过氧乙酸的性质-制备和应用

:2004-02-18:(1971-),,,,,,(,450003):,29::R187.2:A:1006-8414(2004)03-0171-03TheProperty,PreparationandApplicationofPeraceticAcidLIUJi-qi,LIShu-jian,WANGJing(HenanProvincialSanitaryandAnti-epidemicStation,Zhengzhou450003)Abstract:Theproperty,mainpreparingmethodsandapplicationofperacetionacidareintroducedbriefly.Thispapercanhelptodevelopnewkindsofperacetionacidandwidenthemarketofperacetionacid.29referencesarepresented.Keywords:Peraceticacid(peraceticacid),,1902,,207080,,200342()(),,,,,1[1-3],,C2H4O3,76.0518,CCH3OOOH,,,0.1,110,1.226,,45%(g/ml),(40.5)20%,,,,,,,,,,,,,AB,,1712004153HenanJPrevMed,2004,Vol.15,No.32[4-7],2.1,,:H+CH3COOH+H2O2=CH3COOOH+H2O,:(CH3CO)2O+2H2O2=2CH3COOOH+H2O,,,,,,2.2,,:CH3CHOO2,0CH3COOOH,2.3,,,:3(CH3CO)2NCH2CH2N(COCH3)2+2Na2CO31.5H2O=2Na2CO3+3CH3CONHCH2CH2NHCOCH3+6CH3COOOH,,:3COOHC6H4COOCH3+2Na2CO33H2O2=3HOC6H4COOH+2Na2CO3+3CH3COOOH3,,,,,,,:3.1[4,8-10]207080,2090,,,,,,0.01%0.1%10min,0.25%5min,0.5%5min;,;0.5%lOmin,3.2[11-18],,,,0.5%,,,,,3.3[13-25],4[10.26-29]4.1,:4.2,,2712004153HenanJPrevMed,2004,Vol.15,No.3,,4.3,,::,4.4,16%,1(AB),AB,2448h,18%,100%4.5,,4.6,,:1.[M].:,2002.105.2.[M].:,1999.340344.3,.[J].,12(6):2627.4.[M].:,2002.10881098.5.[J].,1998,15(2):4748.6,,,.[J].,1996,(2):3537.7,,,.[J].,2001,18(1):610.8.[Z].,2002:163.9,.[J].,1997,32(2):68.10.[J]..2003,13(5):473.11,,.SARS[J].,2003,8(3):3636.12,,.0.5%60[J].,2002,31(3):168.13,,.0.5%.[J].1997,(1):45.14.[J].,1996,10(2):114.15.[J].,2003,43(20):73.16,.17%25[J].,1999,29(8):23.17,,.85[J].,2003,43(20):7071.18.33[J].,2001,27(7):225.19,,,.[J].,1995,21(9):29.20,.[J].,1995,(1):31.21,,,.TCF[J].,1999,15(4):6870.22,.[J],1998,(1):1013.23,,,.[J].,1996,14(3):327329.24,,.[J].,2000,8(1):2228.25,.[J].,1994,29(5):300301.26.1.[J].194,8(2):131312.27,,,.1[J].,2003,38(9):55.28,.[J].,1997,10(2):75.29,,.1[J].,2000,20(7):394.3712004153HenanJPrevMed,2004,Vol.15,No.3