典型冶炼厂废水深度处理及零排放工艺设计研究袁新杰

2018－10－091962—2014、、。835001、。。X703A1008－021X201901－0188－03AdvancedTreatmentandZeroDischargeofSmelterWastewaterYuanXinjieXinjiangUygurAutonomousＲegionEnvironmentalProtectionＲesearchInstituteUrumqi835001ChinaAbstractInthispaperthetechnicalresearchonthesmelterwastewatertreatmentiscarriedout．Throughthemethodofpre－classifyingandre－processingthewastewaterthewastewaterwithdifferentcharacteristicsofeachlinkistreatedindepthandeffectively．Thetreatmentprocesscombinesthemoremainstreammembranetreatmenttechnologyevaporationcrystallizationtechnologyetc．tocompletethewastewatertreatmentproblemmoreefficientlyandfurthermeetthenewemissiontargetsofzerodischargeofwastewaterinthesmeltingindustry．Keywordsindustrialwastewatermembranetreatmenttechnologyzeroemissions。。、1。2。11．1、、、、、、、3。1。1ＲOＲOＲO/t/d30200508032015200pH9．18．813．010．02．410．0/μs/cm2950．07270．0340039800．065000．0128700．037300．0TDS/mg/L2492．06264．027862．078778．014508．038342．0Cl－/mg/L454．7586．37872．6430．7＞48000287．2SO42－/mg/L960．62920．24682．913016．146645．013256．3Ca2+/mg/L220．4380．8160．00．070．16931．862．0Mg2+/mg/L170．2504．4190．018．2103．54570．3182．3/mg/L1251．33028．075．1600．636086．1800．8CO32－/mg/L0．00．03780．03150．00．0135．0HCO32－/mg/L1921．52928．0366．011391．80．01875．8/mg/L1576．62402．43453．511974．50．01651．7COD/mg/L5．019．0290．00．0300．075．0GB/T199232005《》·881·SHANDONGCHEMICALINDUSTＲY201948DOI:10.19319/j.cnki.issn.1008-021x.2019.01.07512。2Na+/mg/L＜1000Ca2+/mg/L＜500Mg2+/mg/L＜500pH6～71．21TDS、COD。2TDS600～800mg/L1876～11392mg/LCOD。3Cl－SO42－Cl－48000mg/LSO42－46445mg/L36086．1mg/LCOD4。4。22．11。12．2ＲO、ＲOＲO。DTL－ＲO。DTL－ＲODTＲO。DTＲO。DTＲODTＲODTＲO。DTL－ＲO、DTＲO5MVＲ6。2．33ＲOＲOＲOＲOＲO/m3/d302005028028021070pH9．18．89．07．07．07．0TDS/mg/L2300．05170．031804507．15555．7277．821389．4＜1000Cl－/mg/L454．7586．3569．1951．147．63661．9＜250SO42－/mg/L960．62920．22664．62664．6133．210258．7＜250Ca2+/mg/L220．4380．8160．0324．220．01．077．0Mg2+/mg/L170．2504．4190．0412．520．01．077．0/mg/L1251．33028．02796．3150．07．5577．5＜450CO32－/mg/L0．00．00．00．00．00．0HCO32－/mg/L1921．52928．02796．750．02．5192．5/mg/L1576．62402．42294．750．02．5192．5＜350COD/mg/L5．019．017．217．21．763．5＜60·981·4DTLＲODTＲODTＲOＲOＲO/m3/d320200801570670726．7566．8159．9510．156．7pH10．010．013．02．47．07．07．07．07．07．07．0TDS/mg/L90300．024100．027862．014508．021389．455883．953434．72690．6233365．2269．124484．4＜1000Cl－/mg/L430．7287．27872．6＞480003661．91614．01545．480．76478．78．1734．4＜250SO42－/mg/L13016．113256．34682．946645．010258．711804．711302．9590．247383．759．05371．1＜250Ca2+/mg/L70．162．00．06931．877．060．057．53．0241．00．327．3Mg2+/mg/L103．5182．318．24570．377．0114．1109．25．7457．90．651．9/mg/L600．6800．875．136086．1577．5595．2569．929．82389．13．0270．8＜450CO32－/mg/L3150．0135．03780．00．00．01996．11911．399．88012．410．0908．2HCO32－/mg/L11391．81875．8366．00．0192．56064．65806．8303．224343．130．32759．4/mg/L11974．51651．73453．50．0192．56644．76362．2332．226671．533．23023．3＜350COD/mg/L0．075．0290．0300．063．563．762．86．4244．21．352．2＜603579．68kWh/d0．6/kWh47．81/d3．3kW641．20/d689．01/DTL－ＲO1084．80kWh/d0．6/kWh650．88/d45．2kW1．44L/d25．0/L36．00/d2011．44L/d25．0/L36．00/d2011．12L/d60．0/L67．20/d24/3444．44/d1234．52/dDTＲO901．20kWh/d0．6/kWh540．72/d37．6kW1．92L/d25．0/L48．00/d1511．92L/d25．0/L48．00/d1510．22L/d60．0/L13．44/d24/3348．33/d998．49/dDTＲO5481．60kWh/d0．6/kWh3288．96/d228．4kW17．28L/d25．0/L432．00/d10117．28L/d25．0/L432．00/d1012．08L/d60．0/L124．80/d144/32090．00/d6367．76/d156．00kWh/d0．6/kWh93．60/d6．5kW8900．00/d8993．60/d28752．00kWh/d0．6/kWh17251．20/d1198．0kW17251．20/d57．60kWh/d0．6/kWh34．56/d2．4kW34．56/d955．00/d36524．15/d38．25/t955t/d192·091·SHANDONGCHEMICALINDUSTＲY201948/pH1pH2～5Cu2+pH5。pHNH2H+Cu2+pH。pH5NH2Cu2+。pH5。3．22Cu2+Cu2+/Cu2+2。Cu2+。Cu2+。。4CTS－NOSC。CTS－NOSCpH5。Cu2+。/。1ChoiMoonjungJangJyeyoung．Heavymetalionadsorptionontopolypyrrole－inpregnatedporouscarbonJ．JColloidInterfSci20083251287．2SongJooyoungKongHyeyoungJangJyongsik．Adsorptionofhesvymetalionsfromaqueoussolutionbypolyrhodanine－en-capsulatedmagneticnanoparticlesJ．JColloidInterfSCi20113592505．3．J．200741149－54．4GengXYKwonOHJangJ．Electrospinningofchitosandis-solvedinconcentratedaceticacidsolutionJ．Biomaterials200526275427－5432．5．J．20082511979－982．．/J．2019481191－192．櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌櫌1904ＲO、DTＲO、DTL－ＲO、MVＲ7。、、、。MVＲMVＲMVＲ8、MVＲ、“”“”。“”。1．J．20161643－44．2．J．2010333117－122．3．CN105000635AP．2015－10－28．4．J．2012353237－241．5．D．2001．6．J．199818230－32．7．D．2013．8．D．2013．．J．2019481188－190192．·291·SHANDONGCHEMICALINDUSTＲY201948