材料的高通量制备与表征技术

[e-mail],,,.[J].,2015,33(10):31-49.1232,4441.1000812.1000243.1001904.61173140-R730.58Adoi10.3981/j.issn.1000-7857.2015.10.003Progressinhigh-throughputmaterialssynthesisandcharacterizationAbstractAbstractOverthelast40years,highthroughputexperimentationhasbeendemonstratedtobeaneffectiveapproachtogeneratehugeamountofmaterialdatainashortperiodoftime,anditisnowconsideredakeyelementofMaterialsGenomeInitiative(MGI)tofulfillitspromisetodelivermaterialsofemergingimportancewithmuchfasterpacesandlowercosts.Inthisarticle,thebrieflyhistoryforhighthroughputmaterialssynthesisandcharacterizationisrecalled.Aseriesofrepresentativetechniquesarereviewed,theirlimitationsareidentified,andthechallengesandfuturetrendsareanalyzed.Inperspective,afacilityconsistingofin-siturealtimematerialsprocessing,characterizationandanalysisbasedonsynchrotronlightsourcesorspallationneutronsources,aswellastheoriginalpositionstatisticreflectingmappingtechnologyfornon-uniformmaterialsarelikelytoplayimportantroleinthefuturegenerationhighthroughputmaterialexperimentation.KeywordsKeywordshighthroughputexperimentation;highthroughputcharacterization;materialsgenomics;synchrotron;spallationneutronsource;statisticreflectingmappingWANGHaizhou1,WANGHong2,DINGHong3,XIANGXiaodong2,4,XIANGYong4,ZHANGXiaokun41.ChinaIronandSteelResearchInstituteGroup,Beijing100081,China2.ChinaBuildingMaterialsAcademy,Beijing100024,China3.InstituteofPhysics,ChineseAcademyofSciences,Beijing100190,China4.SchoolofEnergyScienceandEngineering,UniversityofElectronicScienceandTechnologyofChina,Chengdu611731,China3120153310[1]20802090Schultz[2][3]SymyxCorpIntematixCorp2090[4]Symyx[5,6]Intematix[7,8]GE[9]PMN-PT[10]IntermolecularIntel[11]DODDOENISTLBNLNRELATP[12]SPINS[13][14][15][16][17]21.3220153310[18~20][21],CONO[22,23]Symyx22.1Hanak[1]19702112113[1]3Fig.3Modernhighthroughputexperimentationworkflow2HanakFig.2OriginalconceptofhighthroughputmaterialsexperimentationproposedbyHanak3123[24]2.24[4]512DOE343320153310(Intermolecular)a3420153310[1]b[25]0.1%~1.0%0~X%3.1.28a[3]b[12]2090[3,12,26~28]Mao[14],Jin[29,30]ZnO3.1.39[14]0~X%7Fig.7Schematicillustrationsofcompositionspreadfromco-depositiona8Fig.8Schematicillustrationsofdiscretemasksbab3520153310[31,32]Fe-Co-Ni[33]3.2in-situex-situ10a10b[34]3.31[7,18,35,36]2000/s90000/2300dpi11[18]12[19]2[9][37][38]9AxByCzFig.9IllustrationofthedepositionprocessofAxByCzternarythinfilmlibraryusingcontinuousmovingmaskdaAbBcC10Fig.10Highthroughputphaseformationofthinfilmsamplesba/11Fig.11Scanningcombinatorialinkjetprintingsystem3620153310[39,40]MEMSVlassakFe-Pd[41]Cu-Au-Si[41]4[42~44]13[43]5[45][46~48][49]44.1XXXXX2010~100μm14[14,50]4ZnZrSnCe4.210μm15[51]pulsedLaserdepositionPLDZnO-MgO[52][30,53][54]12Fig.12Substrate-net-masksolutioncombustionmicro-reactorarrayba13Fig.13Schematicdiagramofthemicrofluidicparallelscreeningreactorcab3720153310[55~57]16[55~57]4.4VlassakPnSC[41,58,59]25/17[58]80nm900℃104/s10nJ/KCu-Au-Si18[41]1μm10000/hCpH19[60]80~100nm780nm14XFig.14Automaticmicro-beamX-rayfluorescenceanddiffractionsystem15ZnO-MgOFig.15HighthroughputcharacterizationofopticalpropertiesofZnO-MgOcombinatorialmaterialslibraryaXcbbMgO-ZnOaMgO-ZnO-3820153310[61]617Fig.17SchematicillustrationsofPnSC16Fig.16EvanescentmicrowaveprobemicroscopedevelopedatLBNL,USAcab18Cu-Au-SiFig.18CompositiontrendsoverCu-Au-Sisampleslibraryabb/℃aCu/Sic/kJ·mol-13920153310[39,40,62~66]micro-electro-mechanicalsystemMEMS20b19Fig.19Femtosecondpulsedlasersystemforthermalmeasurementdabce20Fig.20Typicalmicro-scalemechanicalmeasurementseMEMSabcdAFM4020153310~0.5μm--4.7[67][68][69][70]21[71]MFMCo-Cr-Mn-Nb-NiCo21bCo-Cr-MoCo24℃24oC21cCo-Cr24oCCr0.2Co0.84.8[42~44]13[43]22[72]4.9[73]LIBS-OPA[74]LA-ICP-MS-OPA[75]X-XRF-OPAOPA-RM[76]SPARK-OPA[77]23[78][76,77]--/24[73]/21MFMCo-Cr-MoFig.21ApplicationofMFMtomapmagneticdomainstoobtainCurietemperature-compositionrelationshipfortheCo-Cr-MoternarysystembCo-Cr-MoaCo-Cr-Mo-Nb-Nic/-Co-Cr-Mo4120153310[77,79]25[80]5Issacs[81]XXGd(La,Sr)AlO3:EuEuYoo[33]XFe-Co-Ni2Gregoire[82]X/Bi-V-Fe/500022PRS-16Fig.22PRS-16multi-channelhighthroughputreactorforcatalysisbyYashentechCorporation23Fig.23PointtopointdistributionofmicrostructureandcompositionofstainlesssteelsabcdPRS-1624Fig.24Statisticdistributionanalysisofin-situmaterialscharacterization4220153310~1226X8X265.1.1XX/XX5.1.2XXX-rayabsor