单分散纳米微粒制备方法研究进展

3(361005),24,,3(200022015)(2001J056)2002206227,2003201220,,RecentDevelopmentonthePreparationofMonodisperseNanoparticlesChenYumin,HeXumin,LanWeiguang,XiaHaiping3(DepartmentofMaterialsScienceandEngineering,CollegeofChemistryandChemicalEngineering,XiamenUniversity,Xiamen361005,China)AbstractMonodispersenanoparticlescanbeobtainedeitherbypreciselycontrolledpreparation,orthroughfractionatingandseparatingofpolydispersenanoparticles.Thispaperprovidesinformationonmonodispersenanoparticlespreparationbyreviewingrecentresearchworks.KeywordsNanoparticles,Monodisperse,Preparation,Fractionation,Separation,,,,,,1,,,2,,144http:PP[1]SiO2CeO2SnO2(TEM),,112,,,:,211211:,[2]ZnO,TEMZnO,20nm,,,,;,,,[3]CuOPZnOPAl2O3,,,10nm,,,,11212[4]MgSO45Mg(OH)23H2OTEM,,1020nm,X(XRD)(16nm),,;24420037http:PP[5],,,,,,Sugimoto[6]22Fe2O3,,2Fe2O3,2Fe2O32m30nm2,,,,,2,11214,Bonet[7](PVP),AuPtPdRuIr,10nmTEM,Rataboul[8],[Zn(C6H11)2],ZnOZnTEM6nm,Selvakannan[9](HAuCl4)(HDA)12h,AuHAuCl4HDA,:,XRD,10-3molPLHAuCl4210-2molPLHDA10-3molPLHAuCl4210-4molPLHDAAu,HDAAu112151982Boutonnet[10]PtPdRhIr,35nm,10%,:,,WPO,Qiu[11](SDS)PPP,Cu,Masui[12]CeO2,(HRTEM),CeO226nm,,,Pileni[13]WPOOPWCdS,:,;,,,113,344http:PP[14]:,,;,Sanchez2Lopez[15]ZnS,TEM8nm,79nm,,Ozawa[16],,W,80nmWW,,,11312(DifferentialMobilityAnalyzer,DMA)[17],DMA(electricmobilitydiameter)DMA,Magnusson[18]30nmAu,DMATEM,20%Hummes[19]Ag,DMAAg;(AFM)10nm,,DMA11313,,Fe,,Otten[20],Fe2(C5H5),3100nmFe,DMAFe2,DMAFe1114114,,,,,Tang[21]Ag(highlyorientedpyrolyticgraphite,HOPG),,:42HOPG,;AgNO3,Ag+;Ag+AgTEM,Ag,72%34nm;Ag,75%515815nm,,Papp[22]Pd:44420037http:PP(),Pd2+Pd,TEM,Pd,24nm,[23],MgFeO4WPO,Mg(OH)22Fe(OH)3,,MgFeO4TEM,2030nm,XRD,:,2,,,,,,,211()(),,,,;,;,Sivamohan[24]CdS,,,5m2,,,,,Wei[25],;(SDS)513nm3813nm,AuKAuCl4Au,SDS,,;SDS,,Au,,SDSAuSDS,SDSAu,;SDS544http:PP[26],2060nm;Wei[25]SDS,10nm,Au2121(a),,,1(b)[27],,,,,,;,,,,(a)(b)1Fig.1Principleofflowfield2flowfractionation(a);(b)Rheilander[27],,,10nm,10nm,10nm,,10nm50nm,Neel0600Tmol-1Fe30nm,Neel84Tmol-1Fe,,,,,,,213,2[28],,,64420037http:PP[28]Fig.2Experimentalsetupofthemagneticfractionationtechnique[28]Rheinlander[28],1T,5nmFe2O3,;450mT30mT,7nm014,450mT,,30nm70nm,,,,(intensity2weighedmean)(volume2weighedaverage),,,Neel;Brown,NeelBrown,Rheinlander[29],,,,214,,,,,,,,,SPLITT(Split2flowthincellfractionation)SPLITTJiang[30],(Isoelecticfocusing)Gole[31]pH(),Massart[32],pH=7,744http:PP[1]FLi,XHYu,HJPanetal.SolidStateSciences,2000,2:767772.[2],,.,2002,60(7):12251229.[3],,.,2002,23(4):706708.[4],,.,2002,23(9):17901791.[5]LLHench,JKWest.Chem.Rev.,1990,90(1):3372.[6]TSugimoto,YSWang,HItohetal.ColloidsSurf.A,1998,134(3):265279.[7]FBonet.VDelmas,SGrugeonetal.NanostructuredMaterrials,1999,11(8):12771284.[8]FRataboul,CNayral,M2JCasanoveetal.J.Organomet.Chem.,2002,6432644:307312.[9]PRSelvakannan,SMandal,RPasrichaetal.Chem.Commun.,2002:13341335.[10]MBoutonnet,JKizling,PSteniusetal.ColloidsSurf.,1982,5(3):209225.[11]SQQiu,JXDong,GXChen.J.ColloidInterfaceSci.,1999,216(2):230234.[12]TMasui,KFujiwara,K2IMachidaetal.Chem.Mater.,1997,9(10):21972204.[13]MPPileni,MLaurence,TKJainetal.Electrochem.ColloidsDispersions,1992:375383.[14]HGleiter.Adv.Mater.,1992,4(728):474481.[15]JCSanchez2Lopez,AFernandez.ThinSolidFilms,1998,317(122):497499.[16]EEZawa,YKawakami,TSeto.Scripta.Mater.,2001,44:22792283.[17]HFissan,DHummes,FStratmannetal.AerosolSci.Technol.,1996,24(1):113.[18]MHMagnusson,KDeppert,J2OMalmetal.NanostructuredMaterials,1999,12:4548.[19]DHummes,SNeumann,FSchmidtetal.J.AerosolSci.,1996,27(1):s163s164.[20]FOtten,KElihn,FEKruisetal.J.AerosolSci.,1998,29(1):s125s126.[21]ZYTang,SQLiu,SJDongetal.J.Electroanaly.Chem.,2001,502:146151.[22]SPapp,ASzucs,IDekany.SolidStatelonics,2001,1412142:169176.[23],,.,2001,3:5861.[24]RSivamohan,HTakahashi,AKasuyaetal.NanoStructuredMaterials,1999,12:8994.[25]G2TWei,F2KLiu.JournalofChromatographyA,1999,836:253260.[26]TSiebrands,MGiersig,PMulvaneyetal.Langmuir,1993,9(9):22972300.[27]TRheinlander,DRoessner,WWeitschiesetal.J.Magn.Magn.Mater.,2000,214(3):269275.[28]TRheinlander,RKotitz,WWeitschiesetal.J.Magn.Magn.Mater.,2000,219:219228.[29]TRheinlander,RKotitz,WWeischiesetal.ColloidPolym.Sci.,2000,278(3):259263.[30]YJiang,MEMiller,MEHansenetal.J.Magn.Magn.Mater.,1999,194(13):5361.[31]AMGole,Csathivel,ALachkeetal.J.Chromatogr.A,1999,848(122):485490.[32]RMassart,EDubois,VCabuiletal.J.Magn.Magn.Mater.,1995,149(122):15.84420037http:PP