高级氧化法提高难降解有机污水生物降解性能的研究进展魏令勇

Bio-refractoryorganicwastewaterBROW。AdvancedoxidationprocessesAOPsBROW、、·OH、、、CO2H2O[1]。AOPs、、、、、。AOPsAOPsBROW。AOPs。AOPsBROW。AOPsBROW。11.1FentonFentonFentonHaberWeissFentonFe2+H2O2·OHCO2、H2O[2]。H2O2·OHUV、Photo、US、MWElectroFentonFentonFentonFentonH2O2+UV、Photo-Fen-ton、US-Fenton、MW-FentonElectro-Fenton[3]。Fenton、pH、H2O2Fe2+、。Fenton102249、。、、、。X703.1A1000-3770(2011)01-0014-0062010-04-15(20876175)(1979－)[e-mail][e-mail]37120111TECHNOLOGYOFWATERTREATMENTVol.37No.1Jan.,201114DOI:10.16796/j.cnki.1000-3770.2011.01.004UV、US、。pH2～4。FentonFenton。Fenton[4]、[5]、[6]、[7][8]B/CBOD5/COD0.3Zahn-WellensSBR、UBAF、MBBR-。Fenton。Fenton·OHBROWH2O2+UVB/C0.130.42[9]Photo-Fenton[10][11]B/C0.033、0.030.55、0.30WM-Fenton、US-Fenton、Electro-Fenton[12]、[13]、[14]B/C0.36。FentonFenton、、、。Fenton、Fenton。1.2BROW、。·OHO3/、O3/UV、O3/H2O2、O3/UV/H2O2O3/US。、pH、O3、pH8～10。。GAC、Fe/ACF、Mn/GAC[15]、[16]、[17]B/C0.46、0.53、0.42O3H2O2·OH[18][19]B/C0.70.36O3UVB/C0.060.5[20]。、、、O3。2ElectrochemicaloxidationprocessesEOPs[21]。、3。DimensionallystableanodeDSA、EOPs。15、。、、、。BROW。PbO2TiTi/PbO2、TaODBODCOD0.390.75[22]Ti/Pt、B/C0.460.68[23]。Ti/Co/SnO2-Sb2O2、GACPBC[24][25]B/C0.220.270.400.43Ti/RuO2-IrO2-TiO2、ACF、GACGACFe2+-Fenton[26]B/C0.1250.486。[27]、[28]。BROW。、、、BROW。、。、、。3-[29]。TiO2、ZnO、CdS、WO3、SnO2TiO2-。TiO2TiO2、、TiO2TiO2TiO2、TiO2-TiO2[30]。、、、pH、。BROW。TiO2[31][32]B/C0.40TiO2FixedbedreactorFBR60minB/C00.65100%95%[33]Ag+、Pb2+、Fe3+、La3+、Y+、Ce3+TiO2ABSAg+5%TiO2B/C0.230.47[34]。、、。、、、。、。3711642×104～5×108Hz1900～5200K5×107Pa400km·s-1[35]。、、、pH。BROW。US[36][37]B/C0.0400.240.36-COD45%81%[38]。、、、、、。US/O3、US/H2O2、US/Fenton、US/UV/TiO2、US/WAO。。5WetairoxidationWAOCatalysiswetairoxidationCWAO。WAOCO2H2O。WAO150～350℃、5～20MPa。WAOCWAO。H2O2WAOCWAOWetperoxideoxidationWPOCatalysiswetperoxideoxidationCWPO。WAO374℃22.1MPaSupercriticalWaterOxidationSCWO。CWAO、3。WAOSCWO、、、。CWAOWPO。。WAOB/C0.0750.68[39]WAOSBRWAOB/C0.050.51SBRCOD95%CWAOVcCuO/Al2O3Ti-Ce-BiTi-Ce-BiCOD23%B/C0.170.6[40]。CWAO[41][42]。WAOH2O2CWPO[43]。、、、。17。6AOPs、、。AOPsAOPs。1。。、AOPs。2。AOPs、。。3。、。4AOPsAOPs。AOPs。5。。AOPs、、。[1],,.[J].,2004,24(11):9-12.[2]FHaber,JWeiss.Thecatalyticdecompositionofhydrogenperox-idebyironsalts[C].ProceedingsoftheRoyalSocietyofLondon(SeriesA),1934,147(51):332-345.[3]ENeyens,JBaeyens.AreviewofclassicFenton'speroxidationasanadvancedoxidationtechnique[J].JournalofHazardousMateri-als,2003,98:33-50.[4]LMater,EVCRosa,JBerto,etal.Asimplemethodologytoeval-uateinfluenceofH2O2andFe2+concentrationsonthemineralizationandbiodegradabilityoforganiccompoundsinwaterandsoilcon-taminatedwithcrudepetroleum[J].JournalofHazardousMaterials,2007,149:379-386.