帝人芳纶应用介绍

27Twaronhelpstomeettheincreasingreinforcingandprotectivedemandsintires特威隆帮助满足日益增长的轮胎强化和保护需求DolfWoldringhandWilliamWang–TeijinAramidAsia,departmentTires,Shanghai,ChinaDolfWoldringh，王云海---帝人芳纶（上海）有限公司轮胎应用部，中国上海RubberCarcassConference2011,Qingdao中国橡胶协会2011橡胶骨架材料高峰论坛，青岛Outline演讲概要•Teijin&TeijinAramid帝人公司和帝人芳纶公司•公司介绍•Twaron特威隆芳纶产品•Twaronintires特威隆芳纶产品在轮胎中的应用•Twaronyarnportfolio特威隆纱线系列介绍•Hybrids混合帘线/帘子布介绍•Aramidshortfibersandpulp短纤维和浆粕•Trendsintires轮胎的发展趋势•Lowerweight轻量化轮胎•Protective防护型轮胎•Hybridtechnology混合帘子布技术28BusinessGroupStructureTeijinLimited帝人有限公司事业部结构介绍芳纶纤维事业部新事业开发部IT事业部炭纤维事业部聚酯纤维事业部塑料事业部纤维产品销售事业部~19000employeesworldwide帝人全球有19000名员工医药事业部薄膜事业部Annualturnover:~USD8.7billion年营业额为87亿美元IntroductiontoTeijinAramidB.V.帝人芳纶公司介绍•Servingtheindustryforover30years已在本行业服务30多年•Globalpresence业务推展至全球各地•1,550employeesworldwide全球有1550名员工•80patentpositions拥有80个专利•5%ofturnoverinvestedinR&D每年5%的销售额用于研发•Dedicatedconvertingfacilities一流专业的芳纶产品转换设施•Majorshareparaaramidmarketworldwide拥有全球大份额市场29Tenacity(mN/tex)Fromthestart:dedicatedtoaramid从公司成立起就致力于芳纶产品的开发1967:startAramidresearchinArnhem在荷兰阿纳姆市开始研发1977:startpilotproduction芳纶试生产开始1987:startproductioninEmmen在荷兰埃门市商业化生产开始1997:firstcapacityincrease第一次扩产2000:PurchasedbyTeijin帝人公司收购2001:Capacityexpansionplan第一阶段扩产计划2003:1stphasecompleted第一阶段扩产计划一期完工2005:2ndphasecompleted第一阶段扩产计划二期完工2006/7:2ndexpansionplan第二阶段扩产计划2008:1stphasecompleted第二阶段扩产计划一期完工2011:……….¾1.000.000.000€in10years.¾在过去的10年已累计追加投资10亿欧元Twaron特威隆产品特性Comparisonbetweendifferentreinforcingmaterialsbasedonmass•Highstrength高强度•5timesstrongerthansteel•5倍于钢丝•Highmodulus高模量•Lowweight重量轻•Temperaturestability耐高温•Chemicalresistance耐腐蚀•Norust不生锈•Noflatspotting轮胎无平点25002000150010005000不同加强材料性能对比0510152025Elongationatbreak(%)断裂伸长率TwaronTwaronHMSteelPETPA66Rayon30Twaronintires特威隆产品在轮胎中的应用•TheuseofTwaronintirescanbedividedintotwogroups•在轮胎中的应用可分为两大类：•Reinforcement用于对轮胎的加强•Protective用于轮胎的保护Reinforcement轮胎加强的应用案例Passengercar轿车胎Capply冠带层Bead胎圈Sidewall胎壁Belt/Breaker带束层/隔层Motorcycle摩托车轮胎Belt带束层Bicycletire自行车轮胎Bead带束层芳纶冠带层芳纶耐切割带束层2层芳纶胎壁芳纶胎圈31Protective–保护类应用案例•Bicycletire自行车轮胎•Antipuncturebreaker/shortfibers•耐扎刺隔离层/短纤维•OTR(Offtheroad)工程轮胎•Sidewallreinforcement胎壁加强•Cutresistantbreaker耐切割隔离层•Motorcycle摩托车轮胎•Cutbelt耐切割带束层•Aircrafttires航空轮胎•Aramidprotectivelayer芳纶保护层OverviewoftheuseofTwaronindifferentTires特威隆在不同轮胎中的应用Tiretype轮胎类型Reinforcement加强Protective保护Capply冠带层Carcass胎体Belt带束层Sidewall胎壁Bead胎圈Belt带束层Sidewall胎壁Passenger轿车胎XDevDevXDevXRacing赛车胎XX?XX?X?Truck/Bus卡/客车轮胎DevOTR工程轮胎)XXXAircraft航空