超疏水性材料表面的制备_应用和相关理论研究的新进展

:(2007BS04007);;:(1984-),,;*,Tel:[phone];Email:[e-mail].范治平1,魏增江1,田冬1,肖成龙1,孙晓玲1,陈承来2,刘伟良1*(1.山东轻工业学院材料科学与工程学院,玻璃与功能陶瓷加工与测试技术山东省重点实验室,济南250353;2.山东省聊城水文局,聊城252055):WenzelCassie,;;,:;;;;150,,,,,,1超疏水理论进展,[1],s,g=s,l+g,lcos(1)(1)s,gs,lg,lWenzel[2,3],,,Wenzel:cos=r(s,g-s,l)/g,l(2)(2):r=/,cos=rcos,r1,Wenzel,Cassie[4]:,180,,:cos=f1cos-f2(3),f1f2Cassie[4],,i:cos=a1cosl+a2cos2(4)ai,a1+a2=1!105!11,,,,Furmidge[5]:mgsin=k!lv(cosr-cosa)m,g,k,!,ar,lv,,,,Restagno[6],,,,,,2超疏水表面的制备方法,,2.1Fang[9],,,,168.3Shi[10],/,62%,168Chen[12],,,156,Kiyoharu[11],,,pH55~80;,,,,2.2Xue[14](VSiOxNPs),150~1600nm,,,,Chen[15],,,150,4,Nystrom[13](ATRP),,,ATRP,,ATRP,,,23Hou[7],!106!201011,,,,2.4Wu[8],Cu[CH3(CH2)10COO]2,,,,,,,2.5Xi[16],0.08A/cm2,15357.9Chen[15],,,,,2.6Chen[17],,154,7,pH113,,,,2.7[18],(MMT)MgCl2,ZieglerNattaTiCl4MgCl2MMT,ZieglerNatta∀#,,(152.2∃0.8),,,2.8[20],,,[19]pH,95%∀#,/,,2.9[21],,,,160,pH,2.10[22]/,,,TiO2,1545,2.1,,2.11[23],,,157,92.3%,2.12[24]ZnO,,!107!11,(1601),53超疏水表面的功能性应用,,3.1[25]Nosonovsky[26],,(1),,,;[27],1∀#0,,;1,,;K,x,Fm[25]Figure1A∀capillaryengine#thatconvertsthechangeofthesurfaceenergyintothemechanicalenergyInthe0state,thesurfaceenergyishighenoughtoformameniscus,andthemeniscusforcedeflectsthetip.Inthe1state,thesurfaceenergyislower,themeniscusisdestroyedandthetipisreturnedtoitsequilibriumposition.Krepresentsspringconstant,andxrepresentstheverticaldisplacementandFmrepresentsthemeniscusforce.[25]3.2,,,,,,Tuteja[28],,3.3,,,,,,,,Shen[29],3.4,,Wang[30]/,,!108!201011∀#,,,,,,[35]3.5Xi[16],,Liu[31](),,,,,3.6Lifton[32],,,,,,,[33]3.7,,Ma[34],4展望,,,,,;,,,,,参考文献:[1]YoungT.PhilTransRSocLond,1805,95:65~87.[2]RobertN,Wenzel.IndEngChem,1936,28:988~994.[3]RobertN,Wenzel.JPhysChem,1949,53:1466~1467.[4]CassieABD.,BaxterS.TransFaradaySoc,1944,40:546~551.[5]FurmidgeCGL.ColloidSci,1962,17:309~324.[6]RestagnoF,PoulardC,CohenC,VagharchakianL,LegerL.Langmuir,2009,25(18):11188~11196.[7]HouW,WangQ.JColloidInterfaceSci,2009,333:400~403.[8]WuW,WangX,LiuX.ApplMaterInterfaces,2009,1(8):1656~1661.[9]FangX,YuZ.FrontChemEngChina,2009,3(1):97~101.[10]ShiM,XiJ,WangH.JAdhesSciTechnol,2008,22:311~318.[11]TadanagaK,YamaguchiN,MatsudaA.JAdhesSciTechnol,2008,22:387~394.[12]ChenY,ChangK,WuK.ApplSurfSci,2009,255:86348642.[13]NystromD,LindqvistJ.ApplMaterInterfaces,2009,1(4)?:816~823.!109!11[14]XueLJ,LiJ,FuJ.ColloidsSurfA,2009,338:15~19.