MetalOrganicFrameworksDesignandApplication

METAL-ORGANICFRAMEWORKSDesignandApplicationEditedbyLEONARDR.MACGILLIVRAYUniversityofIowaMETAL-ORGANICFRAMEWORKSMETAL-ORGANICFRAMEWORKSDesignandApplicationEditedbyLEONARDR.MACGILLIVRAYUniversityofIowaCopyright
2010byJohnWiley&Sons,Inc.Allrightsreserved.PublishedbyJohnWiley&Sons,Inc.,Hoboken,NewJerseyPublishedsimultaneouslyinCanadaNopartofthispublicationmaybereproduced,storedinaretrievalsystem,ortransmittedinanyformorbyanymeans,electronic,mechanical,photocopying,recording,scanning,orotherwise,exckptaspermittedunderSection107or108ofthe1976UnitedStatesCopyrightAct,withouteitherthepriorwrittenpermissionofthePublisher,orauthorizationthoughpaymentoftheappropriateper-copyfeetotheCopyrightClearanceCenter,Inc.,222RosewoodDrive,Danvers,MA01923,978-750-8400,fax[phone],oronthewebat://:Whilethepublisherandauthorhaveusedtheirbesteffortsinpreparingthisbook,theymakenorepresentationsorwarrantieswithrespecttotheaccuracyorcompletenessofthecontentsofthisbookandspecificallydisclaimanyimpliedwarrantiesofmerchantabilityorfitnessforaparticularpurpose.Nowarrantymaybecreatedorextendedbysalesrepresentativesorwrittensalesmaterials.Theadviceandstrategiescontainedhereinmaynotbesuitableforyoursituation.Youshouldconsultwithaprofessionalwhereappropriate.Neitherthepublishernorauthorshallbeliableforanylossofprofitoranyothercommercialdamages,includingbutnotlimitedtospecial,incidental,consequential,orotherdamages.Forgeneralinformationonourotherproductsandservicesorfortechnicalsupport,pleasecontactourCustomerCareDepartmentwithintheUnitedStatesat800-762-2974,outsidetheUnitedStatesat317-572-3993orfax317-572-4002.Wileyalsopublishesitsbooksinavarietyofelectronicformats.Somecontentthatappearsinprintmaynotbeavailableinelectronicformats.FormoreinformationaboutWileyproducts,visitourwebsiteat:designandapplication/editedbyLeonardR.MacGillivray.p.cm.Includesindex.ISBN978-0-470-19556-7(cloth)1.Supramolecularorganometallicchemistry.2.Organometallicpolymers.3.Porousmaterials.I.MacGillivray,LeonardR.QD882.M4820105470.0504426–dc222009049259PrintedinSingapore10987654321CONTENTSPrefaceviiContributorsxi1FromHofmannComplexestoOrganicCoordinationNetworks1MakotoFujita2InsightintotheDevelopmentofMetal-OrganicMaterials(MOMs):AtZeolite-likeMetal-OrganicFrameworks(ZMOFs)37MohamedEddaoudiandJarrodF.Eubank3TopologyandInterpenetration91StuartR.Batten4HighlyConnectedMetal-OrganicFrameworks131PeterHubberstey,XiangLin,NeilR.Champness,andMartinSchro¨der5SurfacePoreEngineeringofPorousCoordinationPolymers165SujitK.GhoshandSusumaKitagawa6RationalDesignofNon-centrosymmetricMetal-OrganicFrameworksforSecond-OrderNonlinearOptics193WenbinLinandShutingWu7SelectiveSorptionofGasesandVaporsinMetal-OrganicFrameworks215HyunukKim,HyungphilChun,andKimoonKimv8HydrogenandMethaneStorageinMetal-OrganicFrameworks249DavidJ.Collins,ShengqianMa,andHong-CaiZhou9TowardsMechanochemicalSynthesisofMetal-OrganicFrameworks:FromCoordinationPolymersandLatticeInclusionCompoundstoPorousMaterials267TomislavFrisˇcˇi
c10Metal-OrganicFrameworkswithPhotochemicalBuildingUnits301SaikatDutta,IvanG.Georgiev,andLeonardR.MacGillivray11MolecularModelingofAdsorptionandDiffusioninMetal-OrganicFrameworks313RandallQ.Snurr,A.O¨zgu¨rYazaydin,DavidDubbeldam,andHoustonFrostIndex341viCONTENTSPREFACEThefieldofmetal-organicframeworks,orMOFs,isundergoingacceleratedandsustainedgrowth.IpersonallybecameacquaintedwithMOFs,ormoregenerallycoordinationpolymers,asanundergraduateresearchstudentwhileatSaintMary’sUniversity,Halifax,NovaScotia,Canada,from1991to1994.Theprocessofmixingreadilyavailablemetalprecursorswithorganiclinkers—manyofwhichfellundertheheadingofbeingcommerciallyavailable—toproduceawidearrayofextendedframeworksclearlythen,andnow,capturedtheimaginationofchemistsandmaterialsscientistsworldwide.Fromafundamentalstandpoint,thereisanimportantlinkbetweenMOFchemistryandthefieldofinorganicchemistry.Inmanyways,MOFchemistryenableschemiststoconnectpreviouslyexistingcoordinationcomplexessoastomakeaconceptuallinkintothefieldofmaterialschemistry.Thislinkhasnowevolvedtoaffordapplicationsrangingfromcatalysistoenergystorage.OrganicchemistsarealsoabletocontributetothemixbycraftingligandswithpropertiesthatoneultimatelyplanstoexpresswithinthewallsofMOFs.Solid-statechemistsandX-raycrystallographersprovideinsightsintothestructuresofMOFssothattheprocessofdesigningandsynthesizingMOFscanberefinedsoastoultimatelycontrolatargetedpropertyandgiverisetofunction.MypersonaldrawtoMOFswas,inretrospect,alsoinspiredbythefieldofsupramolecularchemistry,particularlyasitrelatestotherationaldesignofsolids,orcrystalengineering.Theearly1990switnessedsupramolecularchemistryenveloptheprocessofself-assembly,withacrystalbeingregardedasasupermolec