轮胎XXDevXMotorcycle摩托车轮胎XXBicycle自行车轮胎XX32Breakingtenacity[mN/tex]Breakingtenacity[mN/tex]Twaronyarnportfolio特威隆纱线介绍2500ComparisonTwarontypes(basedon1100-1210dtexdata)特威隆纱线强度/模量性能对比（基于1100～1210Dtexdata)240023002200210010251008D2200Twaron1025特威隆1025系列纱线:-Tenacityandmodulus高强度/高模量Newdevelopmentforcapply为轿车冠带层最新开发的产品210020001000/D1014TwaronD1014特威隆1014系列纱线:-Adhesionactivated=noprediponlyRFL粘合力活化型=该系列纱线无需二维浸胶，只需RFL浸胶-AdhesionactivatedD1014Advantageinhybridcorddipping便于混合帘子布的浸胶190050,060,070,080,090,0100,0110,0120,0130,0140,0Chordmodulus[Gpa]模量2500ComparisonTwarontypes(basedon1100-1210dtexdata)特威隆纱线强度伸长率性能对比（基于1100～1210Dtex数据）2400102523002200D220010082100210020001900Lowelongation低伸长率1000/D1014Highelongation高伸长率2,02,53,03,54,04,5Elongation[%]伸长率（%）33Hybrids混合帘线/帘子布•HybridsofTwaronandpolyamide6,6arecommonlyused,because•通常采用特威隆纱线和尼龙66纱线混合帘线/帘子布，因为：•Higherelongationatbreak更高的断裂伸长率•Partofelongationwillbeconsumed(tirelift,inflationetc.)•轮胎在制造和使用过程需要消耗部分伸长率•Goodadhesion更好的粘合力•Goodfatigue更好的耐疲劳性能Aramidshortfibersandpulp芳纶短纤维和浆粕TeijinAramidproducesapartfromTwaronpara-aramidalsoTechnorapara-aramidfibersforreinforcementofrubbers.除特威隆对位芳纶，帝人芳纶公司还生产Technora对位芳纶TWARON特威隆分子式TECHNORA分子式34Surveymainaramidshortfibers/pulp芳纶短纤维/浆粕介绍Shortfibers/pulpenhancethepropertiesofrubber芳纶短纤维/浆粕提高升橡胶的特性:-Increasedabrasionresistance提高耐磨性能-Increasedlow-strainmodulus提高小应变模量-Betterpunctureresistance更好的耐扎刺性能-Bettergreenstrength更好的绿色强度RhenogranAFP40/NRTwaron（特威隆）-Shortfibers(1,1.5,and3mm)短纤维（1毫米，1.5毫米和3毫米）-Pulp浆粕-Pulpmasterbatch=RhenogranP91/NR,AFP/NR浆粕母粒=RhenogranP91/NR,AFP/NRTechnora-Shortfibers(1,3and6mm)Technora短纤维有1毫米，3毫米和6毫米Twaronwillpartlyfibrillate特威隆部分分解成原纤维Technoraremainsitsintegrityapartfromsomefibrils除一些小纤维外Technora会保持完整Advantagepulp浆粕优势:mechanicalinterlocking机械联锁Advantageshortfibers短纤维优势:orientation定向性Technorahasbetterwearresistance（Technora具有更好的耐磨特性）35Impactshortfibersonmodulus短纤维对模量的影响Abrasiononend(iso4649,methA)磨耗性能对比（参照ISO4649，A方法）•TwaronCF3mm:130mm3abradedvolume•TechnoraCF3mm:100mm3abradedvolume•Control（不含短纤维）:170mm3abradedvolume(10mm3issignificant,apartfromapproximately10%spread,80mm3isextremelow)（大于10立方毫米差异已经是非常明显的，再除去10%，80立方毫米是极低的磨耗）TwaronwillfibrillatemorethanTechnora特威隆短纤维原纤维分解大于TechnoraAbrasion磨耗36m(ytTenaciN/tex)Trendsintires未来轮胎的发展趋势•Lowerweighttires轻量化轮胎•CO2emissionpassengercars-ImpactRegulation(EC)No443/2009•这主要是由于欧盟443/2009法规的影响：对轿车CO2排放限制•Protective防护型轮胎Sustainablesolution–lowerweighttire未来可持续的解决方案—轮胎的轻量化BasedontenacityTwaronhasthebestperformance:基于特威隆的高强度，它具备最佳的性能•Lower