高分子功能梯度材料的研究进展

,,(,430070):,,:;;:TQ317:A:1003-3467(2007)12-0001-05ResearchProgressofFunctionallyGradientPolymerMaterialsZHANGHui-ling,LVPeng,CHENYan-jun(InstituteofMaterialsScienceandEngineering,WuhanUniversityofTechnology,Wuhan430070,China)Abstract:Recently,functionallygradientpolymermaterialshavebecomemoreandmoreimportantinap2plicationfield.Thetypes,preparationmethodsandapplicationsoffunctionallygradientpolymermaterialsarereviewed,andresearchprogressofgradientpolymermaterialsareillustrated.Keywords:functionallygradientpolymermaterials;preparation;application(FGM),/FGM,,,,,,1,:1.1,,,,,,1.2,:,;;1.3:2007-06-06:2007(200750731269):(1956-),,,:(1977-),,,,2005,,:(027)62015745112:,,,,,,(),,,:,;,,,,:;UNIFAC,UNIFAC,1.4,,,(IPN)IPN,,,SKarabanova[1],2,:;;,:,;;;,,,2.1(CRP),,Greszta[2](ATRP),Lee[3]ATRP[4],,,,,[5]ATRP(St)(MMA)Farcet[6],(BA)/St2.2,,Jasso[7],2HENANCHEMICALINDUSTRY200724,,,2565,,Akovali[8](MA)(PSt),(UV)MA,2.3,,,,,,,180[9],,,,1cm2.4,AB,AB,,,,:AB,/,,Ikejima[10]200m/(PVC/PM2MA),[11],23,,PVC/PMMAPVC/(PHMA)(PEO)/PMMA,PSt/PC2.5,,[12],(PP)/(EVAc),,,,,,;,,OHEVAc[13]EVAcOHEVAcPP3070220,EVAc/PPSEMEVA,,PPEVA,,,[14]:,,[15],,,,,2.6312:,,,:0.10.5mm;,,Tran-Cong[16],,,,(2-)/,2.7,,PP/ABS100/0,90/10,0/100,PPABS,0.5min,,,,[17]Stachurski[18],(0290min)(190220250280)2.8Lee[19]Ogumi[20],,,3,PStPSt,PSt/PMA,,,PVC/PHMA,PEO/PMMA(),,[21];,Qin[22],80tan,,4,,,,,,,:[1]KarabanovaVL,MikhalovskyVS,LloydWA,etal.Gra2dientsemi-interpenetratingpolymernetworkbasedonpolyurethaneandpoly(vinylpyrrolidone[J].J.Mater.Chem.,2005,15:499-507.[2]GresztaD,MatyjaszewskiK,PakylaT.Gradientcopoly2mersofstyreneandacrylonitrileviaatomtransferradicalpolymerization[J].PolymerPreprint,1997,38(1):709-710.[3]LeeSB,RussellAJ,etal.ATRPsynthesisofamphiphilicrandom,gradient,andblockcopolymersof2-(dimethyl2amino)ethylmethacrylateandn-butylmethacrylateina2queousmedia[J].biomacromolecules,2003,4:1386-1393.4HENANCHEMICALINDUSTRY200724[4],,.[J].,2001,24(5):268-270.[5],,,.[J].,2004,25(6):1170-1173.[6]FarcetC,CharleuxB.Nitroxide-mediatedminiemulsionpolymerizationofn-butylacrylate:synthesisofconlledhomopolymersandgradientcopolymerswithstyrene[J].Macromol.Symp.,2002,182:249-260.[7]JassoCF,ValdezI,PerezJH,etal.Analysisofacrylatediffusioninaglassypolystrenematrixtopredictgradientstructure[J].JournalofAplliedPolymerScience,2001,80:1343-1348.[8]AkovaliC.Studieswithgradientpolymersofpolystyreneandpoly(methylacrylate)[J].JournalofAppliedPoly2merScience,1999,73:1721-1725.[9]ChekanovYA,PojmanJA.Preparationoffunctionallygradientmaterialsviafrontalpolymerization[J].JournalofAppliedPolymerScience,2000,78:2398-2404.[10]IkejimaT,InoueY.Experimentalapproachestogeneratecompositionalgradientsinthefullybiodegradablepoly2merblendsystembasedonpoly(3-hydroxybutyricacid)[J].MacromolecularChemistryandPhysics,2000,201(14):1598-1604.[11]AgariY,ShimadaM,UedaA.Preparation,characteriza2tionandpropertiesofgradientpolymerblends:discussionofpoly(vinylchloride)/poly(methylmethacrylate)blendfilmscontainingawidecompositionalgradientphase[J].Macromol.Chem.Phys.,1996,197:2017-2033.[12],,,.[J].,1999,(6):752-756.[13]XieXM,XiaoTJ,ZhangZM,etal.Effectofinterfacialtensionontheformationofthegradientmorphologyblends[J].JournalofColloidandInterfaceScience,1998,206:189-194.[14],,,.[J].,1998,(6):682-688.[15],,.[J].,2001,22(12):2104-2107.[16]Tran-CongQ,OkinakaJ.Polymerblendswithspatiallygradedstructurespreparedbyphaseseparationunderatemperaturegradient[J].Polym.Eng.Sci.,1999,39(2):365-374.[17],,.[J].,2004,21(3):151-156.[18]StachurskiZH,EdwardGH,YinM,etal.Particlecoarseninginpolyethylene/polyethyleneblends[J].Macromolecules,1996,29(6):2131-2137.[19]LeeNJ,JangJ,ParkM,etal.Characterizationoffunc2tionallygradientepoxy/carbonfibrecompositepreparedundercentrifugalforce[J].J.Mater.Sci.,1997,32:2013-2020.[20]OgumiZ,AbeT,NakamuraS,etal.Functionallygradi2entpolymerelectrolytepreparedbyplasmapolymeriza2tion[J].SolidStateIonics,1999,121:289-293.[21]BuravallaVR,RemillatC,RongongJA.Advancesindampingmaterialsandtechnology[J].StartMaterialsBulletin,2001,(8):10-13.[22]QinCL,CaiWM,CaiJ,etal.Dampingpropertiesandmorphologyofpolyurethane/vinylesterresininterpene2tratingpolymernetwork[J].MaterialsChemistryandPhysics,2004,85:402-409.4,,100,,208,1.2,4,,,,,:1.,10,50,2.,5,50,3.,5,45,,,,,::[phone]:15838961980512: