沈阳药科大学有机化学硕士考试参考

一、用系统命名法命名下列化合物或根据名称写出其结构，注意立体化学问题。(S)-2,4-环己二烯醇4-甲基-1-苯基-1,5-庚二酮1,2-环氧戊烷(E)-5-苯基-2-辛烯-6-炔OHHPhOOOH3CCCCH2CH2CCCH3HHPh(2R,3S)-3-羟基-2-巯基戊醛2’-硝基-2-甲氧基联苯-4-磺酸CHOHSHCH2CH3HOHNO2H3COSO3H(1R,3S)-1,3-环己二醇的优势构象2-溴-5-异丙基苯酚OHOHOHBr异戊二烯苯基仲丁基醚PhOCHCH2CH3CH3××××cDDDDDDcBDcccccBrCOOHN(CH2CH2Ph)2O.HClO2NNO2NHN=CHPhOHCHOCH=CHOCH2CH3PhHOHHCOPhCH3CH3CH2CH2COO-+CHBr3PhCH2OH+HCOO-H3COH+CH3CH2CH2IBr2/CCl4EtHOHHHEtHOH+CH2PhHBrCH3HBrCH2PhBrHCH3BrH+OOHO饱和NaHSO3固体液体稀H+蒸馏CHOOH杜伦试剂、斐林试剂、羰基试剂、饱和NaHSO3PhHC2H5HClCH3ClHC2H5HPhCH3ClHC2H5HPhH3COH-HC2H5CH3PhCH3OHCH3BrCH3Br1)H+2)-H2OCH3+Br-CH3+Br-COOHBrCH3COOHKMnO4/H+Br2/FeOOHOHOH[H]H+1)B2H6,THF2)H2O2,OH-CHOMgBrOHOH[O]1)HBr2)Mg/Et2OHO2OH-CHO[H]CHOCH2OH浓H2SO4-H2OCHO+或OHD:C:OHA:OOB:OHCH3A:OCCH3CH3OB:OHCH3CCH3OC:OHCH3CHCH3OHD:OHCH3CH2CH3E:OCH3CH3CH2CH3F: