有机化学课后答案第四章碳碳重键的加成

第四章碳碳重键的加成1．完成下列反应（1）BrHBr+H3CH3CCH2（2）CH3CH=CCH3CH3HClOCH3CH-CCH3CH3ClOH+（3）CH3CH=C-CH2CH3CH3Br2CCl4CH3CH-C-CH2CH3BrBrCH3+（4）（5）(CH3)2C=CH-CH2CH2CCCH3Br(CH3)2C-CH2-CH2CH2CCCH3Br+（6）(CH3)2C=CH-CH2CH2CCCH3Br2(CH3)2C-CH2-CH2CH2CCCH3Br+（7）CH3CH2CH2CCHCH3CH2-CH2-CO-CH3OH2HgSO4H2SO4+（8）CH3CH2CH2CCHB2H6H2O2CH3CH2CH2CH2CHOOH-OH2+1/2CH3CCHICH3-C=CH2I+(1mol)（9）CH3CH2CCH3H2CH3CH2CH3HHPd-BaSO4+吡啶（10）CH3CH2CCH3H2CH3CH2CH3HHNaNH3+(l)(11)CH3(1)B2H6CH3OHOH-/H2O(12)CH3B2H6H2O2OH-/H2OCH3OHOH+(13)CH3-CH=CH-CH2CH3CH31)O32)Zn-H2OCH3-CO-CH3CH3CH2CHO+(14)CH3CH2CCH1)O32)Zn-H2OCH3CH2COOHCO2OH2++(15)O2AgO+1/2△(16)1)O32)Zn-H2OOOHHHOC-COH+2(17)CH3IHCH3CH2CH-CH3I+(18)CH3CH3CH3CH3BrBrBrCH3BrCH2CH3BrCH2Brbaa+b+2.写出下列反应的主要产物（1）CH2=CC=CH2CH3CH3COOHCOOHCOOHCOOH+△（2）CH=CHCH3CH=CH2OOOOCH3OO+△（3）CH3CH3+（4）CH2=CH-CNCN+（5）Pd-BaSO4CHCH2=CH-CH2CNi/H2CH2=CH-CH2C=CH2CH3-CH2-CH2-CH2-CH3吡啶（6）CH3-CH=CH-CH=CH-CH3Br245℃CH3-CH-C=CH-CH-CH3BrBr+(1mol)（7）CH3CH=CHCHCBrHCH3CHCH-CCHHBr+(1mol)11．比较下列各组碳正离子的稳定性CH3-C-CH2CH3CH3+CH3-C-CHCH3CH3HCH3-CH-CH2CH2CH3(1)++CH3-CH=CH-CH-CH3+CH3CH2-CH-CH=CH2CH2-CH=CH-CH2CH3(2)++CH3CH2CHCH=CH2CH3CHCH2CH=CH2CH2CH2CH2CH=CH2(3)+++CH3-C-CH2ClCH3CH3-C-CHCl2CH3CH3-C-CCl3CH3(4)+++19．选用四个及四个碳以下的有机化合物为原料合成下列化合物OCH3OCH3(1)+CNCNCNClClCCl4Cl2(2)+△