_磺基脂肪酸甲酯的生产与应用技术进展

-(中国日用化学工业研究所,山西　太原　030001):-(MES)MES,MESMES,MES,MES,,MES,MES:;;:423.11:A:1001-1083(2000)02-0029-06,,,-(MES),MES,MES,LAS,,MES,-(),MES,MES,MES,,MESHenkelStepanLionMES,1t/aMES60t/a[1],MES,StepanMES,LionMES,,,MES1MESMES[2]:,SO3(),SO3-,SO3-(),MESA(),()SO3,SO3()(),(),:1998-04-03,:1998-05-18:(1961-),,1986,,29220004ChinaSurfactantDetergent&Cosmetics,()(3),(2),()SO3SO3,(3),(),(3)SO3,()10%20%(),a.,,(),b.()MESA()MESA()MES(),pH,MES()(V),(),pHMESMES,Yamada[3]:C=CHCH=CHCHSO3RRSO3,,MES,,;,2MESMES,SO3MESSO3,MESSO36%7%(),[4]2.11,5%,()NaOHMESAMESAH2O2,pH,(),24h48hSO3,,1,(35%)(60%)1%3%,2.22,,1000klett,H2O2,,24h48h2,5%,MES,,1%2%,20%35%60%,2.3,H2O2,3,H2O2,8%40%,,(),,,,,,MES,,3020002,30,6%3,MES1210.50.051.0(0.5)0.5%0.05%0.5%MES2MES*(w%)*(w%)(klett5%)153012100200153012100200360.220100*,MESLionMES,MES,C16C18MES,StepanMES[5],,MES,35%37%,,3MESMES,,3.1(),MES(LAS)(AS)4[6]4,,MESLASAS,MESLASAS43.2MESLAS,,MESMES,,MES5MESAOSASLAS[7]5LAS,AOSMES,MES56,MES(6[8])3.3M.Masada[9]MES(7),MES5,LAS,31220004:-73.4MESMES,,MESpH,MESpH,MES,MES,,MES,(3)3MES[10]124.4%33%89%89%3.5,Krafft,MESKrafft8,MESKrafft,MESKrafftLAS,MES,MES8MES4MESMES,MES,,;;1/31/2LASMES,,,4.1MES/LAS[6]MESLAS,MES,MES,MESKrafft,MES,(9)25,MES15,MES/LAS=11,9MES/LAS10MES,LAS,LAS(10),MES/LAS,MES,LASMESLAS,,,44MESLASMES/LAS30%40%(LAS/AOSLAS/AS)20%25%(MES5%10%)15%20%15%25%20%30%15%25%++++3220002,30,MES,20%MES,MES,pH,MES,(11(a))MES/LAS(11(b)),MES/LASLAS,MES/LAS,,MES,11MES/LAS4.2MES/AE[6]LAS,(AE)LAS(12),MESAE12MESAEMES/LASAE,AE,KrafftAE20%,Krafft12,MES,AELASMES/AE13,25,15,MES/AE,AEMES,MES/LAS,MES/AEMES/LAS,MES/AEMES/LAS,,13MES/AE,MES/AE14(a),MES,AEMESAE,AE,MESAE,(b),MESAE14MES/AE,MESLASAE,,,Lion19965MESLASAE,34%,MES/LAS33220004:-5Lion(g/30L)%%Hi-TOP25LASAOSAE41100TOP20LASMESAE39100SuperTOP15MESLASAE341005,,MES,,MES,,MESMES,,MES,,MESLion,MES,MES:[1]KaufmanandR.J,Ruebush.Oleochemicals:AWorldOverviwe.ProceedingsWorldConferenceonOleochemicalsIntothe21stCentury[C].ThomasH.ApplewhiteEd.,AmericanOilChemists'Society,Champaign,IL,1990,18.[2]Fabry,B.andB.Giesen.-SulfoFattyAcidEsterBasedonDifferentAlcohols[J].TensideSurfactantsDetergents,1990,27:243-248.[3]Yamada,K.,andS.Matsutani.SeparationandIndentificationofColoredSubstancesinSulfonatedFattyAcidMethylEster,Presentedat84thAOCS[C].Anaheim,CA,USA,April1993.[4]Foster,N.CandK.D.Hovda.ManufactureofMethylEsterSulfonatesandOtherDerivatives.ProceedingsofInternationalConferenceonSoaps,Detergents,andOleochemicals[C].AmericanOilChemists'Society,FortLauderdale,FL,1997.[5]Stepan.[6]Yoneyama,Yuji.PalmOleochemicalsforUseinDetergent-Lion'sPerspectiveontheApplicationofMethylesterSulfonate.Proceedingsofthe1996PORIMInternationalPalmOilCongress[C].1996.516.[7]Okumura,etal.Proceedingsofthe7thCIDinMoscow[C],1976.[8]Ospinal,C.etal.HouseholdPasteCleaningProductsWorldwide.ProceedingsofInternationalConferenceonSoaps,Detergents,andOleochemicals[C],AmericanOilChemists'Society,FortLauderdale,FL,1997.[9]Masuda,M.,etal.Biodegradationof-SulfonateFattyAcidMethylEster(-SFMe)[J].J.OilChem.Soc.1993,42:643-486.[10]Takashi,I.,etal.[P].FP,2,571,368.[11]Satsuki,T.,MethylEsterSulfonates:aSurfactantBasedonNaturalFats,3rdWorldConferenceonDetergentsProceedings[M].ArnoCahnEd,Montreux,1992.135-140.TheTechnologicDevelopmentofMES'sProductionandApplicationsWANGJun(ChinaResearchInstituteofDailyChemicalIndustry,Taiyuan030001,China)Abstract:TherecentdevelopmentofMES'sproductionandapplicationisreviewed.ThepapermainlydescribesthecharacteristicsofthethreeprocessesforthebleachofMES.Thequalitiesofrawmaterialandproductsofthethreeprocessesarecompared.Thephysico-chemicalpropertiesofMESarealsointroduced.Throughsuitableprocess,MESiscomposedwithsodiumalkylbenzenesulfonateor/andethoxylatedfattyalcoholtoproducephosphor-freepowderdetergents.MESisalsousedinliquiddetergents.Keywords:MES;production;application.—广告—万方萃取　专注专业万方萃取是日化用品天然原料及天然药物中间体行业的专业公司,并代理经销国外多家著名同业公司的产品。现有产品系列包括植物、海洋生物以及蜂蜜、蚕丝等的萃取液、精油、干粉等天然萃取原料上百种,欢迎索取资料及样品。:15:510730:[phone]:(020)822195073420002,30