氢化丁腈橡胶的研究进展

27220064SpecialPurposeRubberProductsVol.27No.2April2006,,(,510640):(HNBR)、、、。:;;:TQ333.7:A:1005-4030(2006)02-0056-06:2005-11-25:(1981-),,,。,、、。,,,120℃;,、,[1]。,。,、、,,,[2]。(HNBR)。1(HNBR)Bayer。1982BayerTherban,Therban17071907,34%38%,Therban1707s,1907s2207[3]。(Zeon)1970HNBR[4],1978、,1980,19844,Zetpol;19955300/[5]。Polysar2070HNBR,1985,198811Or-ange,1600/,Tor-nac。1991,BayerPolysar。,BayerTherban,3000/[6]。HNBR。1992,NBR;,HNBR[7]。1999,:LH-9901,LH-9902[8]。,HNBR2.2/,Bayer(1.0/),Zeon(1.2/)[9]。2HNBR3:NBR、NBR-[10]。2.1NBRNBR。NBR,,、,,,NBR,,-C8N。(Pd)、(Rh)、Ⅷ[11]。200657Pd/C,,95.6%。,,HNBR,。SiO2Pd/SiO2,。2NBR,NBR,,。3[3]:、。[Pd(OAc)2]3,,,,,;NBR,,,,;PhCl(PPh3)3,95%。,,。HNBR81%。,、,。2.2NBRNBRNBRHNBR。2,WilkinsonNBR。Wilkinson()。SinghaWilkinsonNBR,75℃,12h,60%HNBR,。,,。WilkinsonNBR,,,,,,。,,Cu2+。1984WideManHNBR,NBR、、HNBR。Good-YearParKerHNBR,():NBR,100;CuSO4·5H2O,0.008;,0.15;,,15.6;H2O,216.66。:NBR、CuSO4·5H2O,45℃～50℃,,7hH2O,,1hHNBR。:,,;,;,;,,;HNBR。:,,。NBR,Oline,JSR。NBR,HNBR,,,。2.3--(r=0.04,r=0.8),,、,,。HNBR,,:、HNBRHNBR(PZ-MA),(ZSC)。50～60MPa,[12]。3HNBR3.1[13!17]。NBR,[13]:,,582729CH2::;;CHCHCH2L9CH::2CHm9CH::2==CHCH;;2CH::n==CNH2):::NBR9CH2::;;CHCHCH2L'9CH::2CH::2CH::2CH2L9CH::2CHm9CH::2CH==2CH::3CH::n==CNHNBR。,、;,、、,,;,,。HNBR1。1HNBRCH::2::CH==::CN,,-CH2-CH2-CH2-CH2-,,,CH::2::::CHCH==2CH::3,CH::2::;;CHCHCH::::2,3.2HNBR3.2.1HNBR,,NBR,。N.Sandland[18],12。1,2,(NBR)、(CSM)、(CR)(150℃),HNBR;180℃1000h,HNBR(ACM)[19],80%,,HNBR1000h,150℃,NBRCR106℃101℃[20]。1150℃×70h,2150℃3.2.23,HNBR30MPa,(FKM),NBR,CSM,ZSC50MPa。150℃Zetpol2010(FKM)(TFE/P),NBR150℃[18]。,HNBR370200659。HNBRNBR,FKM150℃,22～33～4[20]。3.2.3HNBR、、、,4[20]。/,:5%H2S,20%CO2,75%CH4;:95%,4%,1%。4,FKM,TFE/P,NBR/2,HNBR。HNBR1000h,,[21,22]。43.2.4HNBRNBR,7℃～10℃。NBR,,。HNBR,()。34%,,。,,。TR(:ASTMD1329)(5)。34%,,TR10,,40%,,TR10。HNBR。HNBR(2),[23]。5TR102HNBR102020202010200031104110,%443636362517,g/100g24282841515100℃787878859590,℃-24-31-29-28-35-453.2.5HNBRFKM,NBR,,。HNBR,。,HNBR,,。,,。,HNBR。HNBRHNBR,HN-BRHNBR。,,。,HNBR[8]。,HN-BR(oxazo-line)[24],HNBR41%[25]。4HNBR4.1,,HNBR。HNBR60272,,(Tg),。HNBR,,HNBR、。,Zetpol3110Zetpol2010Zetpol。4.2HNBR,-1%,Zetpol2000,2000LTher-ban1760,1770,1970,2207,,.5%,。HNBRHN-BR,、。Vul-cup40KE,PeroximonF-40,HAV-2(),TAIC(),TMPT(),。DCP()BD-PMH[2,5--2,5()],TAIC。HNBR,。BDPMH4～7,TAIC4,20%[26]。,HNBR,,。4.3HNBRNBR,(,,CaCO3,TiO2)。,。:..,[27]。,ZeonZnO/MMA3:4HNBR---ZSC,60MPa,、,。,ZnO/MMA,HN-BR。2nm(ZD-MA)20～30nm,HNBR,。4.4HNBR,,。HNBR,-40℃～150℃,、。,。HNBR150℃×160h,TR10[28],TOTM()TINTM(),。,DOP()DOS(),。HNBR,,,。ThiokolTP-95[()],G8205(1000～2000),AdiksizerC-9N,C-8()[29]。