含硫酸盐废水处理研究现状与展望

1H2S[1]2[2][3][4]SRBS2-HS-H2SCOD[5]1SRBMPBAB2S2-HS-H2SSRBMPB[6]UASB[7-12]EGSB[13-15]IC[16-17]ASBR[18-22]ABR[23-24][25-27][28-29][30][31-33]CH4[34][31-33][35]MPBABR1231212121.2150112.21501113.214122pHORPX703.1A1000-3770(2013)11-0017-006[e-mail][e-mail]3911201311TECHNOLOGYOFWATERTREATMENTVol.39No.11Nov.,2013173MPB[36]SRBMPB[3537][38]SRB80%Venkata[18]SRBCOD35%27%VFAMPBSRBVFACOD78%80%SRBSRB[37]MPBMotoyu[29]MPBSRBSRB[35]UASBUASBVFA90%MPBSRBBernd[39]SRBMPBSRBMPBSRBMPB[2940]44.1COD[28]0.67COD[38]2SRB[28]1.2COD85%95%3[7]UASB390%94%COD[16]3.580%COD90%Rodriguez[12]UASB0.6746.3%1.085.6%SilvaAJ[26]Osamu[41][11]Ha[42]CODCODCOD10.67[10]Silva[26]Ar-naldo[22][15]SO42-ABMPBSRBRoel[43]CODCOD4.2SRBMPBABCODSRBMPBABArnaldo[44]SO42-2.0g/LMPB[38]7.5kg/(m3d)SRBArnaldo[19]0.251.0g/L99%2.03.0g/L71%95%[16]5.5kg/(m3d)90%Silva[26]3911181235g/L97%[35]COD910g/L25.4kg/(m3d)3g/L8.0kg/(m3d)COD97.2%96.3%4.3[1]Lens[45]SRBS2-HS-H2SH2S[36]Silva[26]pH7.99.287.9%99.8%HS-0.2%12.1%1g/LSRBMPBLens[34]UASB[46]SRB[8]SRBChang[47][48]SRBCr6+[49]SRBU6+[50][8]Martijn[51]Tony[52]Demet[53]Erkan[54]Kaksonen[8]Chang[47][55]Tony[27]7.43kg/(m3d)3.71kg/(m3d)82%CuZnNi97.5%AsFe77.5%82%[25][13]EGSB94%[31-33]+UASB[56]SRBCSBSRB4.4pHpH[57]pH6.06.2SRB80%90%[7]UASBpH8[17]ICpH7Silva[26]pH7.99.287.9%99.8%HS-0.2%12.1%1g/LSRBMPBpHpH5[51]pH[58]pHMartijn[51]40dpH4SRBpH64pHpH4SRB[60]pH460%Jong[59]SRBpH3.5Tony[27]pH3.51%SRBpH20Lopes[10]UASB559pH6pH455%65%pHpH450%pHErkan[54]pH2.53.5COD80%90%pH[12][1]Kak-sonen[8]pH2.53pH7.58.5pHpH4.5ORPORP-320-420mVSRB1980%90%[57]ORP[30]ORPORPCOD[60]Xie[14]EGSBORP-440mVCOD73.4%61.3%Khanal[60]-290mVCOD18g/L6g/L733.8mg/L250.3mg/LMPBORP-265mV98.5%45.9%31g/LORP-290mVMPBKhanal[60]ORPORP50100mV5g/LH2S56.3%1g/L3g/LORP[30]4.6SRBSRB3533[36]SRBSRB[61]SRB345470Augusto[20]1CODErkan[61]865SRBSRB4.7Fe2+SRB12pH[62]Fe3+SRBMPB[42]Zhang[6]He[63]SRBSRB+Fe0Fe05.59[5764][6566][14-15]5ABRCODpH[1]HuangJG,WenY,DingN,etal.Effectofsulfateonanaerobicreductionofnitrobenzenewithacetateorpropionateasanelectrondonor[J].WaterResearch,2012,46:4361-4370.[2].[J].,2011,29:111-113.[3].[J].,2011,5(41):15-17.[4],,,.[J].,2007,24(4):5-8.[5]AlbertJHJ,PietNLL,AlfonsJMS,etal.Applicationofbacteria391120involvedinthebiologicalsulfurcycleforpapermilleffluentpurification[J].ScienceoftheTotalEnvironment,2009,407:1333-1343.[6]ZhangJX,ZhangYB,XieQ,etal.Bioaugmentationandfunctionalpartitioninginazerovalentiron-anaerobicreactorforsulfate-containingwastewatertreatment[J].ChemicalEngineeringjournal,2011,174:159-165.