金属基复合材料的热力学与动力学研究进展

29420104MATERIALSCHINAVol129No14Apr12010:2009-12-02:(50671064):,,1971,,,,(,200240):,,:;;;:TB331:A:1674-3962(2010)04-0023-05TheProgressintheResearchofThermodynamicsandKineticsinMetalMatrixCompositesFANTongxiang,ZHANGCongfa,ZHANGDi(ShanghaiJiaoTongUniversityStateKeyLaboratoryofMetalMatrixComposites,Shanghai200240,China)Abstract:Inthispaperthemodelsofthermodynamicsandkineticsareintroduced.Then,theapplicationsofthemod2elsofthermodynamicsandkineticstocontrolinterfacebetweenreinforcementsandmatrix,selectthekindsofin2situformedreinforcements,controlthesizeofin2situformedreinforcements,designcompositessystemsandoptimizethesyn2thesizingprocess,etcareintroduced.Finally,thesummaryandoutlookstotheresearchofthermodynamicsandkineticsinmetalmatrixcompositesarecarriedout.Keywords:metalmatrixcomposites;thermodynamics;kinetics;models,,,,:;;:;;,[1-2]:(Ex2SituMMCs),(In2SituMMCs),:,,,,,,[3-4],,,,(TrialandErrorMethod),,,©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[5],,,,:Lupis[6]Wilson[7],Lupis,;Wilson;,,,,[8-9]Miedema[10],Wilson[7],,,,[11-13],,[14]Sutherland2Einstein[15]Stokes2Einstein[15]Sutherland2EinsteinStokes2Einstein,,[16],Stokes2Einstein,Sutherland2EinsteinStokes2Einstein,,,:(ActivationRate),,[14]Schwitzgebel[17],,,,[18],,Kirkaldy[19],,,,Morral[20],,[21]1,,,,,,Handwerker[22],,SiC/Al(Al2O3+Cr2O3)/Cr[8,23],Al2SiAlSi,SiCAl:Sr,Zn,Mg,Ca,VCrSiCp/AlSiCAl42©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.(,),SiCp/Al22%Cu,SiCp/Al21%MgSiCp/Al24%Mg,,Sreekumar[24]MiedemaWilsonAl/SiO2Al2O3/MgAl2O4MgAl2O4/MgOMgMgOMgAl2O4,(,Mg,SiO2),,,,1(In2SituMMCs),()PRIMEX-InSituXDTM,:;;;A,B;,,,,,,,[8]TiB2/AlAl3Ti,AlB2TiB2Al3Ti,AlB2TiB2Mg,Cu,Zr,Ni,Fe,VLaAl3TiTiB2ZrSiAl3Ti,TiB2,AlB2[18,25],TiB2/AlTiB,TiB,Cu,Fe,Mg,V,Ni,LaZrTi,Zr,SiTi;Mg,SiCuB,Fe,V,Ni,LaZrB,MgTiB2/Al,:Si,,SiTiB2;,SiTiBTiB2,TiB2,,,Parashivamurthy[26],TiC,TiC1(In2SituMMCs):-(Nucleation2Growth)[27],(BulkInterfaceReaction)[28]-,,[21](AlN+Mg2Si)/MgMg2SiGibbsSi,Mg2Si52©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[29],,[30],,,,1[31]DTAX,,MoSi2-SiC,[32],,[33],,,,;,,,,,,,,,,;,,,[1]SureshS,MortensenA,NeedlemanA.FundamentalsofMetalMatrixComposites[M].Boston(MA):Butterworth2Heine2mann,1993.[2]MiracleDB.MetalMatrixComposites2FromSciencetoTechno2logicalSignificance[J].CompositesScienceandTechnology,2005,65:2526-2540.[3]TjongSC,MaZY.MicrostructuralandMechnicalCharacteris2ticsofinSituMetalMatrixComposites[J].MaterialsScienceandEngineeringR,2000,29(3-4):49-113.[4]Ouyangliuzhang(),Luochengping(),SuiXiangdong(),etal.[J].ChinaFoundryEouipmentandTechnology(),2002(2):6-8.[5]DuYong(),HuangBoyun(),XuHonghui(),etal.Al[J].JournalofCentralSouthUniversity(),2004,35(5):697-701.[6]LupisCHP,ElliottJF.GeneralizedInteractionCoefficients:PartI:Definitions[J].ActaMetallurgica,1966,14(4):529-538.[7]WilsonGM.Vapor2LiquidEquilibriumXI.ANewExpressionfortheExcessFreeEnergyofMixing[J].JAmerChemSoc,1964,86:127-130.[8]FanTX,YangG,ZhangD.PredictionofChemicalStabilityinSiCp/AlCompositeswithAlloyingElementAdditionUsingWilsonEquationandanExtendedMiedemaModel[J].MaterialsScienceandEngineeringA,2005,394:327-338.62©1994-2011ChinaAcademicJournalElectronicPublishingHouse.Allrightsreserved.[9]FanTX,YangG,ZhangD.ThermodynamicEffectofAlloyingAdditiononIn2SituReinforcedTiB2/AlComposites[J].Metallur2gicalandMaterialsTransactionsA,2005,36:225-234.[10]MiedemaAR,ChatelPFde,BoerFRde.CohesioninAlloysemDashFundamentalofaSemi2EmpiricalModel[J].PhysicaB,1980,100B:1-28.[11]YangXiaoning(),MaPeisheng(),ChenHongfang().[J].JournalofChemicalIndustryandEngineering(),1994,45(5):580-588.[12]TyrrellHJV.DiffusionandHeatFlowinLiquids[M].Lon2don:Butterworths,1961.[13]ShimojiM.LiquidMetal[M].London:AcademicPress,1977.[14]SchwitgebelG,LangenG.ApplicationoftheHardSphereThe2orytotheDiffusionofBinaryLiquidAlloySystems[J].ZNaturforsch,1981,36a:1225-1232.[15]PoirierD,GeigerGH.TransportPhenomenainMaterialsPro2cessing[R].WarrendalePA:TheMinerals,MetalsandMateri2alsSociety,1994.[16]CherneFJ,DeymierPA.CalculationoftheTransportProper2tiesofLiquidAluminiumwithEquilibriumandNon2EquilibriumMolecularDynamics[J].ScriptaMaterialia,2001,45:985-991.[17]SchwitgebelG,BeckerW,LangenG.ChemicalDiffusionCo2efficientsinLiquid(Li,Pb),(Li,Ag),(Li,Cd)Alloys[J].ZMetallkde,1983,74:430-433.[18]ChenJQ,FanTX,ZhangD.TernaryDiffusionCoefficients2TheoreticalTreatmentandApplicationtotheIn2Situ2ReinforcedTiB2/AlComposite[J].MetallurgicalandMaterialsTransactionsA,2006,37:2275-2281.[19]KirkaldyJS,YoungDJ.DiffusionintheCondensedState[M].London:InstituteofMetals,1987:161-165.[20]MorralJE.CalculationofDiffusionCoefficientforMulticompo2nentAlloys.In:QiaoZY,XuZH,LiuHL,editors.Com2puterizedPhysicalChemistryofMetallurgyandMaterials[M].Beijing:MetallurgicalIndustryPress,1999.[21]ZhangCF,FanTX,CaoW,etal.SizeControlofin2SituFo