原子连接次序的一些经验规则

(334001),:(1)H3PO3PF3,H3PO3POHOOHHPF3PHOOHOH(2P+3,sp3);(2)N2ONNO(43),NON(2NOsp);(3)COHCN,COC=O,,HCNC=NH,HCN(2NCsp),?,,,()[1]:11H1,1,(B2H6);F,1,d,,H2O2OHOH,C2F4CFFCFF,21,,,,;,N2O,ON,NO31Pauling3:(1);(2),;(3)[2]HCNC=NH,NC()NC(C-=N+H),HCN,HCN(Pauling,,CN,OC,C=O,C[3])41,,H3PO3,,P::93200112:,H3PO3,POH5,2OHOH,7;,,P3,OH,6,H3PO32,,,11HCNO()NHCOCNOH2N2O3NONOO43NOONO2(CN)2NCCNC=NN=C2,3H3PO2POOHHHPHOOHH4,,,P(SCl),PO(21sp3-p,1p-d)[3,4],POsp3pOPdp,OO?:O1,,O1O,,O,,,Pauling(Fe(CO)5Ni(CO)4Cr(CO)6),,CO,,,CO,,,,,,,,CO,3d,,[5],,[1].VSEPR.,2000,(9):4446[2]JamesE.Huheey.InorganicChemistry(thirdedition),1983:365367[3]..2,:,1986:545,522[4]..2,:,1983:133[5]..:,1982:37104200112