电镀镍磷合金研究现状及前景

:1998-05-25;:1998-11-25(310032)(310032)(315207),;;TQ153120,,,,,,(),,,(),,,,,0111,,,,,,,,,,1950,BrennerA[1]27119993JOURNALOFZHEJIANGUNIVERSITYOFTECHNOLOGYVol.27.No.1March1999©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(NiSO47H2O,NiCl26H2O)(H3PO4,H3BO3)(H3PO3),,,,pH,1BrennerA/gL-1NiSO47H2O150J/(Adm-2)510NiCl26H2O45pH0.51.0H3PO440t/7595H3BO350BrennerA1[1],,,,,,[2-5],BrennerA[1];,[6],RajNarayan(H3PO4,H3BO3),70g/L,[2];KozarevK,[5,7],BrennerA,LashmoreDS[1,8,9],;,,[10],,,,,,BrennerA[1]:(1)pHpH015110015,,pH1,(2),,,(3)(5A/dm230A/dm2),,(4)0115,BrennerA[4],BrennerApH0151.0,,pH,pH0153[6];[5],pH,,3627:©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[3-5];RajNarayan,[2-5]BrennerA,(,)VakahidovRS[11],RajNarayanVakahidovRS0119013501512[2,4,12],,,,,,2211LashmoreDS[8]2Cl-Cl2+2e(1)2H2OO2+4H++2e(2)H3PO3+H2OH3PO4+2H++2e(3)3Ni2++2H3PO3+6H++12e3Ni0+2P0+6H2O(4)6H++6e6H0(5)H3PO3+6H0PH3+3H2O(6)2PH3+3Ni2+3Ni0+2P0+6H+,(7)Ni2++2eNi0(8)2H++2eH2(9),ScholderR,PH3Ni2+,,PH3,(6),BundlerM[13]Ni2+1molH3PO3,3H+3e3H0(10)H3PO3+3H+P0+3H2O(11)RajNarayan,,[2,14,15],;[6],4619991©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(12),,LashmoreDSBundlerM,212,Lash2moreDS[8],,,;[16],,1,,:++[17],c2,(0109,01100112),,,,Ts/Tt(Tt();Ts)TsTTt,,[19],Ts/Tt,TsTt,,Ts/Tt,,3311,[21];[2],,(fcc),100!,01086!8!,5627:©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(),2104!,0117!,,,,,[16],,,Bernal,,;,,312,,:31211XBrennerA,,,[1,22-24],31212,,[17,20],31213,[14,15],,,,X(XPS),,OkamotoTX[3,2426]4411,,41111[27,28](0109)7.85g/cm3,7.9g/cm341112[28]60cm(0109),[16];,41113(0110):010105W/(m)0.0135W/(m)[28],:13.810-6(-1)14.510-6(-1)[29]6619991©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[29],0108,,[16],,4111501090110,2[29][14]400,HV960[16],,,,GrahamAH[30]2/kgcm-275(%)36/kgcm-220000(HV)500800,,15%0110,,,[8,9][5],,,41116,[14,30],,,,,41117200,[30],,,[5,15]260,,Ni3P340,,500750,,,[5,9,30]41118,01100112,(3[31]),,,[14,31,36]0110,0Cr18Ni944,,,3/g(m2h)-1302mol30502mol5001080110014701101100112010370103501910123011401160124011741320146(2160h),(90d)[14,32],7627:©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.:41211,,,,41212[33],,,Ni2P,01300140[15,24],[21]:,,,,H2PO2-;H2PO2-,Ni2+,,,,,,[34],5,,[37],B,01100112B,,,,,304316Ni-P8619991©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(15115),,,,6[38],,,,,,;,[39],,1BrennerA,CouchDE,WilliamsEK.Electrodepositionofalloysofphoshoruswithnickelorcobalt.JResNatlBurStand,1950,44:1091192RajNaryan,MungoleMN.ElectrodepositionofNi-Palloycoatings.SurfaceTechnology,1985,24:2332423,,11,1986,44(2):1331384,,11,1982,3:3541511,1983,4(3):3742611(),1982,4:55607KozarevK.ChemAbstracts,1968:68-262558LashmoreDS,RatzkerM,PrattKW.ElectrodepositionandcorrosionperformanceofNi-Pamorphousalloys.Plat2ingandSurfaceFinishing,1986,9:748291()/49555321011,1990,23(3):353611VakahidovRS.ChemAbstracts,(1967)67-2868512VakahidovRS,ChemAbstracts,(1972)76-8004713BundlerM.ElectrochemicalbehaviorofelectrodepositionofNi-Pamorphousalloys.ZAnorgAllgChem,1965,340:113119141Ni-P131929815,1()1,1991,1:28361611,1984,2:16211711,1991,24(1):7119627:©1994-2009ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(12):60060619()11:,198911420,,1(Fe,Co,Ni)-P1,1986,22(2):B80B892111,1991,24(1):1720221Ni-P1,1981,32(12):62663223,1Ni-P1BoshokuGijutsu,1989,38:59359824,1,1988,8(3):24024625,,1HN6251,1989,22(5):413,1626OkamotoT.AstudyontheelectrolessNi-PAmorphousalloyfilms.JNon-Crystallinesolids,1982,61&62:37938427GutzeitG.ElectrolessNickel:Alternativetochromiumcoatings.TransInst,MetalFinishing,1956,33:38339328GutzeitG.DevelopmentofamorphouselectrolessplatingofNi-Panditsapplication.CorrosionTechnology,1956,5:33134629CrehanWJ.Electrolessnickeldeposits.MetalFinishing,1975,73(1);3844301Ni-P1,1984,6(1):152031,,11,1986,7(1):172132ParkerK.Theformulationofelectrolessplatingnickel2phoshorusplatingbaths.PlatingandSurfaceFinishing,1987,74(2):606833,,11,1990,11(3):2482523411,1991,12(6):27327935,11,1996,18(3):323936,11,1996,25(5):15183711,1996,17(1):161838,,:,1986141142239,,1Ni-P1,1996,16(3):36AReviewofStudyofElectroplatingofAmorphousNi-PAlloyandProspectsofitsApplicationsHeJianboWuXiaoan(CollegeofMechanicalandElectricalEngineering,ZhejiangUniversityofTechnology,Hangzhou310032)HuangHui(CollegeofChemicalEngineering,ZhejiangUniversityofTechnology,Hangzhou310032)YuanJunguoXieShuihai(ZhenghaiRefineandChemicalCompanyLtd315207)AbstractThestudyofelectroplatingproblemsofamorphousNi-Palloysuchasthecompositionofbathsolution,thecontrollingconditionsofamorphous,themech