甲醇合成反应器概述

20028Aug.2002294YunnanChemicalTechnologyVol.29,No4,,,,,(,,163714):,,:;;;:TQ053.5:A:10042275X(2002)0520020206SynopsisonMethanolSynthesisReactorXIAOHai2cheng,LIYing2hui,XUXian2ming,GUOJi2ning,ZHANGZhong2tao,KONGFan2hua(ResearchInstituteofDaqingPetrochemicalCompany,Daqing163714,China)Abstract:Principlesanddevelopmentofmethanolsynthesisreactor,thetypicalindustralizedprocesswereintro2duced,anddifferentreactorsunderresearchathomeandabroadwerediscussed.Keywords:methanol;fixedbedreactor;slurrybedreactor;supercritical2phase160,,,70,90,,,,,,,,,,22.1ICIICIICI1966,5MPa,4,,,0.50.6MPa,80ICI2,,311400t/dICI(1):,,,,,4,,,1,3,,,,,3h30t,10h,,2,,,,,,1ICI2.2LurgiLurgiLurgi5MPa,250Lurgi2,,,,,0.1MPa1.5,,,2.3(MGCC/MHI)1957(800t/d),,Lurgi,,14%(mol)13,2Lurgi,291010J/t,3000t/d()2.4TOPSOETOPSOE,,0.20.3MPa,,,,,,40,5000t/d2.5TECICILurgi,90,TECMRF2Z,,;;,,,,,1220024:,;,,,,,,,,,,,,,25002800t/d5000t/d,,,,,33.1:,ICI75t/a,Lurgi45t/a,,LurgiLinde,,Lurgi,ICI,,,TopsoeCasale,,3.1.13,,,,,,,,,,,,,,342,,,2220024,,,,,,3.1.224,,,,,2,100kt/a,,,CO,,5,,,10,GSSTFRRSIPR23.1.3GSSTFR(22)GSSTFR,(),,,,,CO100%3.1.4RSIPR()RSIPR,,,,CO97%2550kg/d,CO/H2,,,3.1.52,,,,(%,V/V):CO29.2,CO23.0,H267.5,CO+CO290%3.2F2T,1975,,22,,,,,22,5,3.2.15,,,,(0.81.2mm):,,;,,,411MPa,220260,20006000h-1:,,,,,,1,3220024:,,,(CO60%90%),,,,,,,Sasol,,,,,,,20%30%,53.2.2,,,,1990,,,,,,,,,,,,,,,3.3,,,,,CO90%,40008000h-1,1.2Meoh/h.gcat,,,4(1),,,22,,(2)20t/a,170t/a,,,(3),,,C30220t/a,(4),,,,,4220024[1],,1FT[J]1,1995,23(6):7131[2],,1[J]1,1999,27():1721781[3],1[C]1,13171[4],,1[J]1,2001,8(2):13161[5],1[J]1,1999,37(1):49521[6],,1[J]1,1999,16(1):39441[7],1[J]1,2001,29(3):1932001[8]1[J]1,1999,20(4):16201[9],,1[J]1,2000,8(6):49521[10],,1()[J]1,2000,12:32351[11],1[J]1,2001,2:32351[12]1[J]1,1994,2:7111[13]1[J]1,2000,25(1):56611[14],,1[J]1,1998,17(6)1[15],,1[J]1,1999,1:25271[16],,1[J]1,1999,27:41521[17]1[M]1:11995,891051[18]1[M]1:,2000,1871951[19]DryRJ.Possibilitiesforthedevelopmentoflargecapacitymethanolsynthesisreactorsynfuelproduction[J]1IndEngChemRes,1988,27:616624.[20]GrimmP.SixyearssuccessfuloperationofLindeisothermareactor[J]1LindeReportsonScienceandTechnology,1991,49:57591(:2002205217)(17),(0.1%),,,(1%)2.3,,/,,/,;,/,,,3/,/,,,,/,,[1]1[M]1:,19961[2].[J].,1995,9:471[3].[J].,1996,8:4191[4].[J].,1993,1:161[5].[J].,1991,28(5):2901[6].[M].:,1993:61[7].[M].:,1984:71[8].[J].,1999,11(6):501:(1957),,,(:2002204228)5220024: