MBR在难降解有机废水处理中的研究及应用

MBＲ1121．2000922．200092MBＲ。MBＲX703B1000－4602201324－0023－04ＲesearchandApplicationofMBＲforTreatmentofＲefractoryOrganicWastewaterTANGQing-quan1WEIHong-bin1TANGXiu-hua21．CollegeofEnvironmentalScienceandEngineeringTongjiUniversityShanghai200092China2．ShanghaiZhongyaoEnvironmentalProtectionIndustryCo．Ltd．Shanghai200092ChinaAbstractTheresearchandapplicationstatusofMBＲforrefractoryorganicwastewatertreatmentaswellastheappropriateoperationconditionsweresummarized．ThemembranefoulingmechanismsandcontrolstrategieswerediscussedandtheresearchandapplicationsofMBＲwereprospected．KeywordsMBＲindustrialwastewatertreatmentrefractoryorganicwastewatermem-branefouling、、、、、、、。MBＲ、、、。MBＲSＲTHＲT。MBＲ、MBＲ。1MBＲ、1.1MBＲMBＲ1。MBＲ。MBＲ2。MBＲMBＲ3。1.2MBＲMBＲ、、。PVDF、PES、PEPSF。0．01～0．45μm。。1.3MBＲCSTＲ、PFＲ、SBＲ·32·2924201312CHINAWATEＲ＆WASTEWATEＲVol．29No．24Dec．2013MBＲ。CSTＲ。CSTＲPFＲSBＲ、、。2MBＲ2.1MBＲ。MBＲCOD、、、、SS。MBＲＲO。MBＲ。1MBＲ。1MBＲTab．1DataofMBＲfortreatmentofrefractoryorganicwastewaterMLSS/g·L－1COD/g·L－1/mg·L－1COD/%/%418～190．4～1．150～1107393560．5～0．65—80—6PE6～90．9～1．3—＞85—7PE—0．12～0．25—＞82—813～170．68～2．24．8～28＞95＞919+ＲO105381999210PES6～80．6～1—＞80—2.22.2.1MBＲMBＲ。EPS。11。MBＲ2～3m/s12。MBＲ10∶1～50∶113。2.2.2HＲT、SＲTMBＲMBＲHＲT2～10d0．5～3d。MBＲSＲTF/M。SＲT。SＲT20～50d。MBＲMLSS12～15g/L。MBＲMLSS30g/L14。2.2.3pHMBＲpH。pH=1215。pHMBＲ。MBＲ20～30℃MBＲ30～40℃。MBＲ。。MBＲMBＲ50～55℃。EPS、SMP。、。MBＲ。·42·2924．watergasheat．com2.32.3.1MBＲ。。MLSS、OLＲ。EPS/SMP。MBＲ、、MLSS、SMP、EPS、、、。。2.3.2、SＲT、//、、、216。MBＲ17。。。2Tab．2Membranefoulingcontrolstrategies①HＲT→EPS②→③→④→①PAC→EPS②/→③→①SＲT→EPSSMP②MLSS→③F/M→④→EPS3MBＲ、。“+MBＲ”350m3/dPVDFCOD＜1500mg/LCOD＜60mg/L。3MBＲ。3MBＲTab．3EngineeringprojectsofMBＲfortreatmentofrefractoryorganicwastewater/m3·d－1MLSS/g·L－1COD/g·L－1COD/%18200－20209019—PVDF83～4＞9220120PVDF103～6＞9521320PP5～80．658222—PVDF—0．35～0．5585231000PVDF0．8～1．20．18942450091．8＞874MBＲ、。、、。MBＲ、ＲO、。MBＲ。1LinHong-junGaoWei-jueMengFan-gangetal．Mem-branebioreactorsforindustrialwastewatertreatmentacritreviewJ．CritＲevEnvSciTechnol2012427677－740．2MarrotBBarrios-MartinezAMoulinPetal．Industrial·52·．watergasheat．comMBＲ2924wastewatertreatmentinamembranebioreactorareviewJ．EnvironProg200423159－68．3FutselaarHSchonewilleHdeVenteDetal．NOＲITairliftMBＲside-streamsystemformunicipalwastewa-tertreatmentJ．Desalination20072041/31－7．4．MBＲJ．2010269131－133．5．J．200323340－43．6．J．200218340－43．7．J．200218256－59．8YigitNOUzalNKoseogluHetal．Treatmentofadenimproducingtextileindustrywastewaterusingpilot-scalemembranebioreactorJ．Desalination20092401/3143－150．9JolantaBEwaNKwarciakA．Landfillleachatetreat-mentbymeansofanaerobicmembranebioreactorJ．Desalination20082211/3559－565．10．J．199920653－55．11KimJSLeeCHChangISetal．EffectofpumpshearontheperformanceofacrossflowmembranebioreactorJ．SepWaterＲes20013592137－2144．12TardieuEGrasmickAGeaugeyVetal．InfluenceofhydrodynamicsonfoulingvelocityinarecirctulaedMBＲforwastewatertreatmentJ．MembrSci19991561131－140．13WuYZhangHW．Biodegradationofsynthetichighphenolcontaminationwastewaterbyanimmersedmem-branebioreactorA．ProceedingsofInternationalCon-ferenceonEnvironmentalScienceandInformationAppli-cationTechnologyC．WuhanESIAT2009．14CornelPKrauseS．Membranebioreactorsinindustrialwastewatertreatment－EuropeanexperiencesexamplesandtrendsJ．WaterSciTechnol200653337－44．15ChongNMPaiSLChenCHetal．BioaugmentationofanactivatedsludgereceivingpHshockloadingsJ．BioresourTechnol1997592/3235－240．16WangZWuZMaiSetal．ＲesearchandapplicationsofmembranebioreactorsinChinaProgressandprospectJ．SepPurifiTechnol2008622249－263．17AchilliACathTYMarchandEAetal．TheforwardosmosismembranebioreactoralowfoulingalternativetoMBＲprocessesJ．Desalination20092391/310－21．18．MBＲJ．2004301036－39．19KimBＲAndersonJEMuellerSAetal．Designandstartupofamembrane-biological-reactorsystemataFord-engineplantfortreatingoilywastewaterJ．WaterEnvironＲes2006784362－371．20．－MBＲJ．201137363－64．21．MBＲJ．200828882－85．22．MBＲJ．2012641288－1292．23．－ABＲ－MBＲJ．200935567－68．24．MBＲJ．200933172－7483．1988－。[e-mail]2013－08－28·62·2924．watergasheat．com