评印染助剂发展回顾和方向探讨(三)

():;:TS19012:A:1000-4017(2006)19-0049-03(2)APEOAPEO(NPEO),APEO80%,(OPEO),APEO15%,(DPEO)(DN2PEO)APEO1%APEO,APEO,,,,APEOBASFLeaphenUAPEOAEOASAPEO,,APEOAPEO,APEO,APEOAEO;,50%EOAPEO,APEO,(LAS)APEOAPEOAPEO,7.5%44//%199520002005199520002005LAS31035040033.332.432.0AES70801007.57.48.0AS6080906.57.47.2AEO801001308.69.310.4APEO7080807.57.46.434039045036.636.136.093010801250100100100,25.5%26.5%,AEOAPEO63%APEO1995,7.5,25,20,4.5,13;198715,251995,,,2000,,,APEO,APEO,(EPA)30,NPNPEO,[31]NPEO,LD50=1600mg/kg,4%80%,EO,,,2080(OSPAR)15NPEO;,APEO,APEO2003/53/EC,2005117,APEO,APEO0.1%(1000mg/kg),APEO,20025152002/371/ECAPEOECO2label,APEO7APEO,,(FEO)(APG)N2(NAGA)(FMEE),APEOAPEO,48g/L,0.52.0g/L,,,,,,(40%50%),,2003/53/EC,:,,4%6%;,APEO,,,APEOHPLC,,,,94()(2006No.19);,BASFDyStarAPEO,,,APEO,(3)AOXAOX(AbsorbableOrganicHal2ogen)(),,AOX2070,AOX,pH2,,,,1000,,,AOX1979EPA;19853,DIN38409H14[32];199610,,AOX,1987(FederalEffluentLaw)AOX100g/L,0.5mg/L,,,AOX,,,,,,,AOX(4):,;;,,,,,(THPC),(Proban),(THPN)2,CP228kJ/mol,CN(304.7kJ/mol),PyrovatexCPN2,LD5010g/kg,LC50100mg/L,,N2,,,,:CH2CH+OCONH2POCH3OCH3HRONaOPOCH3OCH3CH2CHCONH2HCHONHOH2CCOCH2CH2POCH3H3COOH150,,31,,(TMM)(HMM),TMMHMM,,HMM660mg/kg,225mg/kg;TMM,20032152003/11/EC,(PBDPE)(OBDPE)0.1%(1000mg/kg),2004815Oeko2TexStandard1002005,,LD50=15g/kg,PBOPEOBOPE,,,Sb2O3,ISO1052E04:1994(,pH5.5),,,,(5),MCR,,,05(2006No.19)(ETAD)1974(),3.1,,30%,,;,,,,,,,,,,3.1.1,,95H2O2+OH-HOO-+H2OpH[33],pH10.511.0,80%,,50%,,20%,,60min46%,AR2750Pre2stogenEB,13%16%,,2090,(Fe3+,Cu2+,Co3+,Ni3+,Cr3+);2090,,(TAED)[34](AOBS),TAED[35]:NCOCH3COCH3CH2CH2NCOCH3COCH32HOO-CH3CONHCH2CH2NHCOCH3+2CH3COOO-TAED,,6070,pH89TAED/H2O2H2O2,,TencelAH2O2TAED/H2O2,69.9%74.9%TAED,H2O2,:H2O2,35kPa,TAED/H2O2,61kPa[36](AOBS)[37]AOBS,C610,,,[38]:OCORSO3Na+HOO-COROO-+HOSO3NaAOBS/H2O2,4050,,H2O2,[39]AOBS,:(1)H2NCH2CH2NH2+4CH3COClNCOCH3COCH3CH2CH2NCOCH3COCH3(2)OH+H2SO4115HOSO3H+H2OC8H17COOH+SOCl2106112C8H17COCl+SO2+HClHOSO3H+C8H17COClOCOC8H17SO3H+HClOCOC8H17SO3H+NaOHOCOC8H17SO3Na+H2O()()()197520012024000,,()2,:98833272:(021)55213494552100112375:[phone]:20008215()(2006No.19)