100种有机化学人名反应

1.ArndtEistertCH2O+CH2N2O-CH2N+NN2O2.BaeyerVilligerOCH3CH3CH3OOCH3CH3H2SO5Caro’s3.BechampC6H5-NO2+2Fe+6HClC6H5-NH2+2FeCl3+2H2OFeCl2FeCl3FeSO4CaCl24.BeckmannRNOHR'RRNHR'ONR'ROHR'NHRO5.BeyerZnCl2NH2NHRR'HNRR'++R'CHORCOCH3HClH2Doebner-MillerDoebner-MillerNH2NHCH3HNCH3+H2CH3O2(CH3CHO)6.BlancZnCl2NH4ClAlCl3SnCl4H2SO4H3PO4+++HCHOHClZnCl2H2OCH2ClHClHCHO/HClH2C(OMe)2/HClMeOCH2Cl-CH2OH,-CHO,-CH2CN,-CH2NH2-CH37.BouvealtN,N-R’MgXR’R2NHOR'MgXR2NR'OMgXHHXR'CHO++MgX2R2NH+8.BouvealtBlancROR'OC2H5OHNaRCH2OHR'OH+LiAlH49.BuchererOHNH2(NH4)2SO3,NH3,150,6atmNa2SO3,H2O10.CannizzaroP29129211.ChichibabinAl2O3NCH33CH3CHO+++NH33H2OH212.ChichibabinH5C2OOC2H5O+3RMgXROHRRRMgXRMgXH5C2OOC2H5O+RMgXRH5C2OH5C2OOMgXROC2H5OH2ORCOOH+C2H5OHRRORMgXRH5C2OROMgXROC2H5OMgXOC2H513.Chichibabin50100NNNHNaNNH2NaNH2105110,6676%H2O4-2,62,4,62,2’Bechamp14.Chugaev12020030015.ClaisenCH2CH=CH2OHOCH2CH=CH2200OCH2CH=CH2OHCH2CH=CH2200ClOCH2CH=CH2ClOHCH2CH=CH225016.Claisen(P352~354)17.ClaisenSchmidt(P287)18.Clemmensen(P291)19.Cope1201-N,N--3-3--1CH3N+O-C6H5HCH3CH3*CH3CH2H5C6+(CH3)2NOH*20.CriegeeR2CCR'2OHOH+++Pb(AcO)4RROR'R'ORHCCHR'OHOH+Pb(AcO)4RCHOR'CHO21.CurtiusRN-ON+N-N2O=C=N-RH2ORNHCOOHRNH2-CO2RNO22.DarzensClaisen2,3-O+H2CCOORClC2H5ONaCOHHCClCOORHClCCHOCOORCCHOCOOHCHCHOCO2CHCC23.DelepineC6H12N4+RCH2I[RCH2NC6H12N3]I3HCl,C2H5OH6H2ORCH2NH3I+6HCHO+3NH4ClRCH2NH3INaOHRCH2NH2RIRBrRCl9524.DieckmannClaisenn=2,3(CH2)nCH2COORCH2COOR(CH2)nHCCH2C2H5ONaCOORCOCO2(CH2)nHCCH2COOHCO(CH2)nH2CCH2CO25.DielsAlderP83-8426.EtardCS2CH3CHOCrO2Cl227.Favorskii-X-CH2-COR+NaOHR-CH2-COOH+NaXOHClHCOOHNaOH-NaCl28.FeistBenary-,-1,3-RCCH2ClOH2CCOOR'CCH3OORCOOR'CH3HOC2H5ClCH2ClHCOCH2ClOCOOC2H5CH3C2H5ClCH3COCH2COOC2H5H2O,HClH2O,HCl29.FischerZnCl2NHNCHH2CRNHNHCHHCRNH2CCHRNH2NHCHCNH3R-ZnCl2CuClH2SO4HCl-30.FriedelCraftsP276,P131-13231.FriedelCraftsP130-131RCl+AlCl3R+HClAlCl3FeCl3SbCl5SnCl4BF3TiCl4ZnCl21molP25825932.FriesAlCl3100H3COHCOCH3OHH3CCOCH3H3COCH3OAlCl316520AlCl3BF3ZnCl2FeCl3CS2CCl433.GabrielP454NKOONOORCOOC2H5+XRCOOC2H5-KX3H2O(H+)++COOHCOOHC2H5OHRNH2COOH34.GabrielP37237335.GattermannHCNHClAlCl3ZnCl2OHCHOOHOHCOH+HCN+HClAlCl3OCH3H3COCHOHCNHCl++AlCl340-50GattermannCH3CH3CHONHNHCHOHCNHCl+AlCl3100,39%HCNHCl+4036.GattermannAdamsGattermannZn(CN)2HCNOHCH3CH(CH3)2OHCH(CH3)2CHOCH3Zn(CN)2+HCl+AlCl399%37.GattermannKochP27638.GrignardP18518639.HantzschHClH2OCOOC2H5CH2CH3COClCH2COR+NH3-HCl-H2ONHRH3CC2H5OOC40.HantzschCH2ROOCH3COR'OHHNHHCOORCH2CH3OCOORCHH3CNH2R'HCOOROCH3NHNR'HROOCCOORCH3H3CR'ROOCCOORCH3H3CHNO2+++41.HinsbergP37842.HoeschGattermannHoeschOHOHOHOHRNH.HClOHOHRONHNHRNH.HClNHROHClRCNRCN43.HoffmannAgOH100200H3CH2CH2CNCH2CH3CH3H3CH2CCH2H3CNCH3CH2CH2CH3H2OOH++(CH3)4NOH(CH3)3N+CH3OH130~13544.HoffmannH3N+RXH3NR+XRNH3+NH3RNH2+NH4RNH2+RXR2NH2+XR2NH2+NH3R2NH+NH4R2NH+RXR3NH+XR3NH+NH3R3N+NH4RIRBrRClC6H5ClNH3C6H5NH2ClNO2NHCH3NO2++CH3NH2CU2O,20060atmC2H5OH16045.HoffmannP33946.HoffmannH3CH2CCCH3CH3OHH3CH2CCCH2CH3-H2OHofmannHofmannHofmann47.KnoevenagelP35448.KolbeNaOHH2102CH3COONa+2H2OC2H6+2CO2+2NaOH+H2H2CH2CCOONaCOONaH2CH2CH2CCOORH2CCOOR2+2CO249.KolbeRX+NaCNRCN+NaXAgCN100CuCN56%Ca(CN)211%Zn(CN)22.6%KCNNaCNRIRBrRCl50.KolbeSchmittCO2180~20025%ONaONaCOONaOHOHCOOHH+CO22++Schmitt1254~7atm51.KucherovHg2+CHCH++H2OCH3CHORCCHHg++/H2SO4Hg++/H2SO4H2ORCOCH352.Lebedeff400500Al2O3ZnO1,3++2CH3CH2OHCH2CH2H2H2O20%53.LeuckartRNHR'OR'RNRR'R'R++++HCOOHCO2H2O40~90%MgSO4MgCl22~4mol54.LiebenP28955.LossenP2O5OORRONRHOH+NH2OHR-N=C=O(Ac)56.MannichNHCH3CH3H3CCOCH2CH2NCH3CH3NH2CH2COCH3CCH3CH3CH3COCH3++HCHO.HClNaOH.HCl57.MeerweinPonndorfVerieyORROR'R'HAlORRAlOHR'R'ORRHAlOR'R'+_3/3_3+MeerweinPonndorfVeriey12358.Meyer+RCH2XNaNO2RCH2NO2NaX++R2CHXNaNO2NaXR2CHONO++NaNO2NaXR3CONOR3CX59.MeyerSchusterH5C6CCC6H5H5C6OHCCHH5C6H5C6COC6H5H+60.MichaelNaORCH2H5C6CHCHCOORH5C6HCCH2COORCOORCOOR+H2CCOORCOORH5C6CH2COOHCH2COOHCH2RABABCOORCORCNCONH2NO2SO2RCHORCCHRCOORCORCNCONH2NO2SO2RClaisen61.NefOCH3CH3+NaCCHCHONaCH3CH3H2OCHOHCH3CH362.OppenauerP274RR'OH++(H3C)2CO[(CH3)3C-O]3Al(CH3)2CHOHRR'O21,4-63.PechmannAlCl3P2O5OHOHOHOHOHOOHOCH3OOHOHCH3OOCHROCOHCH3+CH3COCH2COOC2H5-H2O,-C2H5OH64.PerkinH2CH2CBrBrH2CCOORCOORCOORCOORCOOHC2H5ONa-CO2+65.PerkinC6H5-CHO(CH3CO)2OCH3COONaC6H5-CH=CH-COOH170-180+66.PrileschajewRHHRORHRHOOHOCOOHOCHCH2++CH2=CH-CH=CH2R2C=CR2RHC=CR2R2C=CH2RCH=CHRRCH=CH2H2C=CH2.1,2-67.Prinsm1,3-CH3CH3CH2CH2CH3CH3OHCH2OHCH2OCH2CH2OCH3CH3CH2O,H+2CH2O,H+H2OBF31-m1,3-68.ReformatskyP32269.ReimerTiemann20~30%5060%OHOHCHOCHCl3HO+SO3HCNCOOHNO225%70.Riley(R(H)COCH3)RCH2CHOCH2CH2CH2RCOCHOCH3COCH3CH3COCHOSeO2SeO2SeO271.RosenmundPaBaSO4RCOClRCHOH2(Pd-BaSO4)50~80%90%72.RosenmundBraunCuCNCuSO4BrCNCuCNCuBr++73.SandmeyerN2XBrClCN74.SaytzeffSaytzeffSaytzeffHofmannSaytzeffN+N:RRRRRClBrICNCl-Cu+Br-Cu+I-CN-Cu+CCCCHXHCCCCHCCCCH-HXαββCH3CH2CH3CH3OHH3CCHCH3CH3CH3CH2CH2CH3+87.5%12.5%15%H2SO4-H2OXSaytzeff75.SchiemannSchiemann++++++++C6H5NH22HClNaNO2C6H5N2ClNaCl2H2OHBF4C6H5N2BF4HClC6H5-FN2BF3C6H5N2ClC6H5N2BF465%80~90%76.SchmidtRCOOH++++++++++HN3H2SO4R-NH2CO2N2HOOCCH2CH2COOH2HN3H2NCH2CH2NH22CO22N2RCHORCNRNHCHORCORRCONHRH2SO4H2SO4H2SO4HN3HN3N277.SchottenBaumannScho