生物质制取液体燃料技术发展趋势与分析

©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[]2004-06-14;2004-09-13[](1975-),,,,,,(,230026)[]4;,;;[];;[]TK6[]A[]1009-1742(2005)04-0005-061,,,2005,2010,2020110108,115108215108t,35%,45%54%,(),8108t,30EJ(1EJ=11018J),,,,250104t,112210,,,4,2(fastpyrolysis)(103104K/s)(0151s)(500),,,(),[1]5kg/h420525,,CO2,,70%[2],,,550,0138mm,018s,63%[3],,1000©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[4]Aston,(t600)(v112m/s)7716%,[5]laval,450,15kPa,35%[6],,600,67%[7]20MJ/kg,,(w(O)40%),,,,(),(),,,,[4,5,7],,,,[1],CO2,CO2,ZnCl2,,[8][9],,,,,,,,,,,,[10],,,,,,,,,33MJ/kg,116[11],,,,,,3(liquefaction)2:(),250400;(15MPa)(),(H2CO),,20%,35%70%,40MJ/kgS.A.Rezzoug[12],(150280)(2060min)(w67©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.=0115%,,),,,,250w=017%A.Demirbas[13]9,,575K,(w(KOH)012),3112%,6317%,Sid2AhmedRezzoug[14]:100g400g,1g,250;,FeNiMoCoMo,(3MPa6MPa9MPa),,6MPa,NiMo,350,31,2%,41106MJ/kg,,,,,,,,;,S.Sawayama[15]300350,0111h,Na2CO3(w(Na2CO3)05%),,()64%,4519MJ/kg,()48%,2310MJ/kgGinburgB.Z.[16]Y.Dote[17]300Na2CO310MP,64%,T.Minwowa[18]340,1h,,36MJ/kg,,,,,K.Yamaberi[19],,[20],314,,,,,,,,,4(supercriticalextrac2tion),,,,GoudriaanF.[21],,,46%,10%MustafaCemek[22]ZnCl2(w(ZnCl2)=10%),573K,,5515%6016%AtilaCaglar[23],491K2219%74:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[24],,583K,,,6310%,w=10%NaOH,,,8414%,,,,,5(biotechnology),,2,,,,[25],80%,5%,90%[26],,0105%0106%018%0104%,310,60%,2224,9,4118%3,,,,720kg200L[27],[28]Iogen,,[29],Arkenol,,400104gal(15106L),,,2500104gal(95106L),,400104gal(15106L)ArcherDanielsMidland,[30]BCInternational9000,,76106L,[29],,,,,,,,,,,,,,,,6,,87©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(),,,,,,,,,,,,,,,,(),,,,,,,[1],,,.[J].,2002,23(4):462466[2],,.[J].,2000,16(3):263269[3],,.[J].,1999,17(5):7174[4]WagenaarBM.Therotatingconereactorforrapidsolidsprocessing[D].TheNetherlands:UniversityofTwent[5]BridgwaterAV,PeacokeGVC.Fastpyrolysisprocessforbiomass[J].RenewableandsustainableEnergyReview,2000,(4):173[6]LemieuxR,RoyC,CaumiadeB,etal.Preliminaryengineeringdataforscaleupofabiomassvacuumpyrolysisreactor[J].ACSpreprints(Divoffuelchem),1987,32(2):1220[7]DieboldJ,ScahillJ.Productionofprimaryoilsinavortexreactor[J].ACSpreprints(Divoffuelchem),1987,32(2):2128[8],,,.[J].,2001,(8):1317[9],,.[J].,2001,3(4):6367[10],,,.[J].,2002,23(1):410[11],.[J].,2003,(3):1316[12]RezzougSA,CapartR.Assessmentofwoodliquefactioninacidifiedethyleneglycolusingexperimentaldesignmethodology[J].EnergyconversionandManagement,2003,44:781792[13]DemirbasA.Effectoflignincontentonaqueousliquefactionproductsofbiomass[J].EnergyConversion&Management,2000,41:16011607[14]RezzougSid2Ahmed,CapartR.Liquefactionofwoodintwosuccessivesteps:solvolysisinethylene2glycolandcatalytichydrotreatment[J].AppliedEnergy,2003,72:631644[15]SawayamaS,MinowaT,YokoyamaS2Y.PossibilityofrenewableenergyproductionandCO2mitigationbythermochemicalliquefactionofmicroalgae[J].BiomassandBioenergy,199917(1):3339[16]GinburgBZ.liquidfuel(oil)fromhalophilicalgae:arenewableresourceofnon2pollutionenergy[J].RenewableEnergy,1993,23(3):249252[17]DoteY,SawayamaS,InoueS,etal.Recoveryofliquidfuelfromhydrocarbon2richmicroalgaebythermochemicalliquefaction[J].Fuel,1994,73(12):18551857[18]MinowaT,YokoyamaS,KishimotoM,etal.OilproductionfromalgalcellsofDunaliellatertiolectaby94:©1994-2010ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[J].Fuel,1995,74(12):17351738[19]YamaberiK,TakagiM,YoshidaT.Nitrogendepletionforintracellulartriglycerideaccumulationtoenhanceliquefactionyieldofmarinemicroalgalcellsintoafueloil[J].Biotechnol,1998,(6):4448[20],,,.[J].,2000,1(3):2428[21]GoudriaanF,PeferoenDG.Liquidfuelsfrombiomassviaahydrothermalprocess[J].ChemicalengineeringScience,1990,45(8):27292734[22]CemekM,KucukMM.LiquidproductsfromVerbascumstalkbysupercriticalfluidextraction[J].EnergyConversion&Management,2001,42:125130[23]CaglarA,DemirbasA.Conversionofcottoncocoonshelltoliquidproductsbysupercriticalfluidextractionandlowpressurepyrolysisinthepresenceofalkalis[J].EnergyConversionandManagement,2001,42:10951104[24]DemirbasA.Liquefactionofolivehuskbysupercriticalfluidextraction[J].EnergyConversion&Management,2000,41:18751883[25].[J].,1996,(4):37[26],,.[J].,2003,19(4):278281[27],.[J].,1997,(1):2228[28],,,.[J].(),2000,26(1):5660[29],.[M].:,2003.194194[30].[N].,2001-06-11AnOverviewofTechnologyforLiquidFuelFromBiomassZhengJilu,ZhuXifeng,GuoQingxiang,ZhuQingshi(BiomassCleanEnergyLaboratory,UniversityofScienceandTechnologyofChina,Hefei230026,China)[Abstract]Fourkindsoftechnologyforliquidfuelfrombiomass,togetherwiththeirprinciplesandprocedures,arenarrated.Thepaperismainlyconcernedaboutnewtendencyinallkindsoftechnologyforliquidfuel,forexampleselectivef