[5]HTekin,OBilkay,SSAtaberk,etal.UseofFentonoxidationtoimprovethebiodegradabilityofapharmaceuticalwastewater[J].JournalofHazardousMaterials,2006,136:258-265.[6]XJWang,YSong,JSMai.CombinedFentonoxidationandaero-bicbiologicalprocessesfortreatingasurfactantwastewatercon-tainingabundantsulfate[J].JournalofHazardousMaterials,2008,160:344-348.[7]SChen,DZSun,JSChung.Treatmentofpesticidewastewaterbymoving-bedbiofilmreactorcombinedwithFenton-coagulationpre-treatment[J].JournalofHazardousMaterials,2007,144:577-584.[8],,.Fenton-[J].,2007,1(4):57-60.[9]JLdeMorais,PPZamora.Useofadvancedoxidationprocessestoimprovethebiodegradabilityofmaturelandfillleachates[J].JournalofHazardousMaterials,2005,123:181-186.[10]MJFarré,X.Doménech,J.Peral.Assessmentofphoto-FentonandbiologicaltreatmentcouplingforDiuronandLinuronremovalfromwater[J].WaterResearch,2006,40:2533-2540.[11],,,.Fenton[J].,2004,30(6):344-347.[12]YYang,PWang,SShi,etal.MicrowaveenhancedFenton-likepro-cessforthetreatmentofhighconcentrationpharmaceuticalwastewater[J].JournalofHazardousMaterials,2009,168:238-245.[13],,,.US/Fenton-[J].,2006,26(6):17-20.[14]FAloui,SKchaou,SSayadi.Physicochemicaltreatmentsofanion-icsurfactantswastewater:effectonaerobicbiodegradability[J].JournalofHazardousMaterials,2009,164:353-359.[15]LCLei,LGu,X.WZhang,etal.Catalyticoxidationofhighlycon-centratedrealindustrialwastewaterbyintegratedozoneandactivat-edcarbon[J].AppliedCatalysisA:General,2007,327:287-294.[16],,,.-[J].:,2006,32(4):449-454.[17],,.[J].,2007,30(5):65-68.[18]CTizaoui,LBouselmi,LMansouri,etal.Landfillleachatetreat-mentwithozoneandozone/hydrogenperoxidesystems[J].JournalofHazardousMaterials,2007,140:316-324.[19],,.O3/H2O2[J].,2004,1:15-16[20]JJWu,CCWu,HWMa,etal.Treatmentoflandfillleachatebyo-zone-basedadvancedoxidationprocesses[J].Chemosphere,2004,54:997-1003.37118[21],,.[M].:,2002:94-105.[22],,.[J].,2005,31(5):73-75[23]AGVlyssides,MLoizidou,PKKarlis,etal.Electrochemicaloxi-dationofatextiledyewastewaterusingaPt/Tielectrode[J].JournalofHazardousMaterials,1999,70:.41-52.[24],,.[J].:,2008,38(2):309-312,318.[25]BWang,WPKong,HZMa.Electrochemicaltreatmentofpapermillwastewaterusingthree-dimensionalelectrodeswithTi/Co/SnO2-Sb2O5anode[J].JournalofHazardousMaterials,2007,146:295-301.[26],,.-Fenton[J].,2008,35(6):84-89.[27],,,.[J].,2006,7(11):121-123.[28],,,.-[J].:,2006,36():138-140.[29],,.[J].,1997,25(5):553-558.[30]UIGaya,AHAbdullah.Heterogeneou