteria.BiochemicalandBiophysicalResearchCommunications,2000,274:626~630[DOI]2BhattiZI,TodaH,FurukawaK.P-Nitrophenoldegradationbyactivatedsludgeattachedonnonwovens.WaterResearch,2002,36:1135~1142[DOI]3RogersKR,VanEmonJM.Immunoassayforp-Nitrophenolinurine.EPAReport1993,EPA/600/A-93/074,USA4SpainJC,vanVeldPA,MontiCA,etal.Comparisonofp-nitrophenolbiodegradationinfieldandlaboratorytestsyetems.AppliedandEnvironmentalMicrobiology,1984,48:944~9505ZaidiBR,ImamSH.Inoculationofmicroorganismstoenhancebiodegradationofphenoliccompoundsinindustrialwastewater:isolationandidentificationofthreeindigenousbacterialstrains.JournalofGeneralandAppliedMicrobiology,1996,42:249~2566USEnvironmentalProtectionAgencyWaterQualityCriteria.1976,USEnvironmentalProtectionAgency,WashingtonDC7LeungKT,TresseO,AerrampalliD,etal.Mineralizationofp-nitrophenolbypentachlorophenol-degradingSphingomonasspp.FEMSMicrobiologyLetters,1997,155:107~114[DOI]8HanneLF,KirkLL,AppelSM,etal.Degradationandinductionspecificityinactinomycetesthatdegradep-nitrophenol.AppliedandEnvironmentalMicrobiology,1993,59:3505~35089JainRK,DreisbachJH,SpainJC.Biodegradationofp-nitrophenolvia1,2,4-benzenetriolbyan3:335:3030~303210SpainJC,GbisonDT.Pathwayforbiodegradationofp-nitrophenolinaMoraxellasp.AppliedandEnvironmentalMicrobiology,1991,57:812~81911Moreno-CastiliaC,Rivera-UtriliaJ,Lpez-RamnMV,etal.Adsorptionofsomesubstitutedphenolsonactivatedcarbonsfromabituminouscoal.Carbon,1995,33:845~851[DOI]12ChernJM,ChienYW.Adsorptionofnitrophenolontoactivatedcarbon:isothermsandbreakthroughcurves.WaterResearch,2002,36:647~655[DOI]13ChernJM,ChienYW.Competitiveadsorptionofbenzoicacidandp-nitrophenolontoactivatedcarbon:isothermandbreakthroughcurves.WaterResearch,2003,37:2347~2356[DOI]14GadekarPT,MukkolathAV,TiwariKK.Recoveryofnitrophenolsfromaqueoussolutionsbyaliquidemulsionmembranesystem.SeparationScienceandTechnology,1992,27:427~44515TompkinsCJ,MichaelsAS,PerettiSW.Removalofp-nitrophenolfromaqueoussolutionbymembrane-supportedsolventextraction.JournalofMembraneScience,1992,75:277~292[DOI]16DieckmannMS,GrayKA.Acomparisonofthedegradationof4-nitrophenolviadirectandsensitizedphotocatalysisinTiO2slurries.WaterResearch,1996,30:1169~1183[DOI]17BandaraJ,KiwiJ,Pu