双氧水工作液中蒽醌的降解与再生-张涛

102710201510ChemicalＲesearchandApplicationVol．27No．10Oct．20151004-1656201510-1427-07*411105、、、、、、、、、。。、。O625．463ADegradationandregenerationofanthraquinoneinworkingsolutionofhydrogenperoxideZHANGTaoDUANZheng-kang*LIShengYANJian-huaXIEFanSchoolofChemicalEngineeringXiangtanUniversityxiangtan411105ChinaAbstractHydrogenperoxidewasanimportantinorganicchemicalmaterialsandfinechemicalproductsandwaswidelyusedinchemicaltextilepaperfoodpharmaceuticalmetallurgyelectronicsagriculturemilitaryenvironmentalprotectionandotherfields.Theanthraquinonewasrelativelymaturetechnologytobecometheworld'sleadingproducerofhydrogenperoxidemethod.Inthispaperthedegradationmechanismofeffectiveanthraquinoneinworkingsolutionwasperformedincludingthedegradationofhy-drogenationdegradationofoxidationanddegradationofsolventandthetotalfigureofdegradationproductsgeneratedwassup-posedtheregenerationmechanismofactivatedaluminaandlyewereintroducedtheresearchprogressinimprovementofregenera-tiveeffectofactivatedaluminainrecentyearswasreviewed．Keywordshydrogenperoxidedegradationactivatedaluminathemechanismofregenerationregenerationeffect、、、、、、、、。。1-3。、、、、。。。1、2015-03-262015-06-0114A1451964-。[e-mail]27。。。42-、2--2-。5-2--2-。Drelink-iewicz62-、、、2-、2-、-2-、-2-、-2--2-。7-8。-2-、-2-、-2--2-0.1%-0.5%。2-、-2-、2-、-2-、-2--、2--2-0.1%。2。2.12--2-。。β9。2-112-Fig.1ThereactionofdeephydrogenationofEAQ2.2Drelinkiewicz10。11。22Fig.2Themechanismofhydrogenationofcarbonyl8241102.3-2--2--2-PDMA33Fig.3Ｒeactionmechanismsofdegradationofoxidation2.4、。C975∶25。、12。44Fig.4Thereactionsofdegradationofeffectiveanthraquinone9241273、。、13。。。。、、。3.13.1.1KazuharuOgasawara14-2-55-2-Fig.5ThemechanismofregenerationofEPOXH4EAQＲeijoAksela153mol-2-1mol2-2mol-2-66-2-Fig.6TheconversionofH4EAQKeigoKamata162-2-772-Fig.7ThemechanismofregenerationofEANT3.1.2Drelinkiewicz17。2--2-2--2-882--2-Fig.8ThemechanismofregenerationofEANOHandH4EANOH034110MarcinLukasiewicz182-2-992-Fig.9ThemechanismofregenerationofEAN3.2、、。。OH19。3.3。、。Pd、Pd-C、Pt、NiAl2O3I、II。20。。3.4。。。1、。2、。3、。4、21。。4。。4.12220%MgCl230℃36hpH10-1230h500℃40h。。Veronique23。Hiroshi24pH=10pH=7.1-7.530min。2-pH。Drelinkiewicz25Na2SiO3。26100。4.2Aksela15。。。13412724.3%。27。N210min-30min60℃-80℃。10812g·L－1。28。9g·L－130。290.1mol·L－15∶180℃10min60℃。。4.330500℃-600℃。50-150N/6-202-35.81%-7.01%。31NN-5%2h40℃-50℃。3.61g·L－1。。32。93%-97%75nm5%0.42ml·g－150-100。。60℃。10g·L－10.3%。33。400℃-700℃3h-5h。5.73g·L－1119.9N。34。3g·L－1-20g·L－1。5。。、。。1．-J．2014138-41．2．J．2014229701-704．3．1-J．201325121746-1748．4．J．2010821-4．2341105．-J．201433111286-1289．6DrelinkiewiczA．Kineticaspectsintheselectivityofdeephydrogenationof2-ethylanthraquinoneoverPd/SiO2J．MolCatalAchem1995101161-74．7．P．CN201210210793．02012-10-03．8．J．2014304485-488．9．J．20132184-7．10DrelinkiewiczA．Investigationof2-ethylanthraquinonedegradationonpalladiumcatalystsJ．MolCatalAChemical2006246167-175．11DrelinkiewiczA．2-EthylanthraquinonehydrogenationonPd/Al2O3theeffectofwaterandNaOHonthedegrada-tionprocessJ．AppliedCatalysisAGeneral200528459-67．12．H2O2J．201531172-77．13．J．20111145-46．14OgasawaraKMinatoKKatoK．ＲegenerationmethodofworkingsolutionP．US8296961999-02-02．15EspooＲAKiviniemiJP．Ｒegenerationofaworkingso-lutioninahydrogenperoxideproductionprocessP．US01817412003-09-25．16KamataKKasaiJYamaguchiKMizunoN．EfficientheterogeneousoxidationofalkylareneswithmolecularoxygenJ．OrgLett200463577-3580．17DrelinkiewiczA．Hydrogenationof2-ethyl-910-anthra-quinoneonPd/SiO2catalyststheroleofhumidityinthetransformationofhydroquinoneformJ．MolCatalAChem20062581-9．18LukasiewiczMBogdalDPielichowskiJ．Microwaveas-sistedoxidationofsomearomaticsbyhydrogenperoxideatsupportedtungstencatalystJ．MolDivers200610491-493．19．J．2004237691-695．20．J．200840124-7．21．J．201544348-50．22．P．CN200810132332．X2008-07-11．23VeroniqueDClaudeV．ProcessforthemanufactureofhydrogenperoxideP．US53426031994-04-15．24HasegawaHIuraKHagiwaraIetal．Methodforactiva-tinghydrogenationcatalystmethodforproducinghydro-genperoxideincludingsameP．US78335102010-11-16．25DrelinkiewiezAKangasP．Hydrogenationof2-ethylan-thraquinoneoverPd/SiO2andPd/Al2O3inthefixed-bedreactortheeffectofthetypeofthesupportJ．CatalLett200494157-168．26．P．CN201310736807．72014-04-09．27．P．CN201210439954．32014-05-21．28．P．CN201210440126．12014-05-21．29．P．CN201010227561．72010-11-24．30．P．CN201110085762．22012-10-17．31．P．CN201410097020．52014-06-25．32．P．CN200810246589．82009-06-17．33．P．CN20141009092．52014-06-25．34．P．CN200810060449．12009-10-14．3341