1-3-二氨基硫脲的制备

16120043JOURNALOFJIANGSUPOLYTECHNICUNIVERSITYVOI.16NO.1Mar.20041005-8893200401-0035-0513-1221.21301613-TCHHDTCICS2=2.2I120C45minHDTCTCHHDTC20h8hTCH90%13-O623.54+2A13-TCH11~42TCH3513-!#$CS2+2H2NNH2-H2NNHCSSHNH2NH21HDTCH2NNHCSSHNH2NH2-H2NNHCSNHNH2+H2STCH2$HDTCTCH70%6HDTCTCH5TCH90%20hHDTCTCHTCH11.185%1.2CS22003-11-051964-2-2003HDTCHDTCH2STCH1.3X-4eiementVarioEL!IR460KBr22.1HDTC2.1.1HDTCCS2HDTCCS221110C45min411HDTC1HDTC95%2.1.2HDTCCS221110C30min45min60min75min2230min45minHDTC45minHDTC94.57%HDTCHDTC2HDTC2.1.3HDTCCS221145minHDTC33HDTC310C20CHDTC94.57%95.71%HDTC52.1.4CS2HDTC20C45minCS21.8112.0112.2112.4114HDTC4CS221142.2111!2004HDTC2.2Il20C45minHDTC96.3%4CS2HDTC2.2HDTCTCH2.2.lTCH2HDTCH2STCHHDTCHDTCHDTCHDTCl2HDTCNaOHH2NNHCSS-H3N+NH2+NaOH-HDTCH2NNHCSS-Na++NH2NH2+H2ONaDTC3NaDTC+NH2NH2-TCH+NaSHNaSH+HDTC-NaDTC+H2S+NH2NH2HDTCBH2NNHCSS-H3N+NH2+B-HDTCH2NNHCSS-B++NH2NH2BDTC4BDTC+NH2NH2-TCH+BSHBSH+HDTC-BDTC+H2S+NH2NH25HDTC77C81HDTC7.5mOI%5HDTCTCH80%TCH65%NaOHTCH58%TCHHDTCTCHCS2HDTC5TCH2.2.2HDTCTCH677C81l0%HDTCHDTCTCH6TCHHDTCl.25TCH89.6%TCHl.256HDTCTCH2.2.3TCHHDTC7HDTC!.l3-HDTC1.2577C8hHDTCTCHHDTC7TCH7TCH10%TCH90%TCHTCH10%2.2.4TCH8HDTCHDTC1.258h8TCH877CTCH89.6%HDTC50CH2SHDTC580CH2STCHHDTC77CTCH2.2.5TCHHDTCHDTC1.2577CTCH99TCH9TCH7h8hTCH85%89.6%TCH8h3HDTC118~122CTCH170~172C171CC11.36%N52.73%H5.72%CSNcm-1!11485!212801140!37501525NH925NH3200!NH41HDTCICS2=2.2I120C45min2HDTC20h8hTCH90%3!2004CS2HDTC1SinghBSrivastavaU.4-2-thiazoIyI-1-2-hydroxy-benzaIdehydethiosemicarbazoneasaCheIatingLigandCompIe-xeswithVanadiumIVCobaItIINickeIIICopperIICadmiumIIandMercuryIIJ.SynthReactInorgMet-OrgChem1989193279-291.2.J.1998142153.3IskanderMFEI-SayedLEI-ToukhyA.CoordinationCom-poundsofHydrazineDerivativeswithTransitionMetaIs-XIXRedoxReactionsofCuIISaItswithThiosemicarbazideandHy-drazine-S-methyI-dithiocarboxyLateSchiefBasesJ.JIn-orgNucIChem19804281145-1150.4BaiJFWuJGWangLFetaI.SynthesisPropertiesandAntioxidativeBehaviorofSomeTransitionMetaICompIexesofN-benzoyIaminothioxomethyIgIycineJ.SynthReactInorgMet-OrgChem1998286917-928.5JackmanDennisECombsetaI.ProcessfortheProductionofThiocarbohydrazideP.US49469951990-08-07.6BurnsGR.MeteaICompIexesofThiocarbohydrazideJ.InorgChem196872277-282.ProcessfortheProductionofThiocarbohydrazideSHENGMei1JIANGYan-ging2LUZheng-wei21.KeyLaboratoryofFinePetrochemicaIEngineeringJiangsuPoIytechnicUniversityChangzhou213016ChinaAbstractAprocessofproducingthiocarbohydrazideTCHbyusingcarbondisuIfideandhydrazinewasstud-ied.TheexperimentaIresuItsshowthattheoptimaIconditionsforforminghydrazinium-dithocarbazinataHDTCwerehydrazinetocarbondisuIfidemoIarratioat2.211reactiontime45minat20C.AnimprovedprocessforproducingTCHfromHDTCwasinvestigated.ItwasshowedthatTCHwasproducedbyheatingHDTCinthepres-enceofhydrazineandaIittIeinhibitorreactiontimedecreasedto8hfrom20handthetotaIyieIdofTCHwasa-bout90%.TheprocessforproducingTCHdidnotreguireremovingtheexcessofhydrazinebutdidproduceTCHinhighyieId.KeywordsthiocarbohydrazideTCHhydrazinium-dithocarbazinataHDTChydrazinecarbondisuIfide93.13-1,3-二氨基硫脲的制备作者：盛梅，蒋燕清，陆峥伟作者单位：江苏工业学院,精细石油化工重点实验室,江苏,常州,213016刊名：江苏工业学院学报英文刊名：JOURNALOFJIANGSUPOLYTECHNICUNIVERSITY年，卷(期)：2004,16(1)被引用次数：1次参考文献(6条)1.SinghB;SrivastavaU4-(2-thiazolyl)-1-(2-hydroxybenzaldehyde)thiosemicarbazoneasaChelatingLigand:ComplexeswithVanadium(IV)Cobalt(II),Nickel(II),Copper(II),Cadmium(II)andMercury(II)1989(03)2.毕思玮;李桂枝;刘树祥联苯已酮缩氨基硫脲过渡金属配合物的合成及其对水稻白叶枯病菌的杀菌活性研究1998(02)3.ISKANDERMF;El-SayedL;El-ToukhyACoordinationCompoundsofHydrazineDerivativeswithTransitionMetals-XIX:RedoxReactionsofCu(II)SaltswithThiosemicarbazideandHydrazine-S-methyl-dithiocarboxyLateSchiefBases1980(08)4.BaiJF;WuJG;WangLFSynthesis,PropertiesandAntioxidativeBehaviorofSomeTransitionMetalComplexesofN-glycine[外文期刊]1998(06)5.Jackman;DennisE;CombsProcessfortheProductionofThiocarbohydrazide19906.BurnsGRMetealComplexesofThiocarbohydrazide1968(02)本文读者也读过(10条)1.谈春霞.萧泰.TANChun-xia.XIAOTai双缩二氨基硫脲类化合物的合成及其电化学性质研究[期刊论文]-应用化工2006,35(5)2.陈平生.罗书平.王文静.郑鹛间硝基苯甲酰亚肼基二硫代碳酸苄酯的合成[期刊论文]-应用化工2003,32(4)3.聂国朝三乙胺催化合成2,5-二巯基-1,3,4-噻二唑[期刊论文]-化学工业与工程技术2004,25(2)4.张有明.任海仙.魏太保.ZHANGYou-Ming.RENHai-Xian.WEITai-Bao间苯二甲醛缩双芳氨基硫脲的合成及阴离子识别研究[期刊论文]-高等学校化学学报2006,27(11)5.黄红玉杂环有机锡Schiff碱配合物的合成、表征及抑菌活性研究[学位论文]20086.王连.付晓娅肝性胸水22例分析[期刊论文]-现代临床医学2005,31(4)7.聂国朝三乙胺催化合成2,5-二巯基-1,3,4-噻二唑研究[期刊论文]-化工生产与技术2004,11(1)8.时运铭.ShiYunmingN,N'-二苯基硫脲合成方法的改进研究[期刊论文]-现代塑料加工应用2003,15(2)9.白银娟.李春圆.赵水侠.陈旭东.赵桂仿.史真.BAIYin-juan.LIChun-yuan.ZHAOShui-xia.CHENXu-dong.ZHAOGui-fang.SHIzhen均三唑并噻二唑衍生物的微波合成[期刊论文]-化学研究与应用2008,20(3)10.曹运珠.韩晶.毋丹.王小静.王玥.葛茂发.邢永恒.CAOYun-zhu.HANJing.WUDan.WANGXiao-jing.WANGYue.GEMao-fa.XINGYong-heng乙酰二茂铁缩肼基硫代甲酸苄酯的制备、晶体结构及光谱研究[期刊论文]-化学研究与应用2008,20(9)引证文献(1条)1.孙庆庆.王敏.沈淑娇.徐洪良.叶晓霞三唑类席夫碱的绿色合成和生物活性研究[期刊论文]-温州医学院学报2012(3)本文链接：