[7],,.UASB[J].,2011,34(2):136-138.[8]KaksonenAH,RiekkolaVML,PuhakkaJA.Optimizationofmetalsulphideprecipitationinfluidized-bedtreatmentofacidicwastewater[J].WaterResearch,3002,37:255-266.[9]ShigeiuSY,KenichiroTH,TatsuoYG,etal.Characterizationoflightedupflowanaerobicsludgeblanket(LUASB)methodundersulfate-richconditions[J].JournalofBi-kxenceandBioen-inbbrino,2001,91(2):195-201.[10]LopesSIC,SulistyawatiI,CapelaMI,etal.LowpH(6,5and4)sulfatereductionduringtheacidificationofsucroseunderthermophilic(55)conditions[J].ProcessBiochemistry,2007,42:580-591.[11]SubtilELC.SulfateanddissolvedsulfidevariationunderlowCOD/Sulfateratioinup-flowanaerobicsludgeblanket(UASB)treatingdomesticwastewater[J].Ambi-Agua,2012,7(1):130-139.[12]RodriguezRP,OliveiraGHD,RaimundiIM,etal.AssessmentofaUASBreactorfortheremovalofsulfatefromacidminewater[J].InternationalBiodeterioration&Biodegradation,2012,74:48-53.[13],,,.(EGSB)[J].,2011,6(30):1175-1179.[14]XieQL,LiYH,BaiSY,etal.EffectsofORP,recyclingrateandHRTonsimultaneoussulfatereductionandsulfurproductioninexpandedgranularsludgebed(EGSB)reactorsundermicro-aerobicconditionsfortreatingmolassesdistillerywastewater[J].WaterScience&Technology,2012,66(6):1253-1252.[15],,,.-[J].,2009,3,30(3):924-929.[16],,,.IC[J].,2011,3(5),593-596.[17],,,.IC[J].,2011,24(3):325-331.[18]VenkataMS,ChandrasekharaRN,KrishnaKP,etal.Bioaug-mentationofananaerobicsequencingbatchbiofilmreactor(AnSB-BR)withimmobilizedsulphatereducingbacteria(SRB)forthetreatmentofsulphatebearingchemicalwastewater[J].ProcessBio-chemistry,2005,40:2849-2857.[19]ArnaldoS,MarceloZ.Anaerobictreatmentofsulfate-richwastewa-terinananaerobicsequentialbatchreactor(AnSBR)usingbutanolasthecarbonsource[J].JournalofEnvironmentalManagement,2011,92:1537-1541.[20]AugustoLOC,CatarinaSAC,SuzanaMR,etal.TemperatureandfeedstrategyeffectsonsulfateandorganicmatterremovalinanAnSBB[J].JournalofEnvironmentalManagement,2011,92:1714-1723.[21]ArnaldoS,RobertoSC,JuliaSH,etal.Post-treatmentofeffluentsfromthesulfatereductionprocessbyanaerobicsequencingbatchbiofilmreactors[J].Desalination,2009,237:243-253.[22]ArnaldoS,EugenioF.Applicationoftheanaerobicsequencingbatchreactorswithfixedfilminthetreatmentofindustrialwastewatercontaininghighsulfateconcentration[J].HolosEnvironment,2009,9(1):65.[23],,.SO42-SRB[J].,2010,9(33):164-168.[24],,,.[J].,2012,35(7):36-39.[25]TonyJ,DavidLP.Removalofsulfateandheavymetalsbysulfatereducingbacteriainshort-termbenchscaleupflowanaerobicpackedbedreactorrun