CrayValley-Introduction

IntroductionofC4technologiesAgendaCRAYVALLEYIntroductionHydroxylatedPolybutadienes–PolybdandKrasolresinsHydroxylatedPolybutadienes–PolybdandKrasolresinsHomopolymer–RiconresinsHomopolymer–RiconresinsCuringtechnologiesCuringtechnologiesCrayValleyHSC2CrayValleyOverviewCrayValleyOverviewADivisionofTotalSAUpstreamSupplyandMarketingRefiningandCrayValleyHSC3UpstreamSupplyandMarketingRefiningandChemicalsNewFocusFor2014•Oil&gasexploration•Production•Gas&power•Alternativeenergy•SupplyandMarketingofOilProducts•Refining•America•Europe•Asia•PolymersTurnover2013US$261BillionsHeadcounts:98799EmployeesCrayValleyHSCFocusMarketsFocusMarkets•Tire•HotMeltsSpecialtyMarketsSpecialtyMarkets•ThermoplasticAdditives4RubberRubber•TirePerformanceAdditives•Coagents•Processaids•RubberAdhesionAdhesivesAdhesives•Pressuresensitive•Reactiveadhesives•IGS•AutomotiveSealantsSpecialtyMarketsSpecialtyMarketsAdditives•Electronics•PrintedWiringBoards•FlexographicPrintingPlatesGlobalPresenceGlobalPresenceResearchRegionalHQSalesOfficeGlobalHQManufacturingDistributionNetworkFromFeedStreamsFromFeedStreamsCC44CC55CC99Polybd®OZnORR6LiquidRubberLiquidRubberAliphaticHydrocarbonresinsAromaticHydrocarbonresinsNorsolene®Wingtack®Krasol®Ricon®OOOSMA®OODymalink®Dymalink®GlassTransitionTemperature(GlassTransitionTemperature(TgTg))LiquidRubbersAliphaticHRWingtack®AromaticHRNorsolene®InertSolid7-10010050200150TgoC0-50LiquidRubbersPolybd®Krasol®Ricon®ReactivePolymerSMA®MolecularWeight(MolecularWeight(MMnn))Norsolene®Ricon®810010000100000g/mollogscale1000Krasol®Wingtack®Polybd®SMA®AgendaCRAYVALLEYIntroductionHydroxylatedPolybutadienes–PolybdandKrasolresinsHydroxylatedPolybutadienes–PolybdandKrasolresinsHomopolymer–RiconresinsHomopolymer–RiconresinsCuringtechnologiesCuringtechnologiesCrayValleyHSC9LiquidLiquidPolybutadienePolybutadienegeneralpropertiesgeneralpropertiesGeneralPropertiesLiquidRubber(from0,5Pa.s@25°°°°C)(lowMolecularweight)n≈50butadiene10LiquidRubber(from0,5Pa.s@25°°°°C)(lowMolecularweight)NonPolarsystem(36dyne/cm)Hydrophobic(lowMVTR)Hydrolyticstability(AcidandBaseresistance)LowTg(downto-90°°°°C)(nophasetransitionVsT°°°°C)Crosslinkable(Unsaturationsandfunctionalities)PolyPolybdbd®®andKrasolandKrasol™™PolybutadienePolyolsHOOH0.20.60.2nOHOH0.15Polybd®Krasol™0.60.250.15nFEATURES•Polybdresins•PrimaryOH•Branchedstructure:2,4OH/chain•ThermosetPU•LowVinylcontent•VeryLowTg:-75°C•Lowerviscosity•Lowerprice•Krasolresins•PrimaryorSecondaryOH•Linearstructure:2OH/chain•Stableprepolymer•CanproduceTPU•HighVinylcontent•LowTg:-55°C•HighercompatibilitywithPolyetherPolyolsKrasolKrasol™™HydrogenatedPolybutadienePolyolsKrasol™12HydrogenationFeatures•TerminalHydroxylGroups(notaffected)•Linearstructure:2OH/chain•PrimaryOH•SaturatedBackbone•ThermalResistance•Clearliquid•UVResistance•ChemicalIntermediatesPolybutadienePolybutadienePolyolsPolyolsProductsrangeOHTypeVinyl%FunctH2%Mng/molViscosityPa.s@25°CPolybdR45HTLO1st202,4028005PolybdR20LM1st202,4012002OHTypeVinyl%FunctH2%Mng/molViscosityPa.s@25°CPolybd®13KrasolLBH(P)20002(1)651,90200010KrasolLBH(P)30002(1)651,90300013KrasolLBH5000M2nd6510450020KrasolH-LBHP2000101,995200010KrasolH-LBHP3000101,995300015KrasolH-LBH5000M2nd0195450025Krasol™HydrogenatedKrasol™RiconRicon®®ButadieneHomopolymersandCopolymers*xyzOOO*wVeryFlexibleanionicpolymerizationtechnology14ControlofMicro/macrostructuresVinylcontent:from10to90%Styrenecontent:from0to50%Maleiccontent:from0to20%Molecularweight:from1000to10000g/molTg:from–95°°°°Cto0°°°°CViscosity:from0.5Pa.s@25°°°°CViscositycontrolReactivitycontrolTg°°°°CcontrolMechanicalpropertiescontrolRICONRICON®®ButadieneHomopolymersandCopolymersrangeCommercialnamesB/S%/%Mn(g/mo)lTg(oC)Vinyl(%)Viscosity(cps@25oC)Ricon130100/02500-8628750Ricon131100/04500-82282750Ricon134100/08000-672815000Ricon142100/03900-74559750Ricon150100/03900-387040000DiversifiedRiconmicrostructures=optimizedpropertiesLiquidPolybutadiene15Ricon152100/02900-278020000*Ricon153100/04700-228560000*Ricon154100/05200-1490250000*Ricon156100/01400-55701600Ricon157100/01800-49706000Ricon10075/254500-227040000*Ricon18172/283200-643017500Ricon18472/288600-613075000PolybutadienerubberLiquidStyrene-ButadienerubberRICONRICON®®MAMAMaleicAnhydrideButadieneHomopolymersOOOmaleinization16ControlofMaleicAnhydridegraftingRiconisusedasbackboneMaleicAnhydridecontent:2to11MA/chainViscosity:from6,5Pa.s@25°°°°CPolar–NonPolarstructureMetalAdhesioncompatibilIzationDispersionsSurfacetreatmentRICONRICON®®MAMAMaleicAnhydrideButadieneHomopolymersrangeRiconMArangeisdiversifiedtoreachcustomerdemandsCommercialNameB/S%/%Mn(g/mol)Tg(oC)Vinyl(%)Viscosity(cps@25oCMA/ChainFunctionality130MA8100/03100-772865002130MA13100/03100-7328170004130MA20100/03600-682835000**6131MA5100/05300-6828150002131MA10100/05000-6828480005131MA17100/055002850000*9131MA20100/07500-6628100000*11156MA17100/0250070120000**3184MA672/289900-4730170000*6OOOCuringTechnologiesCuringTechnologiesReactionsofPolybdResins:HydroxylGroupsPolybd2,4OH/chainNCO,CatalystNCO,Catalyst3DNetwork–GelformationNCO,CatalystCuringTec