光纤氧传感器技术进展

第17卷第6期　　　　　　　　　　　　　　　分析科学学报2001年12月Vol.17　No.6　　　　　　　　　　JOURNALOFANALYTICALSCIENCEDec.　2001:1006-6144(2001)06-0510-05洪江星　李　伟　庄峙厦*　陈　曦　孙大海　王小如(,,361005):综述了近年来国内外光纤氧传感器技术的研究及应用情况,探索了光纤和荧光指示剂的进展,阐述了氧传感技术和制作氧传感膜的机理及光纤氧传感器的应用情况,并展望了光纤氧传感器的发展趋势。引用文献30篇。:光纤;氧;传感器;评述:O657.15;O612.6　　　:A1,[1-3],,,,(DissolvedOxygen,DO),,Wittkanpf[2]Clark,,,,,(FiberOpticalChemicalSensors,FOCS),,,Clark,,[3]22.12050,,,60,80,,[4]:2000-02-20::;CCD;(863)818-Q-095102.2:,,;,;;,;,;;,;,[5],,,[4]2.3,[6],1980PetersonpHFOCS,1984FOCSFOCS,FOCS,pHFOCS,,,[7],,[8],33.1,Stern-Volmer[1]:F0/F=1+Ksv[Q](1)Ksv=kS0(2)k=AD(3)FF0,S0,KsvStern-Volmer,k,A,D,[Q]ADk,,,3.280,,12h[9],1984Wolfbeis,,(50ms),1989,Philip[10]1102153XAD-4XAD-8,102XAD-4,,,[Pt(P2O5H2-2)4]4-511第6期洪江星等:光纤氧传感器技术进展第17卷,515nm,[11];[Pt(A-)(CN)2]Ru(bpy)2+3,,[12];-0.5%-100%O2,5s,5,[13][14](RuOsReRhIr),,,,d6[15],,[16]ReL(CO)3CNR+L(A-),L[17],,,[18],[19],2,2-1,10-Brian[3]pHRu(bpy)2+3Ru(ph2phen)2+3,pH=7Ru(ph2phen)2+3,,[20]Ru()4,7--1,10-Ru()[4,7-(4-)-1,10-]3(ClO4)2Ru()[4,7-(4-)-1,10-]3(ClO4)2Kerry[21]Ru()[5--1,10-]3(ClO4)2,,,Ignacy[22][Ru(dpp)3Cl2]3.3,,-3.3.1Kerry[21]Ru()[5--1,10-]3(ClO4)2:20mL2%[C-()-]1h,35%5%N,N-()0.1mol/L()210-4mol/LRu()[5--1,10-]3(ClO4)2,pH6.51mW488nm13min3.3.2--(Sol-Gel)-,,-,,[23]-,Si-O-Si,,,SiO2,,[24](Methyltriethoxysilane,MTEOS)(Ethyltriethoxysilane,ETEOS),MTEOS/TEOSETEOS/TEOS,(QG%),(QDO%),100%ETEOSQDO100%MTEOSQDO,,512第6期分析科学学报第17卷9.2Lgml-1,,,,,[25]4Wolthuis[26],Viologen:600nm,,30800mmHg,2%(30150mmHg)5%(150mmHg),1mmHg,15s,C,,(Imaging-FiberOxygenSensor,IFOS)IFOSRu(ph2phen)2+337,4CCD,/(BloodGasAnalysis,BGA),,BGAIFOS,,IFOS[27](BiochemicalOxygenDemand,BOD)DO,,,Clark,[28]/Ru(ph2phen)3ClO4,10001,80pw,6,50h,530s,50Lm,,H2SCO2,,,[29],,,,,DO,[30]5,,,,,,:[1]AislingKM,ColetteMM,BrianDM.Analyst[J],1996,121(6):785.[2]WittkanpfM,ChemnitiusGC,CammannK.SensorsandActuatorsB[J],1997,43(1-3):40.[3]BrianDM,ColetteMM,GerardO.Analyst[J],1993,118(4):385.513第6期洪江星等:光纤氧传感器技术进展第17卷[4].[J],1997,17(4):248.[5],.[J],1995,2:14.[6],,.[J],1997,3(5):17.[7]PeterCH,SusieSST.Analyst[J],1993,118(8):991.[8],,.[J],1997,16(5):5.[9]MarcJPL.Anal.Chim.Acta[J],1991,255(1):209.[10]PlillipYFL,RamaierN.Analyst[J],1989,114(8):1191.[11]Xiang-MingL,Kwok-YinW.Anal.Chim.Acta[J],1992,262(1):27.[12]WeekeyW-SL,Kwok-YinW.Anal.Chem[J].,1993,65(3):255.[13]Sang-KyuangL,IchiroO.Analyst[J],1997,122(1):81.[14]PaulH.Anal.Chem[J].,1996,68(5):2615.[15]CarrawayER,DemasJN.Anal.Chem[J].,1991,63(4):337.[16]WenyingX,KristiAK.Anal.Chem[J].,1996,68(15):2605.[17]LouAnnS,DemasJN.Anal.Chem[J].,1993,65(23):3480.[18]PaulH,MarcJPL.Anal.Chem[J].,1995,67(1):88.[19]Chun-ManC,Mee-YeeC,MinquanZ.Analyst[J],1999,124:691.[20],StefanR.[J],1997,17(4):279.[21]KerryPM,XuepingL.Anal.Chim.Acta[J],1998,361(1-2):73.[22]IgnacyG,GryczynskiZ.Analyst[J],1999,124:1041.[23]NealAW,BrettRW,JeffreyDJ.AppliedSpectroscopy[J],1998,52(5):750.[24]LevO,TsionskyM.Anal.Chem[J].,1995,67(1):22A.[25]McDonaghC,MacCraithBD.Anal.Chem[J].,1998,70(1):45.[26]WolthuisRA.IEEETransactionsonBiomidicalEngineering[J],1992,39(2):185.[27]YadongZ,AngelaR,ChariesS.Anal.Chem[J].,1999,71:3887.[28]JamesND,DeGraffBA.AnalyticalChemistryNews&Features[J],1999,10:793A.[29]WangW.SeanTechnology[J],1999,40:69.[30],.[J],1999,18(3):1.DevelopmentofFiberOpticOxygenSensorsHONGJiang-xing,LIWei,ZHUANGZhi-xia*,CHENXi,SUNDa-hai,WANGXiao-ru(TheKeyLaboratoryofAnalyticalSciencesofMOEandDepartmentofChemistry,XiamenUniversity,Xiamen,361005,China)Abstract:Thispaperreviewedthedevelopmentoffiberopticoxygensensors,theopticalfiberandthefluorescenceprobeinrecentyears.Themechanismsofoxygensensingmembraneandtheoxygensensorsweredepicted.Thedevelopmentdirectionoffiberopticoxygensensorswasprospectedwith30referencepapers.Keywords:Fiberoptic;Oxygen;Sensors;Review514第6期分析科学学报第17卷