[15]ChenLJ,ChenM,ZhouHD.ApplSurfSci,2008,255:3459~3462.[16]XiWJ,QiaoZM,ZhuCL.ApplSurfSci,2009,255:4836~4839.[17]ChenH,YuanZQ,ZhangJD.JPorousMater,2009,16:447~451.[18],,.,2008,29,1:1~3.[19],,.,2008,29,2:14~17.[20],,.,2009,6:29~30.[21],,.,2009,30:137l~l374.[22],,.,2009,30:731~734.[23],,.,2008,5:43~47.[24],,.,2008,11:1906~1908.[25]BhushanB,LingX.JPhysCondensMatter,2008,20:485009.[26]NosonovskyM,BhushanB.JAdhesSciTechnol,2008,22:2105~2115.[27]BhushanB,LingX.JColloidInterfaceSci,2009,329:196~201.[28]TutejaA,ChoiW,MabriJM,McKinleyGH,CohenRE.ProcNatlAcadSci,2008,105:18200~18205.[29]ShenL,JiJ,ShenJ.Langmuir,2008,24:9962~9965.[30]WangYL,SimsCE,MarcP,BachmanM,LiGP,NancyL.Langmuir,2006,22:8257~8262.[31]LiuT,YinYS,ChenSG,ChangXT,ChengS.ElectrochimActa,2007,52:3709~3713.[32]LiftonA,SimonS.,FrahmRE.AT&TBellLabTechJ,2005,10:173~178.[33]LiWZ,WangX,ChenZW,WajeM,YanYS.Langmuir,2005,21:9386~9389.[34]MaM,MaoY,GuptaM,GleasonKK,RutledgeGC.Macromolecules,2005,38:9742~9748[35]SunTL,TanH,HanD,FuQ,JiangL.Small,2005,1:959~963.AdvanceonSuperhydrophobicSurface:Preparation,ApplicationandRelativeTheoreticalResearchFANZhiping1,WEIZengjiang1,TIANDong1,XIAOChenglong1,SUNXiaoling1,CHENChengLai2,LIUWeiLiang1*(1SchoolofMaterialsScienceandEngineering,ShandongInstituteofLightIndustry,KeyLaboratoryofProcessingandTestingTechnologyofGlassFunctionalCeramicsofShandongProvince,Jinan,250353,China;2HydrologyBureauofLiaocheng,Liaocheng252055,China)Abstract:Thisreviewcoversthelatesttheoreticalresearch,includingWenzelequation,Cassieequation,andanewexperimentaltechniqueisproposedtoeasilymeasurebothadvancingandrecedingcontactanglesofaliquidonasolidsurfacewithunprecedentedaccuracy.Thepreparationmethods,SolGelprocessing,chemicalmodificationmethod,flameplatingmethod,solutionmethod,etchingmethod,hydrothermalmethod,microscalephaseseparationmethod,insitupolymerizationmethod,electrospinningmethod,andanodizingmethod,whichemergedinrecentyears,weresummarized.Wealsointroducedtheapplicationofthelatestfeaturesofsuperhydrophobicsurface,involvingmicroscalematerialenergyfiled,biomedicaldomain,opticsfiled,fueleconomyarea,andbattery.Finally,thedevelopingtendencyofthesuperhydrophobicsurfacepreparationandtheoreticalstudywereprospectedobjectively.Keywords:Superhydrophobic;Superhydrophobicsurface;Lotuslike;Microandnanostructure;Contactangle!110!201011