2020年西南大学[1099]《物理化学》作业答案

1....2....3.100~10000nm.10000nm.100nm.1~100nm4cNaNO3=300cNa2SO4=295cMgCl2=25cAlCl3....5KBrAgNO3..NO3-..Ag+6....7CO2....8TfTf*TfTf*....9().T100kPa.T100kPa.T100kPa.T100kPa10:()....11-10-10.G0h0..G0H0.G=0H=0.G0H012dG=-SdT+VdpdG.298K...13160J200J.40J.360J.40J.360J140.001molkg-1K3[Fe(CN)6].6.010-3mol?kg-1.5.010-3mol?kg-1.4.510-3mol?kg-1.3.010-3mol?kg-1151000K2SO3=2SO2+O2Ke=0.290K0molL-1().0.0595.0.00354.0.290.0.53916.F.W.Q+W.Q.Q-W17....18m=m++-....19....20....21.B....22....23....24.....25X202P.20X.25XX.25X.20X.25PX26.....27.....28.....29.Ce0.t1/2..Ea.Km30.....31.....pH32.lnc0/cAtk.lncAtk.lnc0/cAtk.lnc0/cAtk.lncAtk33.....34.....35.....36.....37.....38.....39.....40CMC.CMC.CMC.CMC..41C=-20.01t+16mol/dm-3s.800s..k=20.01mol/dm-3/s.C0=16mol/dm-3.400s42.....43rGm.rGm=0G2=G1.rGm0G2G1.rGm0G2G1.rGm0G2G1.rGm0G2G144.....45.....46QW.Q=0.Q0.W0.Q0.W047KCl.....48.....49.....50.rHm0K.rHm.rHm0K.rHm.rHm0K51.A..B.52.A..B.53.A..B.54.A..B.55.A..B.56spccc=0.A..B.57.A..B.58.A..B.59.A..B.60.A..B.61.A..B.62.A..B.63.A..B.64.A..B.65.A..B.66.A..B.67.A..B.681K.A..B.69.A..B.70NaCl.A..B.71.A..B.72.A..B.73.A..B.74.A..B.75.A..B.76.A..B.77.A..B.78.A..B.79.A..B.80E0rGm0.A..B.81.A..B.82.A..B.83.A..B.84.A..B.85SO.A..B.86.A..B.87.A..B.881.A..B.89.A..B.90100mL0.08molL-1KI100mL0.05molL-1AgNO3AgIAlCl3Al3+919212930?10+2,K=2NaCl,H2Of=0max=4NaCl(s)94aNaOHaQ0b9596T197981molH299ABTATBEABBDEEAE