大学有机化学期末考试题(含三套试卷和参考答案)

1.1101.CCHC(CH3)3(H3C)2HCH2.3--6--2--1-3.OCH34.CHO5.6.7.OH8.9.COOH10..2481.CHCH2ClCHBrKCN/EtOH2.23.4.+CO2CH35.1,B2H62,H2O2,OH-1,Hg(OAc)2,H2O-THF2,NaBH46.OOOOO7.CH2ClClNaOHH2O8.ClCH3+H2OOHSN1+9.C2H5ONaOCH3O+CH2=CHCCH3OC2H5ONa10.+C12O3H2OZnCH=CH2CH3COCH3H2OHBrMgH+CH3COC13BrBrZnEtOH11.COCH3+Cl2H+12.Fe,HClH2SO4HNO3CH3(CH3CO)2OBr2NaOHH2SO4NaNO2H3PO2(2).2141.NaOH(A).CH3CH2COCH2Br(B).CH3CH2CHCH2Br(C).(CH3)3CH2Br(D).CH3(CH2)2CH2BrCH32.CH3Br(A).CH3COO-(B).CH3CH2O-(C).C6H5O-(D).OH-3.(A)CH3CCH(B)H2O(C)CH3CH2OH(D)p-O2NC6H4OH(E)C6H5OH(F)p-CH3C6H4OH4.COOHOHHOHCOOHHA,CH3CH3B,C,(2R,3S,4S)-2,4--3-5.()AC6H5COCH3BC2H5OHCCH3CH2COCH2CH3DCH3COCH2CH346.HNO2N2()AH2NCONH2BCH3CHNH2COOHCC6H5NHCH3DC6H5NH27.()ACCl3COOHBCH3COOHCCH2ClCOOHDHCOOH.6.27141.CH2OH2.OO3.CHCHOH4.4O55.CH3CHCHOHCHOCH3OOOH.82-NN--1-B(C9H10O)AlCl3AOCH3BrCHN(C2H5)2D61Fisher23.1101.Z--225--3-2.HOCH2CHCCH2CH2CH2BrCH2CH23.(S)4.33-5.OHCHO6.ONH22-phenylacetamide7.8.NH2HO3S9.410.O.2481.2.BrCN34.5.6.CO2CH3OHOH(NH2NH2,NaOH,(HOCH2CH2)2O7.8.OHCCHCH2CH2CH2CHOC1C17CH2OHClCH3OH+CH3OH9.10.OOCH3CH2CH2CCH3OOCH3O11.COCH2Cl12.CH3NH2Fe,HClH2SO4HNO3CH3NO2CH3(CH3CO)2OCH3NHCOCH3CH3NHCOCH3BrBr2NaOHCH3NH2BrH2SO4NaNO2H3PO2CH3Br(2).2141.A2.B3.D4.A5.C6.C7.D.6..27141.CHOBrMgEt2OMgBrO1,2,H2OCH2OHCrO3-2PyCHO1,KOH2,NaBH4TM82.ONa+-CCH1,2,H3O+HOCCHHg2+H2SO4OHOCH3OCH33.O3,H2OHCCH1,Na,NH3(l)2,CH3CH2BrCCH1,Na,NH3(l)2,OHH2LindlarOH4.CH3COCH3Ba(OH)2I2(CH3)2CCHCOCH3C6H5MgBrCuBrOBr2/NaOHHOOAlCl3H2CC(CH3)2HOOPPATM5.CH3CHCHOCH3+HCHOOH-H2OCH3CCHOCH2OHCH3HCNCH3CCH2OHCH3CHCNOHOOOHH+H2OCH3CCH2OHCH3CHCOOHOHH+-H2O.28A.CH3CH2COClOB.C.Br2,CH3COOHD.ON(C2H5)29.1101.CHOHHOCH2OH2.HClBrCl3.5424.CHO5.NH2HO6.OOO7.8.COOHBr9.CONH210.HCNOCH3CH3.2301.CHCH2ClCHBrKCN/EtOH2.CH3CH2COCH2CO2C2H51,LiAlH42,H3O+CH3COCH3TsOH3.O-CN+HCl4.10H3CCCH3OHCCH3OHCH3H2SO4HIO45.HHOH3O+6.OH3CH3COEtONa/EtOH7.C2H5ONaOCH3O+CH2=CHCCH3OC2H5ONa8.HNO3/H2SO4Br2FeSn+HClHNO20~5HClCu2Cl2C(1)..2121.CH3Br(A).CH3COO-(B).CH3CH2O-(C).C6H5O-(D).OH-2.A,CH3CH2OHB,CH3COCH3C,CH3CH2CHOD,CH3COCH2CH33.AOOOONHBCD114.TNT5.a.b.c.d.AabcdBdabcCbcadDdacb6.ABCD.212123456SN.210201.CH2OH2.4O3.CHCHOH4.CH3CHCHOHCHOCH3OOOH12.5101.2-NN--1-B(C9H10O)AlCl3AOCH3BrCHN(C2H5)2D2.A(C6H10)B(C6H9Ag)AC(C6H14)CBCAR-S.6131Fisher23.1101.S-23-2.Z-12--1-3.CH3CCHCHCHCH3OHCH34.33-5.6.7.CH2(COOCH2CH3)2,8.9.10.NN-.2301.2.BrCNCH3CH2CHOHCH2CH2OHOO3.4.OCNH3CCOCCH3CH3CH3(H3CCCH3O5.6.HHOHOHOC2H5H3CH3COOH7.OOCH3CH2CH2CCH3OOCH3O148.HNO3/H2SO4NO2Br2FeNO2BrSn+HClNH2BrHNO20~5N2+BrHClCu2Cl2ClBrC(1)..2121.B2.C3.C4.c5.b6.B.212123456.210201.CHOBrMgEt2OMgBrO1,2,H2OCH2OHCrO3-2PyCHO1,KOH2,NaBH4TM2.CH3COCH3Ba(OH)2I2(CH3)2CCHCOCH3C6H5MgBrCuBrOBr2/NaOHHOOAlCl3H2CC(CH3)2HOOPPATM3.O3,H2OHCCH1,Na,NH3(l)2,CH3CH2BrCCH1,Na,NH3(l)2,OHH2LindlarOH4.15CH3CHCHOCH3+HCHOOH-H2OCH3CCHOCH2OHCH3HCNCH3CCH2OHCH3CHCNOHOOOHH+H2OCH3CCH2OHCH3CHCOOHOHH+-H2O.5101.A.CH3CH2COClOB.C.Br2,CH3COOHD.ON(C2H5)22..6a.ABCD2,4TollenI2/NaOHb.AB2CTollenABCI2/NaOHCHI3BCCCH3HCH2CH3CHCHH3CCH2CH3CH(I)(R)-2--1-(II)(S)-2--1-A(I)(II)CH3CH2CHCCAgCH3BCH3CH2CHCH2CH3CH3C16CH3CHCH2COOHBr(110)1.2.3.4.5.6.7.8.9.2,4210.2021.(a)(CH3)2CCH2CH3,(b)(CH3)3CCHCH3,(c)C6H5CH2CH2+++2.3ABCCHCH2(CH3)2CHCOCH(CH3)2ACOOHBSO3HCCH3DCHOCH2ClClCH2CH2Cl(CH3)2CHCH2CHC(CH3)2(CH3)2CHCH2NH2174()ANaBNaHCO3CFeCl3DBr25.SN2(a)CH3CH2Br,(b)(CH3)2CHCH2Br,(c)(CH3)3CCH2Br6.AKIBCD7ABCD8.SN1()()()A.IIIB.IIIIVC.IIVD.IIIV9ABCD10.ABCD16123456105CH3CCH3OCH3CHCH3OHCH3CH2CH2OHCH3CCH2CH3OCH3NO2NO2CH3CH3CH2NO2CH3ONO2181131-2.1-2-2-2021.2.3.+CH3ClAlCl34.5.6.7.CH3CH2CHCH2Cl2/H2O(CH3)2CCHCH2CH3O3Zn,H2O(1)(2)CH3CH2CH2CH2BrMgC2H5OHOCH3CH2CH2OCH3+HI(CH3CH2CHONaOHCOCH3Cl2,H2ONaOH198.9.10.2441.2.3.4.CH3CH2CHCH2CH3CH2CH2CH2OHBrCH3BrNO2CH3CH2CH2HOCH2CH2OCH2CH2OCH2CH2OHCH3CH2CCH3OHCH3(CH3CO)2O+OHCH3CH2CCCH3+H2OH2SO4HgSO4ClCH3SN2+H2O205.6.10C6H12OAAC6H14OBBCC6H12CDEDEAE(CH3)2CCH2(CH3)3CCOOHCHO211Fisher231011.212.2523.4.2435.36.7.8.9.10.2021.A2.C3.B4.B5.A6.D7.C8.C9.B10.D612345651.a.ABC1,31Ag(NH3)2+CABBr2/CCl4BAb.ABKMnO4AB2.abcBr2{}{abc}Ag(NH3)2+{ab20COOCH3COOCH3COCH3CH3OHCH3CHCHCCH3CH3CH3O221.2.3.4.5.6.7.8.9.10.CH3CH2CHCH2Cl2/H2OCH3CH2CHCH2ClOH(CH3)2CCHCH2CH3O3Zn,H2O(1)(2)CH3COCH3+CH3CH2CHOCH3CH2CH2CH2BrMgC2H5OHCH3CH2CH2CH2MgBrCH3CH2CH2CH3+BrMgOC2H5OCH3CH2CH2OCH3+HI(ICH2CH2I+CH3ICH3CH2CHONaOHCH3CH2CHCHCHOOHCH3COCH3Cl2,H2ONaOHCOOH+CHCl3(CH3CO)2O+OHOCOCH3ClCH3SN2+H2OCH3OHCH3CH2CCCH3+H2OHgSO4CH3CH2CH2COCH3+CH3CH2CCH2CH3OH2SO4+CH3ClAlCl3CH323201.2.3.4.5.6.102AB.C.DE.CH3CH2CHCH2CH3CH2CH2CH2OH(1)BH3(2)H2O2/CH3BrCH3BrNO2HNO3CH3NO2CH3CH2CCH3OHCH3Cl2CH2ClMgCH2MgCl(1)CH3CCH3O(2)CH3CHCCH2CH3CH3OCH3CHCHCH2CH3CH3OHCH3CCH3CHCH2CH3CH3CH2CHOCH3CCH3OCH2CH2HOCH2CH2OCH2CH2OCH2CH2OHClCH2CH2OHCl2/H2OHOCH2CH2OHO2ClCH2CH2OHNaOHHOCH2CH2OCH2CH2OCH2CH2OHKMnO4(CH3)2CCH2HBr(CH3)3CBrMgCO2(1)(2)H2O/(CH3)3CCOOH(CH3)3CMgBrO3Zn,H2OCOHCH2CH2CHOOH(1)(2)CHO,-H2OCHO??-OHBr2/Fe