4.5HNBR,RD/MBMB/445。,,。5HNBR5.1NBR,,。NBR,。HNBRCR,30℃,HNBR、、,,,。,HN-BR。HNBR,。200661、、、,,HNBR(NBR,,),HNBR、。5.2、、O,R-12R-134a,HNBR2。HNBRTR10-35℃～-40℃,50%～60%,、,、、O。,,,。,NBR。H2S,CO2,,,、。,HNBR、、、、、、、、。HNBR、、、,,。5.3HNBR,,。ZSC,,JIS-A90,,,,、,,,,[30]。5.4,HNBR、、。,HNBRHNBR。HNBR、、、、、、,、。,,HN-BR。HNBRABS/PVC。ABS/PVCHNBR,。(PVC)、(EVA)HNBR,PVC,EVA,HNBR[31]。HNBR、、,,、,PVC/HNBR[32];HNBR/PC,,[33];EPDMHNBR[34]。HNBR。620、,、。HNBR,,,,,,HNBR,HNBR。:[1],.[J].,2004,27(6):360～362.[2].[J].,2001,11(4):27～32.[3].(HNBR)[J].,1998,28(11):19～24.[4].HNBR[J].,1998,28(11):1～6.[5].[J].,1996.26(1):12～16.[6].HNBR[J].,1998,28(11):31～38.[7].HNBR/[J].,2000,30(7):26～29.[8].HNBR[J].,2002,49(4):215～221.[9].[J].,2005,33(2):5～7.62272[10].[J].,2002,17(3):61～62.[11].NBR[J].,2002,75(5):207～209.[12].HNBR/[J].,2000,30(7):26～28.[13].[J].,1993,69(9):653.[14].NBRZeoforteZSC[J].,1991,28(8):53.[15]HAYASHIS.Lowtemperaturepropertiesofhydrogena-tednitrilerubber[J].RubberChemistryandTechnology,1991,64(4):534.[16]ThormerJ.Crosslinkingsystemeffectonprocessingbe-haviorandperformanceprofileofHNBR[J].Rubberworld,1989,201(2):25.[17].---(HNBR)[J].,2001,22(3):18～20.[18]SandlandN,HarrisS,NakajimaK.HydrogenatedNBR(HNBR)inpowersteeringhose[J].Polymer&PolymerComposites,1997,5(8):555～561.[19].[J].,1992,39(10):628～633.[20]HashimotoK,TodanioY.HandbookofElastomers[M].NewYork:MarcelDekkerInc.,1988.741～757.[21]NakagawaT,ToyaT.Ozoneresistanceofhighlysaturat-ednitrilerubber(HNBR)[J].JornalofElastomersandPlastics,1992,24(3):240～261.[22],.[J].,2001,22(2):54～57.[23],.[J].,1996,4(2):31～34.[24]FultonJ.Adductsofanaminoalcoholandnitrilerubber[P].U.S.Pat:4879352,1989.[25]BrownT.Fibrereinforcedbelt[P].USPat:5051299,1991.[26]DunnJR,BlackshowGC,TimarJ.CompressionsetandsealingforceretentionofHNBR[J].Elastomerics,1986,118(12):20～25.[27].[J].,1992,12(1):13～17.[28]KlingenderRC.Low-temperaturepropertiesofhydro-genatednitrilerubber(HNBR)[J].RubberChemTechn-ol,1991,64(4):534～543.[29].[J].,1995,42(6):342～344.[30].[J].,1995,18(1):43～46.[31],.HNBR[J].,1996,19(4):252～254.[32]ManojNR,DePP.Hotairandfuelagingofpoly(vinylchloride)/nitrilerubber[J].PolymerDegradationandSta-bility,1994,44(1):43～47.[33]ChoudhuryNR,BhowmickAK.Thermostableinsulatingthermoplasticelastomersfromrubberpolycarbonateblends[J].JornalofElastomersandPlastics,1996,28(2):161～168.[34].[J].,1998,8(3):43～48.TheStudyofHydrogenatedAcrylonitrile-ButadieneRubberYUQuan,HUANGCheng-ya,YESu-juan(SouthChinaUniversityofTechnology,Guangzhou510640,China)Abstract:Thedevelopmentofhydrogenatedacrylonitrile-butadienerubb